全文获取类型
收费全文 | 489篇 |
免费 | 33篇 |
专业分类
电工技术 | 1篇 |
化学工业 | 161篇 |
金属工艺 | 11篇 |
机械仪表 | 4篇 |
建筑科学 | 11篇 |
能源动力 | 10篇 |
轻工业 | 143篇 |
水利工程 | 6篇 |
石油天然气 | 8篇 |
无线电 | 20篇 |
一般工业技术 | 59篇 |
冶金工业 | 34篇 |
原子能技术 | 2篇 |
自动化技术 | 52篇 |
出版年
2023年 | 5篇 |
2022年 | 12篇 |
2021年 | 22篇 |
2020年 | 8篇 |
2019年 | 21篇 |
2018年 | 10篇 |
2017年 | 14篇 |
2016年 | 18篇 |
2015年 | 17篇 |
2014年 | 15篇 |
2013年 | 41篇 |
2012年 | 33篇 |
2011年 | 36篇 |
2010年 | 23篇 |
2009年 | 25篇 |
2008年 | 25篇 |
2007年 | 28篇 |
2006年 | 15篇 |
2005年 | 18篇 |
2004年 | 13篇 |
2003年 | 11篇 |
2002年 | 11篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 8篇 |
1998年 | 11篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 12篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1974年 | 1篇 |
1972年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有522条查询结果,搜索用时 109 毫秒
41.
42.
Jose García-Torres Elvira Gómez Elisa Vallés 《Journal of Applied Electrochemistry》2009,39(2):233-240
Cobalt electrodeposits were prepared from an electrolytic bath containing cobalt perchlorate. The effect of different species,
organic (thiourea and sodium gluconate) and inorganic (boric acid), on the crystallographic structure, morphology, magnetic
properties and electrochemical behaviour of cobalt electrodeposits was investigated. Amorphous cobalt, hcp cobalt and a non-usual
primitive cubic cobalt phase were observed depending on the bath composition. Depending on the structure, different morphologies
and magnetic properties were found. Coercivity values of the cobalt coatings ranged from around 15 Oe for amorphous, nodular
deposits to 380 Oe for cobalt coatings showing acicular morphology and hcp structure with a (002) preferred orientation. Knowledge
of the influence of the species on the properties of cobalt makes it possible to obtain tailored cobalt films. 相似文献
43.
Ivano Camoni Riccardo Fabbrini Leonello Attias Alfonso Di Muccio Elvira Cecere Antonio Consolino Francesca Roberti 《Food Additives & Contaminants》2001,18(10):932-936
In 1997 the Italian monitoring programme for pesticide residues in food comprised 7951 samples of 152 different foods for which a total of 275 pesticides were analysed. For 90 pesticides, the National Estimated Daily Intakes (NEDIs) were calculated by using the 90th percentile value and the food consumption data for the general Italian population. The calculated NEDIs were found to represent only a small portion of the respective Acceptable Daily Intake (ADI). 相似文献
44.
Stefania Vichi Montserrat Riu-Aumatell Mercé Mora-Pons Josep M. Guadayol Susana Buxaderas Elvira López-Tamames 《Food chemistry》2007,105(4):1748-1754
HS-SPME coupled to GC/MS was applied to the analysis of the volatile fraction of Juniperus communis L. berries, which are the principal ingredient used for gin aromatization. Seventy seven compounds were identified by comparison with reference compounds or tentatively identified by comparing their mass spectra and retention index with those reported in mass spectra libraries and literature, respectively. Seventy four were detected by SPME and sixty eight were detected by solvent distillation extraction (SDE). These were mainly mono- and sesquiterpenic compounds that represented more than the 80% of the gin’s volatile composition. A high percent content was due to monoterpenoids, whose analysis could be important for the assessment of sensory quality control of juniper due to their impact on gin aroma. The main monoterpenoids detected in the headspace of the juniper berries from two periods of collection were terpinen-4-ol, p-cymene, β-myrcene, γ-terpinene, α-pinene and limonene. These represented more than the 70% of the sample’s volatile fraction. The proposed SPME method required short times and the low cost of analysis and enabled to detect a number of compounds comparable with SDE or much higher than the number of compounds reported by other extraction techniques. The results suggested the suitability of this technique for the assessment of the volatile composition of juniper berries intended for gin flavouring. 相似文献
45.
Electrodeposition of Co-Ni and Co-Ni-Cu alloys was performed in a sulphate-citrate medium. Experimental electrodeposition parameters (pH, cobalt(II), nickel(II) and citrate concentrations) were varied in order to analyse their influence on the deposition. Anomalous Co-Ni codeposition occured in the citrate medium. High [Ni(II)]/[Co(II)] ratios (above 5) were suitable for the preparation of homogeneous magnetic Co-rich Co-Ni deposits of hexagonal close-packed (hcp) structure or face centred cubic (fcc) structure as a function of the deposition potential.The presence of very low copper(II) concentrations (<10−2 mol dm−3) in the nickel-cobalt bath makes it possible to incorporate copper in the deposits in amounts ranging from 5 to 60% Cu, although uniform deposits are obtained only for low copper percentages. These ternary deposits are solid solutions with fcc structure and magnetic behaviour both dependent on the deposition potential. 相似文献
46.
P.D Sanz L Otero C de Elvira J.A Carrasco 《International Journal of Refrigeration》1997,20(5):301-307
Experimental freezing of water in high-pressure domain is studied considering temperature reduction (TRF) as well as high-pressure-assisted freezing (HPAF). The most important advantage of HPAF is that the whole volume of the sample is subcooled when an expansion is made, so a rapid and uniform nucleation and growth of ice crystals are produced. In this work through mathematical modelling the amount of ice appearing instantaneously in the latter freezing, is predicted. 相似文献
47.
48.
49.
Cerium oxide thin films obtained by cathodic electrodeposition on 2024 aluminium alloy have been studied. The coatings, obtained with electrochemical deposition, offer an effective corrosion protection and require a lower deposition time when compared to chemical conversion coatings. The coatings were obtained at room temperature by deposition from CeCl3/H2O2 aqueous solutions and the influence of several parameters (CeCl3 concentration, H2O2 concentration, deposition time, current intensity) on the corrosion resistance was studied. The composition, morphology and microstructure of the films have been characterized by SEM, XPS and AFM. The corrosion resistance was investigated through potentiodynamic tests in 3% NaCl solution. 相似文献
50.
Hope Badawy Jér?me Brunellière Marina Veryaskina Guillaume Brotons Sophie Sablé Isabelle Lanneluc Kelly Lambert Pascal Marmey Amy Milsted Teresa Cutright Arnaud Nourry Jean-Luc Mouget Pamela Pasetto 《International journal of molecular sciences》2015,16(3):4392-4415
There has been an intense research effort in the last decades in the field of biofouling prevention as it concerns many aspects of everyday life and causes problems to devices, the environment, and human health. Many different antifouling and antimicrobial materials have been developed to struggle against bacteria and other micro- and macro-organism attachment to different surfaces. However the “miracle solution” has still to be found. The research presented here concerns the synthesis of bio-based polymeric materials and the biological tests that showed their antifouling and, at the same time, antibacterial activity. The raw material used for the coating synthesis was natural rubber. The polyisoprene chains were fragmented to obtain oligomers, which had reactive chemical groups at their chain ends, therefore they could be modified to insert polymerizable and biocidal groups. Films were obtained by radical photopolymerization of the natural rubber derived oligomers and their structure was altered, in order to understand the mechanism of attachment inhibition and to increase the efficiency of the anti-biofouling action. The adhesion of three species of pathogenic bacteria and six strains of marine bacteria was studied. The coatings were able to inhibit bacterial attachment by contact, as it was verified that no detectable leaching of toxic molecules occurred. 相似文献