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41.
In this work, a platinum surface was modified with benzo[c]cinnoline (BCC) to get new insight into the metal modification area. By potential scanning from + 0.4 V to - 0.8 V, the diazotized BCC was reduced electrochemically and grafted onto the platinum electrode surface to form benzo[c]cinnoline modified platinum electrode (Pt-BCC). Electrochemical reduction of benzo[c]cinnoline diazonium salt on the electrode surface yielded a relatively stable organic film. The introduction of BCC molecules onto the platinum surface was verified by cyclic voltammetry, electrochemical impedance spectroscopy, Raman spectroscopy and ellipsometry. The stability and the potential range of the Pt-BCC electrode were also studied. 相似文献
42.
43.
Kara L. Orvis Robert A. Wisher Curtis J. Bonk Tatana M. Olson 《Computers in human behavior》2002,18(6)
The nature of communication among geographically dispersed groups of learners using text messaging in a military training environment was assessed. A total of 6601 acts of chat were coded into one of three interaction content categories (social, task, or technology-related) and analyzed for frequency and relative change over time. Results indicated shifting patterns of interaction over the 6-month course; while technology concerns gradually diminished, on task discussion peaked in the middle months and social interactions were higher at the start and end of the training. Overall, student chats were categorized as on-task 55%, social 30%, or technology-related 15%. Examples of chats and focus group data indicated that there was an emphasis on fostering student problem solving within the online course. 相似文献
44.
Kinetic and equilibrium studies in removing lead ions from aqueous solutions by natural sepiolite 总被引:7,自引:0,他引:7
The capacity of sepiolite for the removal of lead ions from aqueous solution was investigated under different experimental conditions. The Langmuir and Freundlich equations, which are in common use for describing sorption equilibrium for wastewater-treatment applications, were applied to data. The constants and correlation coefficients of these isotherm models for the present system at different conditions such as pH, temperature and particle size were calculated and compared. The equilibrium process was well described by the Langmuir isotherm model and the maximum sorption capacity was found to be 93.4 mg/g for the optimal experimental condition. The thermodynamic parameters (DeltaG(o), DeltaH(o) and DeltaS(o)) for lead sorption on the sepiolite were also determined from the temperature dependence. The influences of specific parameters such as the agitation speed, particle size and initial concentration for the kinetic studies were also examined. The sorption kinetics were tested for first order reversible, pseudo-first order and pseudo-second order reaction and the rate constants of kinetic models were calculated. The best correlation coefficients were obtained using the pseudo-second order kinetic model, indicating that lead uptake process followed the pseudo-second order rate expression. 相似文献
45.
Hazardous waste management involves the collection, transportation, treatment and disposal of hazardous wastes. In this paper a new multiobjective location-routing model is proposed. Our model also includes some constraints, which were observed in the literature but were not incorporated into previous models. The aim of the proposed model is to answer the following questions: where to open treatment centers and with which technologies, where to open disposal centers, how to route different types of hazardous waste to which of the compatible treatment technologies, and how to route waste residues to disposal centers. The model has the objective of minimizing the total cost and the transportation risk. A large-scale implementation of the model in the Central Anatolian region of Turkey is presented. 相似文献
46.
Experiencing Nature: Embodying Animals in Immersive Virtual Environments Increases Inclusion of Nature in Self and Involvement With Nature 下载免费PDF全文
Sun Joo Ahn Joshua Bostick Elise Ogle Kristine L. Nowak Kara T. McGillicuddy Jeremy N. Bailenson 《Journal of Computer-Mediated Communication》2016,21(6):399-419
Immersive virtual environments (IVEs) produce simulations that mimic unmediated sensory experiences. 3 experiments (N = 228) tested how different modalities increase environmental involvement by allowing users to inhabit the body of animals in IVEs or watch the experience on video. Embodying sensory‐rich experiences of animals in IVEs led to greater feeling of embodiment, perception of being present in the virtual world, and interconnection between the self and nature compared to video. Heightened interconnection with nature elicited greater perceptions of imminence of the environmental risk and involvement with nature, which persisted for 1 week. Although the effect sizes were small to moderate, findings suggest that embodied experiences in IVEs may be an effective tool to promote involvement with environmental issues. 相似文献
47.
Schmid K Keasey SL Pittman P Emerson GL Meegan J Tikhonov AP Chen G Schweitzer B Ulrich RG 《Proteomics. Clinical applications》2008,2(10-11):1528-1538
Control of smallpox by mass vaccination was one of the most effective public health measures ever employed for eradicating a devastating infectious disease. However, new methods are needed for monitoring smallpox immunity within current vulnerable populations, and for the development of replacement vaccines for use by immunocompromized or low-responding individuals. As a measure for achieving this goal, we developed a protein microarray of the vaccinia virus proteome by using high-throughput baculovirus expression and purification of individual elements. The array was validated with therapeutic-grade, human hyperimmune sera, and these data were compared to results obtained from individuals vaccinated against smallpox using Dryvax. A high level of reproducibility with a very low background were apparent in repetitive assays that confirmed previously reported antigens and identified new proteins that may be important for neutralizing viral infection. Our results suggest that proteins recognized by antibodies from all vaccinees constituted <10% of the total vaccinia proteome. 相似文献
48.
We define the hazardous waste management problem as the combined decisions of selecting the disposal method, siting the disposal plants and deciding on the waste flow structure. The hazardous waste management problem has additional requirements depending on the selected disposal method. In this paper we focus on incineration, for which the main additional requirement is to satisfy the air pollution standards imposed by the governmental restrictions. We propose a cost-based mathematical model in which the satisfaction of air pollution standards is also incorporated. We used the Gaussian Plume equation in measuring the air pollution concentrations at population centers. A large-scale implementation of the proposed model within Turkey is provided. 相似文献
49.
Ayhan Kara 《Journal of Fusion Energy》2017,36(6):230-233
Nuclear structures with high performance materials will be critical for the success of future fusion energy. Zirconium alloys are extensively used for nuclear reactor core materials as fuel cladding and guide tubes due to excellent radiation and corrosion resistant properties. In this paper, the excitation functions of 90Zr(n,2n)89Zr, 90Zr(n,α)87Sr, 91Zr(n,p)91Y and 92Zr(n,p)92Y nuclear reactions were calculated for energies up to 25 MeV. Besides, ALICE/ASH and TALYS 1.6 codes were used for the cross section calculations. The obtained calculations were compared with the experimental data in the literature. 相似文献
50.
Kara Perlman 《家电科技》1998,(5)
为使连接器保持竞争力,工程人员们都在努力提高其使用简易程度和成本效益以及工效学.连接器仅在气密和阻漏方面优越是不够的.在今天市场上,作为连接器工业还必须具其它卓越性能. 相似文献