Red/near‐infrared (NIR) fluorescent molecules with aggregation‐induced emission (AIE) characteristics are of great interest in bioimaging and therapeutic applications. However, their complicated synthetic approaches remain the major barrier to implementing these applications. Herein, a one‐pot synthetic strategy to prepare a series of red/NIR‐emissive AIE luminogens (AIEgens) by fine‐tuning their molecular structures and substituents is reported. The obtained AIEgens possess simple structures, good solubilities, large Stokes shifts, and bright emissions, which enable their applications toward in vitro and in vivo imaging without any pre‐encapsulation or ‐modification steps. Excellent targeting specificities to lipid droplets (LDs), remarkable photostabilities, high brightness, and low working concentrations in cell imaging application make them remarkably impressive and superior to commercially available LD‐specific dyes. Interestingly, these AIEgens can efficiently generate reactive oxygen species upon visible light irradiation, endowing their effective application for photodynamic ablation of cancer cells. This study, thus, not only demonstrates a facile synthesis of red/NIR AIEgens for dual applications in simultaneous imaging and therapy, but also offers an ideal architecture for the construction of AIEgens with long emission wavelengths. 相似文献
A 1-V CMOS frequency synthesizer is proposed for wireless local area network 802.11a transceivers using a novel transformer-feedback voltage-controlled oscillator (VCO) for low voltage and a stacked frequency divider for low power. Implemented in a 0.18-mum CMOS process and operated at 1-V supply, the VCO measures a phase noise of -140.5 dBc at an offset of 20 MHz with a center frequency of 4.26 GHz and a power consumption of 5.17 mW. Its tuning range is as wide as 920 MHz (23%). By integrating the VCO into a frequency synthesizer, a phase noise of -140.1 dBc/Hz at an offset of 20 MHz is measured at a center frequency of 4.26 GHz. Its output frequency can be changed from 4.112 to 4.352 GHz by switching the 3-bit modulus of the programmable divider. The synthesizer consumes only 9.7 mW and occupies a chip area of 1.28 mm2. 相似文献
Smart cities are built upon information and communication technologies (ICTs) to enable a broad range of advanced services. Through a comprehensive literature review, this study identified four pitfalls brought by the pervasive application of ICT, including information insecurity, privacy leakage, information islands, and digital divide. Therefore, a questionnaire survey together with 27 interviews was conducted in Hong Kong to investigate how the public perceived these pitfalls within the context of mobile apps providing real-time parking information which form a major part of smart mobility. System insecurity and privacy leakage were found to arouse worries among the app-users while their awareness of protecting personal data was found to have room for improvement. Islands of real-time parking information occur as a result of the lack of collaboration among private carpark operators. Digital divide existed widely among the disadvantaged groups and the problem cannot be solved by mere provision of ICT facilities. Overall, technologies alone cannot make a city smart or smarter. It is the suitable way in which ICTs are used to serve all citizens that matters. 相似文献
In this letter, the joint probability density function (pdf) of the order statistics for a set of correlated Nakagami-m fading channels is derived. This result is useful in analyzing the performance of a variety of diversity schemes which involve branch selection. The derivation also yields a computationally efficient method for obtaining the marginal pdf of the p-th order statistic for a set of correlated Nakagami-m fading channels. 相似文献
Recently, research interest has increased in the design, development, and deployment of mobile agent systems for high-level inference and surveillance in a wireless sensor network (WSN). Mobile agent systems employ migrating codes to facilitate flexible application re-tasking, local processing, and collaborative signal and information processing. This provides extra flexibility, as well as new capabilities to WSNs in contrast to the conventional WSN operations based on the client-server computing model. In this article we survey the potential applications of mobile agents in WSNs and discuss the key design issues for such applications. We decompose the agent design functionality into four components, that is, architecture, itinerary planning, middleware system design, and agent cooperation. This taxonomy covers low-level to high-level design issues and facilitates the creation of a component-based and efficient mobile agent system for a wide range of applications. With a different realization for each design component, it is expected that flexible trade-offs (e.g., between energy and delay) can be achieved according to specific application requirements. 相似文献
It is often difficult to obtain sufficient signature samples to train up a signature verification system. An elastic matching method to generate additional samples is proposed to expand the limited training set so that a better estimate of the statistical variations can be obtained. The method differs from existing ones in that it is more suitable for the generation of signature samples. Besides this, a set of peripheral features, which is useful in describing both the internal and external structures of signatures, is employed to represent the signatures in the verification process. Results showed that the additional samples generated by the proposed method could reduce the error rate from 15.6% to 11.4%. It also outperformed another existing method which estimates the class covariance matrix through optimisation techniques. Results also demonstrated that the peripheral features are useful for signature verification. 相似文献
Investigation of a high frequency unsaturated ring oscillator with cross coupled load is presented, and oscillation frequency compared with multi-path high frequency ring oscillators. Stability of oscillation is shown heuristically, via geometric argument on a phase plane, where the presence of negative impedance in the cross coupled pair of the delay cell is deemed important. Oscillation frequency formula is presented, and design insight given. In addition, a novel design methodology on lowering its phase noise is developed. Simulations on example circuit designs using 0.18???m CMOS technology demonstrate the higher frequency obtained, oscillation stability, frequency formula and design insight, as well as phase noise methodology. 相似文献
Both non-orthogonal multiple access (NOMA) and ultra-dense network (UDN) are promising technologies in future wireless networks. However, considering the overlapped coverage of small base stations (SBSs) and the spectrum sharing with NOMA, interference management (IM) becomes a more complex and fundamental problem. Moreover, considering the massive SBSs and dynamic network conditions in UDN, more efficient mechanisms need to be designed to deal with the IM issue. Thus, we propose a distributed self-optimizing interference management approach to address both the intra-cell interference caused by NOMA and the inter-cell interference among dense deployed SBSs. Aiming to minimize the interference and guarantee the users’ requirements, we mathematically formulate the joint resource allocation and user selection problem with consideration of the diverse user requirements, complicated interference topology, and limited resources. Furthermore, we consider the imperfections of successive interference cancellation at receivers for separating and decoding superimposed signals and analyze the impacts of residual interference and outage probability in NOMA-based UDNs. For tractability purpose, we introduce interference graph and satisfaction game theory and propose distributed algorithms to solve the problem. Simulation results show that interference can be reduced significantly in UDNs with NOMA compared with the traditional IM approaches.
A second-order sigma-delta modulator with a 3-b internal quantizer employing the individual level averaging technique has been designed and implemented in a 1.2 μm CMOS technology. Testing results show no observable harmonic distortion components above the noise floor. Peak S/(N+D) ratio of 91 dB and dynamic range of 96 dB have been achieved at a clock rate of 2.56 MHz for a 20 kHz baseband. No tone is observed in the baseband as the amplitude of a 10 kHz input sine wave is reduced from -0.5 dB to -107 dB below the voltage reference. The active area of the prototype chip is 3.1 mm2 and it dissipates 67.5 mW of power from a 5 V supply 相似文献
Hard ferromagnetic (L10 phase) FePt alloy nanoparticles (NPs) with extremely high magnetocrystalline anisotropy are considered to be one of the most promising candidates for the next generation of ultrahigh‐density data storage system. The question of how to generate ordered patterns of L10‐FePt NPs and how to transform the technology for practical applications represents a key current challenge. Here the direct synthesis of L10 phase FePt NPs by pyrolysis of Fe‐containing and Pt‐containing metallopolymer blend without post‐annealing treatment is reported. Rapid single‐step fabrication of large‐area nanodot arrays (periodicity of 500 nm) of L10‐ordered FePt NPs can also be achieved by employing the metallopolymer blend, which possesses excellent solubility in most organic solvents and good solution processability, as the precursor through nanoimprint lithography (NIL). Magnetic force microscopy (MFM) imaging of the nanodot pattern indicates that the patterned L10 phase FePt NPs are capable of exhibiting decent magnetic response, which suggests a great potential to be utilized directly in the fabrication of bit patterned media (BPM) for the next generation of magnetic recording technology. 相似文献