Effect of solution chemistry and operating conditions on the nanofiltration of acid dyes by a nanocomposite membrane

A composite nanofiltration membrane was developed by a poly(acrylic acid) in situ ultraviolet (UV) graft polymerization process using an ultrafiltration polysulfone membrane as a porous support, by a phase inversion method. SEM images showed that the PSf membranes had numerous finger-like pores. Atomic force microscopy (AFM) showed that the roughness of the surface was reduced by an increase in UV irradiation times. The rejections of sodium chloride and sodium sulfate were moderate and declined with the increase of concentration. We observed that by increasing UV irradiation time and nanofiltration pressure applied, retention of dyes was enhanced and in the most irradiated membrane (M-4 membrane) at 4 bars, color removal with a high rejection of about 99.80% was achieved. It was found that the separation efficiency of dyes in the mixture of salt and dyes decreased with the salt concentration due to a decrease in the Donnan effect. It was also found that by varying the pH, the membrane surface and the dyes' charges are changed, which meant that the membrane surface and dyes had different interactions at various pHs.     

Covalent Adaptable Microstructures via Combining Two-Photon Laser Printing and Alkoxyamine Chemistry: Toward Living 3D Microstructures

Manufacturing programmable materials, whose mechanical properties can be adapted on demand, is highly desired for their application in areas ranging from robotics, to biomedicine, or microfluidics. Herein, the inclusion of dynamic and living bonds, such as alkoxyamines, in a printable formulation suitable for two-photon 3D laser printing is exploited. On one hand, taking advantage of the dynamic covalent character of alkoxyamines, the nitroxide exchange reaction is investigated. As a consequence, a reduction of the Young´s Modulus by 50%, is measured by nanoindentation. On the other hand, due to its “living” characteristic, the chain extension becomes possible via nitroxide mediated polymerization. In particular, living nitroxide mediated polymerization of styrene results not only in a dramatic increase of the volume (≈8 times) of the 3D printed microstructure but also an increase of the Young's Modulus by two orders of magnitude (from 14 MPa to 2.7 GPa), while maintaining the shape including fine structural details. Thus, the approach introduces a new dimension by enabling to create microstructures with dynamically tunable size and mechanical properties.     

Magnetic and photocatalytic properties of CoFe2O4/Ni nanocomposites

Journal of Electroceramics - In this research, hard/soft CoFe2O4/Ni magnetic nanocomposite samples with different concentrations of Ni were successfully produced by a two-step mechanical alloying...     

Multiresolution HVS and statistically based image coding scheme

In this paper a novel multiresolution human visual system and statistically based image coding scheme is presented. It decorrelates the input image into a number of subbands using a lifting based wavelet transform. The codec employs a novel statistical encoding algorithm to code the coefficients in the detail subbands. Perceptual weights are applied to regulate the threshold value of each detail subband that is required in the statistical encoding process. The baseband coefficients are losslessly coded. An extension of the codec to the progressive transmission of images is also developed. To evaluate the performance of the coding scheme, it was applied to a number of test images and its performance with and without perceptual weights is evaluated. The results indicate significant improvement in both subjective and objective quality of the reconstructed images when perceptual weights are employed. The performance of the proposed technique was also compared to JPEG and JPEG2000. The results show that the proposed coding scheme outperforms both coding standards at low compression ratios, while offering satisfactory performance at higher compression ratios.     

Genetic-based minimum classification error mapping for accurate identifying Peer-to-Peer applications in the internet traffic

In this paper, we propose a hybrid approach using genetic algorithm and neural networks to classify Peer-to-Peer (P2P) traffic in IP networks. We first compute the minimum classification error (MCE) matrix using genetic algorithm. The MCE matrix is then used during the pre-processing step to map the original dataset into a new space. The mapped data set is then fed to three different classifiers: distance-based, K-Nearest Neighbors, and neural networks classifiers. We measure three different indexes, namely mutual information, Dunn, and SD to evaluate the extent of separation of the data points before and after mapping is performed. The experimental results demonstrate that with the proposed mapping scheme we achieve, on average, 8% higher accuracy in classification of the P2P traffic compare to the previous solutions. Moreover, the genetic-based MCE matrix increases the classification accuracy more than what the basic MCE does.     

A non-reference image fusion metric based on mutual information of image features

The widespread usage of image fusion causes an increase in the importance of assessing the performance of different fusion algorithms. The problem of introducing a suitable quality measure for image fusion lies in the difficulty of defining an ideal fused image. In this paper, we propose a non-reference objective image fusion metric based on mutual information which calculates the amount of information conducted from the source images to the fused image. The considered information is represented by image features like gradients or edges, which are often in the form of two-dimensional signals. In this paper, a method of estimating the joint probability distribution from marginal distributions is also presented which is employed in calculation of mutual information. The proposed method is compared with the most popular existing algorithms. Various experiments, performed on several databases, certify the efficiency of our proposed method which is more consistent with the subjective criteria.     

An adaptive learning automata-based ranking function discovery algorithm

Due to the massive amount of heterogeneous information on the web, insufficient and vague user queries, and use of the same query by different users for different aims, the information retrieval process deals with a huge amount of uncertainty and doubt. Under such circumstances, designing an efficient retrieval function and ranking algorithm by which the most relevant results are provided is of the greatest importance. In this paper, a learning automata-based ranking function discovery algorithm in which different sources of information are combined is proposed. In this method, the learning automaton is used to adjust the portion of the final ranking that is assigned to each source of evidence based on the user feedback. All sources of information are first given the same importance. The proportion of a given source increases, if the documents provided by this source are reviewed by the user and decreases otherwise. As the proposed algorithm proceeds, the probability of appearance of each source in the final ranking gets proportional to its relevance to the user queries. Several simulation experiments are conducted on well-known data collections and query types to show the performance of the proposed algorithm. The obtained results demonstrate that the proposed algorithm outperforms several existing methods in terms of precision at position n, mean average precision, and normalized discount cumulative gain.     

Sensing and identification of carbon monoxide using carbon films fabricated by methane arc discharge decomposition technique

Carbonaceous materials have recently received attention in electronic applications and measurement systems. In this work, we demonstrate the electrical behavior of carbon films fabricated by methane arc discharge decomposition technique. The current-voltage (I-V) characteristics of carbon films are investigated in the presence and absence of gas. The experiment reveals that the current passing through the carbon films increases when the concentration of CO₂ gas is increased from 200 to 800 ppm. This phenomenon which is a result of conductance changes can be employed in sensing applications such as gas sensors.     

Bi-objective optimization approaches to many-to-many hub location routing with distance balancing and hard time window

Neural Computing and Applications - This study addresses a many-to-many hub location-routing problem where the best-found locations of hubs and the best-found tours for each hub are determined with...     

Quantitative characterization of carrier injection across metal–organic interfaces using Bardeen theory

We have investigated the contact between a metal and an organic/polymeric (o/p) material and we have introduced a relation for carrier injection using Bardeen theory. A series of narrow barriers is considered in the semiconductor side to account for the localized nature of the carriers in the o/p material. As an application of the model, we have calculated the hopping rate of carriers in terms of the contact parameters. Also, we have discussed the hopping of carriers deep into the organic dielectric. Finally, we have explored the hopping rate in practical contacts between polyfluorene-based polymers and different electrodes.