Tetrazole tethered polymers for alkaline anion exchange membranes

Poly(2,6-dimethyl-1,4-phenylene oxide) was tethered with a 1,5-disubstituted tetrazole through a quaternary ammonium linkage. The formation of a tetrazole-ion network in the resulting polymers was found to promote the hydroxide ion transport through the Grotthus-type mechanism.

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Optimal rate allocation for production and injection wells in an oil and gas field for enhanced profitability

An oil and gas field requires careful operational planning and management via production optimization for increased recovery and long-term project profitability. This article addresses the challenge of production optimization in a field undergoing secondary recovery by water flooding. The field operates with limited processing capacity at the surface separators, pipeline pressure constraints, and water injection constraints; an economic indicator (net present value, NPV) is used as the objective function. The formulated optimization framework adequately integrates slow-paced subsurface dynamics using reservoir simulation, and fast-paced surface dynamics using sophisticated multiphase flow simulation in the upstream facilities. Optimization of this holistic long-term model is made possible by developing accurate second-order polynomial proxy models at each time step. The resulting formulation is solved as a nonlinear program using commercially available solvers. A comparative analysis is performed using MATLAB's fmincon solver and the IPOPT solver for their robustness, speed, and convergence stability in solving the proposed problem. By implementing two synthetic case studies, our mathematical programming approach determines the optimal production and injection rates of all wells and further demonstrates considerable improvement to the NPV obtained by simultaneously applying the tools of streamline, reservoir, and surface facility simulation for well rate allocation via systematic NLP optimization.     

In situ Y2Si2O7 coatings on SiC fibers: Thermodynamic analysis and processing

It is shown using thermodynamic analysis and kinetic modeling that a processing window exists for the formation of Y₂Si₂O₇ coatings on SiC. The proposed method is validated using an experimental procedure in which the in situ formation of Y₂Si₂O₇ on a commercial SiC-based fiber is demonstrated. The method involves the deposition of YPO₄ on preoxidized fine diameter SiC-based fibers, and heat treating the coated fibers within a calculated processing window of oxygen partial pressure, temperature, degree of preoxidation, and coating thickness. The results are promising for the development of environmentally resistant interfacial coatings for SiC-fiber reinforced SiC-based matrix composites. The proposed and validated approach allows a low-cost method to obtain continuous hermetic coatings on SiC fibers with interfacial properties adequate for tough composite behavior that resists degradation under turbine engine conditions.     

Synthesis and thermal stability of (Co,Ni)O solid solutions

(Co,Ni)O solid solutions are considered as promising protective materials of O₂-evolving anodes for Al production. In this context, two solid-state synthesis methods, namely high-energy ball milling (HEBM) and calcination, have been evaluated for the synthesis of (Co,Ni₎O solid solutions. In all cases, Co_xNi_1−xO solid solutions can be formed over the whole composition range. However, undesired WC contaminant is observed using the HEBM method due to the erosion of the milling tools. Their thermal stability in air has been analyzed by thermogravimetric analyzes (TGA) complemented by X-ray diffraction (XRD) analyses. It is shown that Co_xNi_1−xO solid solutions are stable at 1000°C over the whole composition range whereas they are only stable for x ≤ 46 and x ≤ 22 at 800°C and 700°C, respectively. For higher Co contents, the formation of Co₃O₄ is observed. This is a relevant information for their future use for Al production, which can be done at different temperatures (~700-1000°C) depending of the electrolyte composition.     

Effect of Drying Methods on Dyeing Capacity of Dyestuff Plant Materials

This article presents a study of the effect of drying methods on dyeing capacity of widespread European flora dyestuff plant materials. The natural colorants, derived from the selected plant materials, were applied on chemical pulp in order to examine their dyeability. In this work, three different drying methods were examined—the natural, the air-, and the freeze-drying method—in various conditions. The plant materials that were dried naturally show weak dyeing results in comparison with the air- and freeze-dried materials. Freeze drying significantly improved the dyeing capacity of dyestuff plant materials with high initial moisture content. On the other hand, air drying at low temperature and high relative humidity improved the dyeing capacity of plant materials with low initial moisture content.     

Poly(lactic acid) nanocomposites: comparison of their properties with montmorillonite and synthetic mica (II)

Our study was to clarify the intercalation of polymer chains to organoclays and to improve the thermo-mechanical properties. Two organoclays were synthesized. One was a montmorillonite modified with hexadecylamine (C₁₆-MMT); the other was a fluorinated-mica modified with hexadecylamine (C₁₆-Mica). Dispersions of organoclays with poly(lactic acid) (PLA) were by using the solution intercalation method at different organoclay contents to produce nano-scale composites. The maximum ultimate tensile strength was observed for blends containing 4 wt% of either of the two organoclays and decreased with further increases in the organoclay content. The initial modulus increased with increasing organoclay content up to 4 wt% for C₁₆-MMT. When the C₁₆-MMT content was greater than this critical wt%, the modulus of the hybrids started to decrease. In contrast, the initial modulus of the hybrids using C₁₆-Mica increased continually with increasing clay content from 2 to 8 wt%. The tensile properties of the C₁₆-Mica hybrids were higher than those of the hybrids containing C₁₆-MMT. The optical translucency was not affected by the organoclay content up to 6 wt%; however, the films containing 8 wt% organoclays were slightly more cloudy.     

A (Triphenylphosphine)Silver (I) Complex as a New Performance Additive in Free‐Radical Photopolymerization under Air

Unusual photochemical properties of an Ag(I)‐derived complex, i.e., bis[(µ‐chloro)bis(triphenylphosphine)silver (I)] ([Ag](PPh₃)) are demonstrated when used in free‐radical photopolymerization reactions: i) [Ag](PPh₃) can act as an innovative photoinitiating system when associated with a commercial type I photoinitiator 2,2‐dimethoxy‐2‐phenylacetophenone to overcome the oxygen inhibition effect during the free‐radical photopolymerization of acrylate monomers, thus accelerating the kinetics of polymerization under air; ii) silver‐based nanoparticles can be in situ generated under air, thus leading to new antibacterial coatings which prevent the growth of Escherichia coli and Staphylococcus aureus after few hours of incubation.     

Novel Redox-Dependent Esterase Activity (EC 3.1.1.2) for DJ-1: Implications for Parkinson’s Disease

Mutations the in human DJ-1 (hDJ-1) gene are associated with early-onset autosomal recessive forms of Parkinson’s disease (PD). hDJ-1/parkinsonism associated deglycase (PARK7) is a cytoprotective multi-functional protein that contains a conserved cysteine-protease domain. Given that cysteine-proteases can act on both amide and ester substrates, we surmised that hDJ-1 possessed cysteine-mediated esterase activity. To test this hypothesis, hDJ-1 was overexpressed, purified and tested for activity towards 4-nitrophenyl acetate (pNPA) as µmol of pNPA hydrolyzed/min/mg·protein (U/mg protein). hDJ-1 showed maximum reaction velocity esterase activity (V_max = 235.10 ± 12.00 U/mg protein), with a sigmoidal fit (S_0.5 = 0.55 ± 0.040 mM) and apparent positive cooperativity (Hill coefficient of 2.05 ± 0.28). A PD-associated mutant of DJ-1 (M26I) lacked activity. Unlike its protease activity which is inactivated by reactive oxygen species (ROS), esterase activity of hDJ-1 is enhanced upon exposure to low concentrations of hydrogen peroxide (<10 µM) and plateaus at elevated concentrations (>100 µM) suggesting that its activity is resistant to oxidative stress. Esterase activity of DJ-1 requires oxidation of catalytic cysteines, as chemically protecting cysteines blocked its activity whereas an oxido-mimetic mutant of DJ-1 (C106D) exhibited robust esterase activity. Molecular docking studies suggest that C106 and L126 within its catalytic site interact with esterase substrates. Overall, our data show that hDJ-1 contains intrinsic redox-sensitive esterase activity that is abolished in a PD-associated mutant form of the hDJ-1 protein.     

Development and Characterization of Continuous SiC Fiber‐Reinforced HfB2‐Based UHTC Matrix Composites Using Polymer Impregnation and Slurry Infiltration Techniques

This paper discusses the development of continuous SiC fiber‐reinforced HfB₂‐SiC composite laminates. A range of techniques, based on resin‐based precursors and slurries, for infiltrating porous SiC preforms with HfB₂ powder were developed. While resin‐based precursors proved to be ineffective due to low HfB₂ yield and poor adhesion, the slurry infiltration techniques were effective to varying degrees. The greatest pore filling and composite densities were achieved using pressure and vibration‐assisted pressure infiltration techniques. SiC_f/HfB₂‐SiC laminates were subsequently developed via lamination, cure and pyrolysis of fabrics using a HfB₂‐loaded polymeric SiC precursor, followed by HfB₂ slurry infiltration and preceramic polymer infiltration and pyrolysis (PIP). Repeated PIP processing, for 6–10 cycles, resulted in density increases, from the 3.03–3.22 g/cm³ range after HfB₂ slurry infiltration, to 3.97–4.03 g/cm³ after PIP processing. Correspondingly, there was a decrease in open porosity from approximately 52% to less than 11%. The matrix consisted of discreet, lightly sintered HfB₂ particles dispersed in SiC. The PIP SiC matrix was primarily nanocrystalline after 1300°C pyrolysis, but experienced grain growth with further heat treatment at 1600°C.