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61.
Micro‐ and nanoscale structures of mesiodens dentin: Combined study of FTIR and SAXS/WAXS techniques
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Ozlem Marti Akgun Sevgi Haman Bayari Semra Ide Günseli Guven Polat Ilghar Orujalipoor 《Microscopy research and technique》2015,78(1):52-58
A mesiodens is the most common type of supernumerary tooth present in conjunction to normal dentition. A mesiodens may commonly occur in the central region of the upper or lower jaw. A mesiodens is different from normal teeth in terms of structure and shape. The aim of this study is to evaluate the micro‐ and nanoscale structural properties of mesiodens dentin by combined small‐ and wide‐angle X‐ray scattering (SAXS/WAXS) and Fourier transform infrared (FTIR) spectroscopy. Five freshly extracted, noncarious mesiodens and five normal dentin disks prepared from human incisor teeth were compared. Using FTIR, the phosphate‐to‐amide I, carbonate‐to‐phosphate, and carbonate‐to‐amide I band area ratios and the crystallinity index were quantified. SAXS/WAXS were used to study the nanostructure of mesiodens. An increase in the mineral content in the mesiodens dentin with respect to the normal group was found. Crystallinity was also significantly increased and the protein content decreased in the mesiodens dentin compared with that of normal dentin. SAXS/WAXS results revealed that mesiodens dentin has a more calcified tissue. Further, SAXS analysis revealed a nonuniform distribution of dentin fibrils in mesiodens. Microsc. Res. Tech., 78:52–58, 2015. © 2014 Wiley Periodicals, Inc. 相似文献
62.
Huseyin Cankaya Reyhane Kilci Alphan Sennaroglu Emel Yilgor Iskender Yilgor 《应用聚合物科学杂志》2010,117(1):378-383
Novel, polymeric UV‐to‐visible converters were prepared by doping elastomeric poly(ether‐urethaneurea) copolymers with 5–25% by weight of ErCl3 6H2O, corresponding to Er3+ concentrations of 2.19 to 10.86% by weight. When excited in the UV at 355 nm, the doped films generated a very broad, continuous visible luminescence between 400 and 750 nm. Preparation and spectroscopic characterization of the samples are discussed in detail. The color coordinates, color temperature, color rendering index of the samples, and the degree of overlap of their emission bands with the spectral response of the eye were determined. The color rendering index of samples is in the 57–70 range. The sample containing 2.19% by weight of Er3+ was found to give the color coordinates closest to the white‐source region and the highest color rendering index. The color temperatures of the samples were in the 5093–5540 K range. Overlap between the emission bands and the spectral response of the eye improved with increasing erbium concentration. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
63.
Emel Kuram Babur Ozcelik Faruk Yilmaz Gokhan Timur Zeynep Munteha Sahin 《Polymer Composites》2014,35(10):2074-2084
The recycling possibilities of poly(butylene terephthalate)/polycarbonate/acrylonitrile–butadiene–styrene (PBT/PC/ABS) ternary blend with and without glass‐fiber content were investigated using repeated injection molding process. In this study, PBT/PC/ABS ternary blends were reprocessed at five times and the results were presented after each recycling process. The recycling possibility of PBT/PC/ABS ternary blend was evaluated by measuring the mechanical, chemical, thermal, and rheological properties. Mechanical properties were determined by the tensile strength, yield strength, strain at break, elastic modulus, impact strength, flexural strength, and flexural modulus. Chemical and thermal properties were evaluated by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermal gravimetric analysis, and scanning electron microscopy. Rheological properties of the ternary blends were studied by melt flow index measurement. From the results, it was found that mechanical properties of recycled composites were better than virgin PBT/PC/ABS ternary blends. POLYM. COMPOS., 35:2074–2084, 2014. © 2014 Society of Plastics Engineers 相似文献
64.
The exchange of hydrogen ions for trivalent chromium species with strongly acidic exchange resins has been investigated. The experiments comprised of systems with chromium chloride and basic chromium sulphate which are applied in leather tanning. Exchange equilibria at ambient temperature were investigated as a function of pH and total chromium concentration. Exchange strongly depends on the speciation in each system. As can be expected, with chromium chloride solutions a strong preference of chromium species occurs. However, a complete pattern is found for systems with basic chromium sulphate where chromium species are not fully preferred. 相似文献
65.
İlknur Demiral Sevgi Sensöz 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2013,35(12):1159-1168
Fixed-bed pyrolysis biooils of hazelnut (Corylus Avellana L.) bagasse have been identified for their structures. The condensed biooils were analyzed for their properties as fuels and compared with petroleum-derived products. The biooil was analyzed by Fourier Transform infrared spectroscopy (FTIR) and 1H-NMR spectra. The biooils were fractionated into pentane solubles and insolubles. Pentane solubles were then solvent fractionated into pentane, toluene and methanol subfractions by fractionated column chromatograpy. The aliphatic subfractions of the biooils were then analyzed by capillary column gas-liquid chromatography (GC). In addition, the physical properties, higher heating value and elemental analysis of the biooil were determined. The empirical formula of biooil that has a heating value of 34.57 MJ/kg was established as CH1.45O0.33N0.127. Chromatographic and spectroscopic studies on the biooil showed that the oil obtained from hazelnut bagasse could be used as a renewable fuel and chemical feedstock. 相似文献
66.
Fine-grained ceramics (with a grain size on the order of a micron) have been produced by the spark plasma sintering (SPS) of various alumina nanopowders. We have compared the microhardness of ceramic samples prepared from 11 alumina nanopowders and that of composites based on such powders. The ceramics have been prepared by both SPS and a conventional technique (sequential pressing and sintering). We examine the effect of the phase composition and average particle size of the starting nanopowder on the microhardness of the ceramics. 相似文献
67.
V. I. Melik-Gaikazyan V. M. Emel’yanov N. P. Emel’yanova A. A. Moiseev V. V. Emel’yanov T. I. Yushina 《Russian Journal of Non-Ferrous Metals》2011,52(6):463-468
The influence of the capillary pressure P
ca of gas in microbubbles on bubble spread over a substrate (particle) after adhesion is considered (for bubbles ranging in
size from 2 mm to 20 nm). The dimensionless parameter K
a characterizes the microbubble spread with decrease in the bubble form factor β by no more than 0.000001 of its initial value.
There is a clear symbatic relation between P
ca and K
a. The microbubble begins to spread when it measures 200 μm; its motion increases markedly as it becomes smaller. With decrease
in bubble size, the rock and slurry particles adhering to its surface are removed. Of course, this enhances the foam quality. 相似文献
68.
L. B. Boinovich A. M. Emel’yanenko 《Protection of Metals and Physical Chemistry of Surfaces》2010,46(4):403-410
A general thermodynamic approach is presented towards a triple point shift in arbitrary spatially limited systems with a curvilinear
interface, including interfacial phases, small particles, and matter in pores. The suggested approach is based on using the
coupling equations for vapor pressure over the bulk and spatially limited media together with the Clausius-Clapeyron relationships,
and allows one to explain the effect of different physical-chemical parameters on the value and sign of the shift in the phase
transition temperature. Besides, an explanation was offered within the developed theory for the difference in the melting
points of different crystal faces, the presence of a nanometer melt layer for the substance in fine pores, and the formation
of premolten or presolidified shell about nanoparticles. 相似文献
69.
70.
A UV-curable acrylated urethane prepolymer was synthesized from tolylene-2,4-diisocyanate (TDI), a polyether polyol (Arcol 1131) and endcapped with 2-hydroxyethyl methacrylate (HEMA) by addition reaction in the presence of dibutyltin dilaurate as catalyst. UV curing was performed with either diethylene glycol diacrylate or thiodiethylene glycol diacrylate as reactive diluent. The effects of reactive diluent types, their concentrations and the humidity of environment on mechanical properties of cured films were investigated. Changes in the tensile strength, elongation and Young's modulus values of the cured films upon addition of reactive diluents with different concentrations were related to the effect of the diluent on the crosslinking density of cured films. The increase of relative humidity from 50 to 95% caused a decrease of tensile strength and Young's modulus values of cured films. It is proposed that the decrease of these physical properties in high relative humidity is due to the formation of hydrogen bonding in polymer chains caused by water molecules. 相似文献