Finite frequency H∞ control of singularly perturbed Euler‐Lagrange systems: An artificial delay approach

In this paper, we show that small artificial delays in the feedback loops operating in different time scales may stabilize singularly perturbed systems (SPSs). An artificial delay approach is proposed for the robust stabilization and L₂‐gain analysis of SPSs in the finite frequency domain. A two‐time‐scale delayed static output feedback controller is designed, in which the controller gains are formulated via a linear matrix inequality (LMI) algorithm. A distinctive feature of the proposed algorithm is setting controller parameters as free variables, which increases the degrees of freedom in controller design and leads to more flexibility in solving LMIs. Moreover, the proposed method is further extended to analyze the finite frequency system specifications of SPSs. The L₂‐gain performance analysis is conducted for parameter‐independent subsystems in their dominant frequency ranges, and the disturbance attenuation level of the original high‐order system is then estimated. Finally, the efficiency of the proposed design method is verified in an active suspension system subject to multiple finite frequency disturbance.     

A DMA study of the interfacial changes on injection‐molded iPP/mica composites modified by a p‐phenylen‐bis‐maleamic acid grafted atactic polypropylene

Present work concerns to the study of the dynamic mechanical and thermal responses of selected polypropylene (iPP)/mica composites with a modified interface from the matrix side by using a p‐phenylen‐bis‐maleamic acid grafted atactic polypropylene, coming from a byproduct of industrial polymerization reactors. Thus, the study is mainly focused on the 75/25 iPP/mica ratio since it was identified in previous works as providing the maximum inter mica particle distance to assure they should participate in the overall process of dissipation of the mechanical energy supplied to the composites. Hence, the present dynamic mechanical analysis discussion tries to correlate the damping responses of the injection‐molded composites with those previously obtained but over compression molded composites as the basis of further studies all along the compositional iPP/mica map. Therefore, the latter let us, on the one hand, to follow how the main values of the different dynamic mechanical analysis parameters vary because of the interfacial modifier presence, and on the other, to develop a robust correlation between them and the corresponding macroscopic mechanical parameters. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45366.     

Case study of the impact of toecap type on the microclimate in protective footwear

Protective footwear plays a critical role in work effectiveness and personal safety. It exhibits special properties due to the use of protective elements and materials, but these components may deteriorate its hygienic characteristics. This paper presents a study on the influence of toecap type on the microclimate in protective footwear (ankle boots). Toecaps made of metal and of a composite polymer material were evaluated. Changes in the footwear microclimate were monitored using a thermal foot model at a perspiration rate of about 5 g/h with and without the simulated movement function. The influence of the toecap material on the microclimate in the footwear was analyzed statistically. Under conditions of simulated movement, higher temperature and relative humidity values (about 32 °C and 90%) were recorded in the toe region of ankle boots with metal toecaps as compared to composite polymer toecaps (about 29 °C and 53%, respectively). These results suggest that protective footwear with composite toecaps ensures better ventilation of the foot during work.     

Pooled versus separate measurements of tree-ring stable isotopes

δ¹³C and δ¹⁸O of tree rings contain time integrated information about the environmental conditions weighted by seasonal growth dynamics and are well established as sources of palaeoclimatic and ecophysiological data. Annually resolved isotope chronologies are frequently produced by pooling dated growth rings from several trees prior to the isotopic analyses. This procedure has the advantage of saving time and resources, but precludes from defining the isotopic error or statistical uncertainty related to the inter-tree variability. Up to now only a few studies have compared isotope series from pooled tree rings with isotopic measurements from individual trees. We tested whether or not the δ¹³C and the δ¹⁸O chronologies derived from pooled and from individual tree rings display significant differences at two locations from the Iberian Peninsula to assess advantages and constraints of both methodologies. The comparisons along the period 1900-2003 reveal a good agreement between pooled chronologies and the two mean master series which were created by averaging raw individual values (Mean) or by generating a mass calibrated mean (MassC). In most of the cases, pooled chronologies show high synchronicity with averaged individual samples at interannual scale but some differences also show up especially when comparing δ¹⁸O decadal to multi-decadal variations. Moreover, differences in the first order autocorrelation among individuals may be obscured by pooling strategies. The lack of replication of pooled chronologies prevents detection of a bias due to a higher mass contribution of one sample but uncertainties associated with the analytical process itself, as sample inhomogeneity, seems to account for the observed differences.     

Electrochemical performance of carbon gels with variable surface chemistry and physics

This study describes the electrochemical characterization of N-doped carbon xerogels in the form of microspheres and of carbon aerogels with varied porosities and surface oxygen complexes. The interfacial capacitance of N-doped carbon xerogels decreased with increased micropore surface area as determined by N₂ adsorption at ?196 °C. The interfacial capacitance showed a good correlation with the areal N_XPS concentration, and the best correlation with the areal concentration of pyrrolic or pyridonic nitrogen functionalities. The gravimetric capacitance decreased with greater xerogel microsphere diameter. The interfacial capacitance of carbon aerogels increased with higher percentage of porosity as determined from particle and true densities. The interfacial capacitance showed a linear relationship with the areal oxygen concentration and with the areal concentrations of CO- and CO₂-evolving groups.     

The photoreceptive cells of the pineal gland in adult zebrafish (Danio rerio)

The zebrafish pineal gland plays a fundamental role in the regulation of the circadian rhythm through the melatonin secretion. The pinealocytes, also called photoreceptive cells, are considered the morphofunctional unit of pineal gland. In literature, the anatomical features, the cellular characteristics, and the pinealocytes morphology of zebrafish pineal gland have not been previously described in detail. Therefore, this study was undertaken to analyze the structure and ultrastructure, as well as the immunohistochemical profile of the zebrafish pineal gland with particular reference to the pinealocytes. Here, we demonstrated, using RT-PCR, immunohistochemistry and transmission electron microscopy, the expression of the mRNA for rhodopsin in the pineal gland of zebrafish, as well as its cellular localization exclusively in the pinealocytes of adult zebrafish. Moreover, the ultrastructural observations demonstrated that the pinealocytes were constituted by an outer segment with numerous lamellar membranes, an inner segment with many mitochondria, and a basal pole with the synapses. Our results taken together demonstrated a central role of zebrafish pinealocytes in the control of pineal gland functions.     

Influence of Unmodified and β-Glycerophosphate Cross-Linked Chitosan on Anti-Candida Activity of Clotrimazole in Semi-Solid Delivery Systems

The combination of an antifungal agent and drug carrier with adjunctive antimicrobial properties represents novel strategy of complex therapy in pharmaceutical technology. The goal of this study was to investigate the unmodified and ion cross-linked chitosan’s influence on anti-Candida activity of clotrimazole used as a model drug in hydrogels. It was particularly crucial to explore whether the chitosans’ structure modification by β-glycerophosphate altered its antifungal properties. Antifungal studies (performed by plate diffusion method according to CLSI reference protocol) revealed that hydrogels obtained with chitosan/β-glycerophosphate displayed lower anti-Candida effect, probably as a result of weakened polycationic properties of chitosan in the presence of ion cross-linker. Designed chitosan hydrogels with clotrimazole were found to be more efficient against tested Candida strains and showed more favorable drug release profile compared to commercially available product. These observations indicate that novel chitosan formulations may be considered as promising semi-solid delivery system of clotrimazole.     

Dithizone modified gold nanoparticles films for potentiometric sensing

For the first time, application of a membrane composed of gold nanoparticles decorated with complexing ligand for potentiometric sensing is shown. Gold nanoparticles drop cast from a solution form a porous structure on a substrate electrode surface. Sample cations can penetrate the gold nanoparticles layer and interact with ligand acting as a charged ionophore, resulting in Nernstian potentiometric responses. Anchoring of complexing ligand on the gold surface abolishes the necessity of ionophore application. Moreover, it opens the possibility of preparation of potentiometric sensors using chelators of significantly different selectivity patterns further enhanced by the absence of polymeric membrane matrix. This was clearly seen, for example, for gold nanoparticles stabilizing the applied ligand-dithizone-thiol conformation leading to a high potentiometric selectivity toward copper ions, much higher than that of ionophores typically used to induce selectivity for polymeric ion-selective membranes.     

Fast and accurate fuzzy C‐means algorithm for MR brain image segmentation

Fuzzy theory based intelligent techniques are widely preferred for medical applications because of high accuracy. Among the fuzzy based techniques, Fuzzy C‐Means (FCM) algorithm is popular than the other approaches due to the availability of expert knowledge. But, one of the hidden facts is that the computational complexity of the FCM algorithm is significantly high. Since medical applications need to be time effective, suitable modifications must be made in this algorithm for practical feasibility. In this study, necessary changes are included in the FCM approach to make the approach time effective without compromising the segmentation efficiency. An additional data reduction approach is performed in the conventional FCM to minimize the computational complexity and the convergence rate. A comparative analysis with the conventional FCM algorithm and the proposed Fast and Accurate FCM (FAFCM) is also given to show the superior nature of the proposed approach. These techniques are analyzed in terms of segmentation efficiency and convergence rate. Experimental results show promising results for the proposed approach. © 2016 Wiley Periodicals, Inc. Int J Imaging Syst Technol, 26, 188–195, 2016     

Porcelain Faucet Handle Failure Analysis

A porcelain faucet handle failed after years of use in a residential rental property. Determining the cause of failure was hampered by the fact that the failed handle was no longer available. The analysis included mechanical testing of exemplar faucet handles to measure the reasonable forces that could be applied by hand and the forces necessary to cause failure. Interface geometry between the porcelain handle and the interior metal nut was a factor. Finite Element Analysis facilitated the study. Results showed that if the faucet handle had sustained damage during a gasket repair, then the failure could be accounted for.