Effect of down-stream processing parameters on the mechanical properties of bacterial cellulose

Bacterial cellulose (BC), a biodegradable polymer with high degree of crystallinity, produced by Gluconacetobacter xylinus, was used as reinforcement in biocomposites. The downstream process parameters involved in the preparation process of BC have important influence on its mechanical properties. The effect of some key processing parameters such as treatment temperature, drying stages, type of treatment solvent and pressure on biocellulose sheets was investigated during drying in order to modify the parameters responsible in mechanical properties. The rise in treatment temperature and drying processes of BC sheets showed about 8 and 11 % reduction in tensile strength, respectively. The addition of NaOH solutions during the treatment reduced the tensile strength of BC sheets sharply, though an increase in NaOH concentration produced treated samples with higher tensile modulus. The use of optimum NaClO solution as a cheap treatment solvent led to an increase of about 10–11 % in the mechanical properties of BC. A pressure increase during drying stage improved the tensile strength of biocellulose sheets by 7 % and resulted in highly enhanced tensile modulus of BC samples. The production process (microbial fermentation) and structural features (porous web-shaped structure) provide an ideal scenario for synthesis of BC composites. A number of schemes have been introduced to synthesize BC composites with different materials. Among these schemes, the initial addition of materials to BC culture media, the treatment of BC with solutions and suspensions, and the dissolution of BC in solvents are the most commonly used techniques.     

Effect of poly(vinyl pyrrolidone) concentration and coagulation bath temperature on the morphology,permeability, and thermal stability of asymmetric cellulose acetate membranes

Cellulose acetate (CA) is widely used in membrane processes. In this study, CA (weight‐average molecular weight = 52,000) was mixed with poly(vinyl pyrrolidone) (PVP; weight‐average molecular weight = 15,000) as an additive in 1‐methyl‐2‐pyrrolidone as a solvent. The phase‐inversion method was used for the preparation of flat‐sheet membranes. The effects of PVP concentration and coagulation bath temperature (CBT) on the morphology, pure water permeation flux, and thermal stability of the prepared membranes were studied and are discussed in this article. The solute rejection of the developed CA membranes was quantified with an insulin protein solution. The results showed that an increase in the CBT levels from 0 to 23°C along with an increase in the PVP concentration in the cast film from 0 to 1.5 wt % resulted in an increase in the macrovoid formation in the membrane sublayer, an increase in the pure water flux (PWF), and a decrease in insulin rejection. Further increases in the PVP concentration from 1.5 to 3, 6, and 9 wt % resulted in gradual suppression of the macrovoid formation, a decrease in PWF, and an increase in insulin rejection. Higher PVP concentrations and lower CBT levels also appeared to result in higher glass‐transition temperatures. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Effect of Al addition on pressureless sintering of B4C

The effect of Al addition on pressureless sintering of B₄C ceramic was analyzed in the present work. Different amounts of Al, from 0 to 5 wt.% were added to the base material and pressureless sintering was conducted at 2050 and 2150 °C under argon atmosphere. Microstructure, crystal phases and density evolution were studied and correlated to Al additions and firing temperature. Density and grain size of sintered samples, increased significantly with Al load while less evidence is the effect of sintering temperature; 94% dense material was obtained by adding 4 wt.% Al regardless of the maximum firing temperature.     

Progressive microforming process: towards the mass production of micro-parts using sheet metal

Although there is considerable published literature on micro-metal forming processes, there is still a lack of research towards implementing these processes commercially. Some of the challenges are handling of micro-parts and process intermittency. This work demonstrates the feasibility of producing symmetric micro-parts using a progressive forming set-up. Such a progressive forming process alleviates the challenges in handling and removal of micro-parts. Micro-pins with diameters of 0.3, 0.5, and 0.8 mm were successfully manufactured without defects. Experimental observations together with process simulation results showed that this process has three main stages: (1) indentation at the very beginning, (2) upsetting, and (3) extrusion predominantly occurring at the very end stage of the stroke. The bulk of the pin forming occurs at the end stroke of the process (extrusion stage). The effects of punch/pin diameter ratio on the pin aspect ratio and the maximum forming load were also investigated. In addition, the finite element results also revealed that a hybrid friction model was required to be implemented for better fit with experimental results as compared to the shear and Coulomb friction models.     

Developing an (Al,Ti)N x C y Interlayer to Improve the Durability of the ta-C Coating on Magnetic Recording Heads

In this study, a new surface pre-treatment technique has been developed to improve the durability of the ultra-thin tetrahedral amorphous carbon (ta-C) coating for magnetic tape drive read/write heads. In this technique, prior to the deposition of an 8-nm ta-C overcoat, a 2-nm thin TiN interlayer was deposited on the heads surface and bombarded with energetic Ar⁺ and C⁺ ions. X-ray photo-electron spectroscopy results revealed that this surface pre-treatment technique would lead to the formation of an atomically mixed (AlTi)N _x C _y interlayer which can chemically bond the interlayer to the overcoat and substrate. The effect of this atomically mixed interlayer on the wear resistance of the ta-C coating was investigated using ball-on-flat tests as well as a functional tape drive tester. According to the ball-on-flat test results, the application of the (AlTi)N _x C _y interlayer was able to improve the wear life of the ta-C overcoat by up to 3.3 times as compared to that of the conventional ta-C coating. The results of the wear tests in a real head/tape interface were in agreement with the ball-on-flat results, and showed that while the conventional ta-C film was completely removed from the head surface, the ta-C film with (AlTi)N _x C _y was able to protect the head surface for wear tests of about 1.6 million meters.     

Numerical and experimental analysis of wall thickness variation of a hemispherical PMMA sheet in thermoforming process

In thermoforming, a heated plastic sheet is stretched into a mold cavity by applying pressure, eventually assisted by direct mechanical loading. Since upon its contact with the cold surface of the mold the sheet is prevented from undertaking any further deformation, the forming sequence induces a thickness variation in the final part. This fundamental inherent defect of thermoforming technology highly affects the optical characteristics of optical products. Therefore, the more uniform the wall thickness, the less chance optical defects will occur. In this research, the production process of a hemispherical transparent PMMA sheet as an optical product was numerically simulated. The simulated process is a two-step process comprising a combination of free forming and plug-assisted forming. In the simulation, the acrylic sheet is assumed to undergo a nonlinear and large elastic deformation which merits application of hyperelastic models. Mooney–Rivlin hyperelastic model is used as the constitutive equation. The obtained numerical results are validated with those achieved from the experiments. Different combinations of free forming and plug-assisted forming methods are studied based on what percentage of total height of the final part is produced by each method. Finally, an optimum combination of the two-step forming process is proposed. With this optimum combination, satisfactorily uniform wall thickness and minimal mold marks on the product surface will be achieved.     

A novel hybrid multi-objective shuffled frog-leaping algorithm for a bi-criteria permutation flow shop scheduling problem

This paper investigates a novel multi-objective model for a permutation flow shop scheduling problem that minimizes both the weighted mean earliness and the weighted mean tardiness. Since a flow shop scheduling problem has been proved to be NP-hard in a strong sense, a new hybrid multi-objective algorithm based on shuffled frog-leaping algorithm (SFLA) and variable neighborhood search (VNS) is devised to find Pareto optimal solutions for the given problem. To validate the performance of the proposed hybrid multi-objective shuffled frog-leaping algorithm (HMOSFLA) in terms of solution quality and diversity level, various test problems are examined. Further, the efficiency of the proposed algorithm, based on various salient metrics, is compared against two well-known multi-objective genetic algorithms: NSGA-II and SPEA-II. Our computational results suggest that the proposed HMOSFLA outperforms the two foregoing algorithms, especially for large-sized problems.