Initial stages of tin electrodeposition from sulfate baths in the presence of gluconate

Tin electrodeposition in its initial stages in acid sulfate/gluconate baths was studied with varying tin and gluconate concentrations using potential-controlled electrochemical techniques. The deposit morphology was observed by scanning electron microscopy (SEM). A comparison with tin electrodeposition from acid sulfate baths in the absence of gluconate was also carried out. Use of a highly acidic bath leads to nonuniform deposits, even in the presence of gluconate; at pH 4 deposits are uniform, brilliant and suitable for finishing applications. Tin crystallites have a well defined morphology which depends on bath agitation conditions. In the absence of agitation, the crystallites have the same tetragonal shape as in a sulfate bath without gluconate.     

Informational Entropy: a Failure Tolerance and Reliability Surrogate for Water Distribution Networks

Evolutionary algorithms are used widely in optimization studies on water distribution networks. The optimization algorithms use simulation models that analyse the networks under various operating conditions. The solution process typically involves cost minimization along with reliability constraints that ensure reasonably satisfactory performance under abnormal operating conditions also. Flow entropy has been employed previously as a surrogate reliability measure. While a body of work exists for a single operating condition under steady state conditions, the effectiveness of flow entropy for systems with multiple operating conditions has received very little attention. This paper describes a multi-objective genetic algorithm that maximizes the flow entropy under multiple operating conditions for any given network. The new methodology proposed is consistent with the maximum entropy formalism that requires active consideration of all the relevant information. Furthermore, an alternative but equivalent flow entropy model that emphasizes the relative uniformity of the nodal demands is described. The flow entropy of water distribution networks under multiple operating conditions is discussed with reference to the joint entropy of multiple probability spaces, which provides the theoretical foundation for the optimization methodology proposed. Besides the rationale, results are included that show that the most robust or failure-tolerant solutions are achieved by maximizing the sum of the entropies.     

Hydrodynamic characteristics of a FCC regenerator

The hydrodynamic and gas mixing characteristics have been determined in a FCC regenerator (0.48 m I.D.x3.4 m high) with FCC particles. Solids holdup in the dense bed decreases with increasing gas velocity, but it increases in the freeboard region. The bubble/void fraction increases with an increase along the bed height at a given gas velocity and increases with increasing gas velocity at a constant bed height. Backmixed tracer gas at the wall region is higher than that at the center region of the bed. The gas backmixing coefficient decreases with increasing gas velocity.     

Polymerization of 2-phenyl-aziridine

Summary The ring-opening polymerization of 2-phenyl aziridine was studied with several catalyst systems: boron trifluoride etherate, chlorhydric acid, perchloric acid, dimethyl sulfate and methyl triflate. The corresponding polyamine was obtained as a pale yellow solid with a number average molecular weight around 2,000–3,000.A kinetic study is discussed in the case of perchloric acid and methyl triflate.     

Performance evaluation of anti-radiation based on the gamma degradation process

In the environment of space radiation, the high-energy charged particles or high-energy photons acting on a spacecraft can cause either temporary device degradation or permanent failure. The traditional probability model is difficult to obtain reliable estimation of unit radiation resistance performance with small samples. Considering that different products will change differently after high-energy particle radiation, we construct a model based on the gamma degradation process. This model can efficiently describe the law of unit radiation resistance variation with the total radiation dose levels under the effect of the total dose and displacement damage. Finally, the proposed model is used to assess the anti-radiation performance of the N-channel power MOSFET device STRH60N20FSY3 produced by STM to obtain average unit radiation resistance, survival probability, survival function, etc.     

Theoretical Investigation of the Viscous Damping Coefficient of Hydraulic Actuators

The viscous damping coefficient(VDC) of hydraulic actuators is crucial for system modeling,control and dynamic characteristic analysis.Currently,the researches on hydraulic actuators focus on behavior assessment,promotion of control performance and efficiency.However,the estimation of the VDC is difficult due to a lack of study.Firstly,using two types of hydraulic cylinders,behaviors of the VDC are experimentally examined with velocities and pressure variations.For the tested plunger type hydraulic cylinder,the exponential model B=αυ~(-β),(α0,β0)or B=α_1e~(-β_1υ)+α_2e~(-β_2υ)(α_1,α_20,β_1,β_20),fits the relation between the VDC and velocities for a given pressure of chamber with high precision.The magnitude of the VDC decreases almost linearly under certain velocities when increasing the chamber pressure from 0.6 MPa to 6.0 MPa.Furthermore,the effects of the chamber pressures on the VDC of piston and plunge type hydraulic cylinders are different due to different sealing types.In order to investigate the VDC of a plunger type hydraulic actuator drastically,a steady-state numerical model has been developed to describe the mechanism incorporating tandem seal lubrication,back-up ring related friction behaviors and shear stress of fluid.It is shown that the simulated results of VDC agree with the measured results with a good accuracy.The proposed method provides an instruction to predict the VDC in system modeling and analysis.     

Image inpainting algorithm based on TV model and evolutionary algorithm

With the development of modern image processing techniques, the numbers of images increase at a high speed in network. As a new form of visual communication, image is widely used in network transmission. However, the image information would be lost after transmission. In view of this, we are motivated to restore the image to make it complete in an effective and efficient way in order to save the network bandwidth. At present, there are two main methods for digital image restoration, texture-based method and non-textured-based method. In the texture-based method, Criminisi algorithm is a widely used algorithm. However, the inaccurate completion order and the inefficiency in searching matching patches are two main limitations of Criminisi algorithm. To overcome these shortcomings, in this paper, an exemplar image completion based on evolutionary algorithm is proposed. In the non-textured-based method, total variation method is a typical algorithm. An improved total variation algorithm is proposed in this paper. In the improved algorithm, the diffusion coefficients are defined according to the distance and direction between the damaged pixel and its neighborhood pixel. Experimental results show that the proposed algorithms have better general performance in image completion. And these two new algorithms could improve the experience of network surfing and reduce the network communication cost.     

A Model of Green Acceptance and Intentions to Use Bike-Sharing: YouBike Users in Taiwan

With the emphasis on sustainability in transportation, bike-sharing systems are gaining popularity. This paper investigates the attitudes of users of a bike-sharing system with the aim of identifying their priorities, thus allowing local governments to focus their efforts most effectively on enhancing users’ intentions to use such systems. The relationships among green perceived usefulness (the extent to which individuals believe that a bike-sharing system will improve the environmental performance of some part of their life within a specific context), user attitude and perceived ease of use with green intentions, and the mediation effect of user attitude towards bike-sharing are explored. The focus of the study is on how to enhance green intentions via perceived usefulness, perceived ease of use and user attitude of the green technology acceptance model (green TAM) (Davis 1989). The two-step approach of structural equation modeling was applied to analyze the empirical results, which indicated that green perceived usefulness and user attitude have positive influences on the green intentions of 262 users and 262 non-users from ten sampled bike-sharing sites around the central administrative districts of Taipei. However, user attitude has the highest mediation effect on green intentions, and perceived ease of use does not have a significant effect on intentions for either users or non-users. Therefore, governmental institutions can strive to improve the attitudes of bike-sharing users and non-users, their green perceived usefulness, and perceived ease of use to strengthen their intentions to use this mode of sustainable transportation.