Extraction of oleic acid from soybean oil and jojoba oil-phase diagrams

Formamide,N-methylformamide,N-dimethylformamide, dimethylsulfoxide, 1,2-butanediol, and 2-butane-1,4-diol were considered as potential extractants of fatty acids from soybean and jojoba oils. Ternary liquid-liquid phase diagrams at 298.15 K, distribution, and selectivity coefficients of oleic acid are reported. Of the investigated solvents, onlyN-methylformamide and 1,2-butanediol have desirable extraction characteristics.     

An end‐to‐end alternative to TCP PEPs: Initial Spreading,a TCP fast start‐up mechanism

While Transmission Control Protocol (TCP) Performance Enhancing Proxy (PEP) solutions have long been undisputed to solve the inherent satellite problems, the improvement of the regular end‐to‐end TCP congestion avoidance algorithms and the recent emphasis on the PEPs drawbacks have opened the question of the PEPs sustainability. Nevertheless, with a vast majority of Internet connections shorter than ten segments, TCP PEPs continue to be required to counter the poor efficiency of the end‐to‐end TCP start‐up mechanisms. To reduce the PEPs dependency, designing a new fast start‐up TCP mechanism is therefore a major concern. But, while enlarging the Initial Window (IW) up to ten segments is, without any doubt, the fastest solution to deal with a short‐lived connection in an uncongested network, numerous researchers are concerned about the impact of the large initial burst on an already congested network. Based on traffic observations and real experiments, Initial Spreading has been designed to remove those concerns whatever the load and type of networks. It offers performance similar to a large IW in uncongested network and outperforms existing end‐to‐end solutions in congested networks. In this paper, we show that Initial Spreading, taking care of the satellite specificities, is an efficient end‐to‐end alternative to the TCP PEPs. Copyright © 2015 John Wiley & Sons, Ltd.     

Zr‐Doped Indium Oxide (IZRO) Transparent Electrodes for Perovskite‐Based Tandem Solar Cells

Parasitic absorption in transparent electrodes is one of the main roadblocks to enabling power conversion efficiencies (PCEs) for perovskite‐based tandem solar cells beyond 30%. To reduce such losses and maximize light coupling, the broadband transparency of such electrodes should be improved, especially at the front of the device. Here, the excellent properties of Zr‐doped indium oxide (IZRO) transparent electrodes for such applications, with improved near‐infrared (NIR) response, compared to conventional tin‐doped indium oxide (ITO) electrodes, are shown. Optimized IZRO films feature a very high electron mobility (up to ≈77 cm² V^?1 s^?1), enabling highly infrared transparent films with a very low sheet resistance (≈18 Ω □^?1 for annealed 100 nm films). For devices, this translates in a parasitic absorption of only ≈5% for IZRO within the solar spectrum (250–2500 nm range), to be compared with ≈10% for commercial ITO. Fundamentally, it is found that the high conductivity of annealed IZRO films is directly linked to promoted crystallinity of the indium oxide (In₂O₃) films due to Zr‐doping. Overall, on a four‐terminal perovskite/silicon tandem device level, an absolute 3.5 mA cm^?2 short‐circuit current improvement in silicon bottom cells is obtained by replacing commercial ITO electrodes with IZRO, resulting in improving the PCE from 23.3% to 26.2%.     

Disaggregate energy consumption and industrial production in South Africa

This paper tries to assess the relationship between disaggregate energy consumption and industrial output in South Africa by undertaking a cointegration analysis using annual data from 1980 to 2005. We also investigate the causal relationships between the various disaggregate forms of energy consumption and industrial production. Our results imply that industrial production and employment are long-run forcing variables for electricity consumption. Applying the [Toda, H.Y., Yamamoto, T., 1995. Statistical inference in vector autoregressions with possibly integrated processes. Journal of Econometrics 66, 225–250] technique to Granger-causality, we find bi-directional causality between oil consumption and industrial production. For the other forms of energy consumption, there is evidence in support of the energy neutrality hypothesis. There is also evidence of causality between employment and electricity consumption as well as coal consumption causing employment.     

Optimal design of conical springs

Mechanical systems often use springs to store energy though their axial length must sometimes be significantly reduced. This leads to the use of conical springs as they are able to telescope. Designers of mechanical systems can call on a large number of tools to assist them though most of these are merely validation tools requiring concomitant trial and error strategies. Optimization strategies can be applied to provide synthesis assistance tools for which the designer simply specifies his requirement. Thus the tool directly indicates the spring best suited to standards and requirements. Recent advances in the study of constant pitch conical springs have provided analytical expressions of their behavior even in the non-linear phase. Considering this, we have used optimization strategies to provide a synthesis tool for conical spring design. An example of application is presented. The tool introduced here is thus a synthesis assistance tool that can be of considerable interest for designers who require a conical spring in their design.     

Reynolds stress and turbulence estimates in bottom boundary layer of Fall of Warness

A broadband acoustic Doppler current profiler (ADCP) moored on the seabed at 42 m depth has been used to observe the mean and turbulent flow components in the tidally energetic Fall of Warness channel over two tidal cycles. The Reynolds stress has been estimated from the difference in variance between the along-beam velocities of opposing acoustic beams. Near bed stress at 2.63 m above seabed (mab) exceeds 7.5 Pa at the time of mean flow (speed of ~ 1.3 m s^− 1) while the ebb stresses are limited to ~ 3.31 Pa during the peak ebb, mean, flow of ~ 1.3 m s^− 1. The production of turbulent kinetic energy (TKE), P was found to be negative below 2 × 10^− 9 W m^− 3 and up to 6 × 10^− 4 W m^− 3 was estimated during flood flows and decreasing to 3 × 10^− 4 W m^− 3. The TKE dissipation rate ε was estimated by inertial dissipation method (IDM) with the greatest value of 2.43 × 10^− 2 W m^− 3 observed near the seabed around maximum ebb, falling to 5.75 × 10^− 5 W m^− 3 around slack water. The comparison between P and ε was performed by calculating individual ratios of P corresponding to ε using a bootstrap resampling technique. The study shows that the ratio ε/P averaged over whole flood and ebb were found to be ~ 0.4138 and ~ 0.4177, respectively, indicating that production exceeded dissipation. The uncertainties in Reynolds stress estimates due to instrument noise were found to be 3 × 10^− 4 Pa while 4.52 × 10^− 2 Pa can be attributed to the uncertainties due to the increase in the flow-related component.     

Experimental comparison of classical PID and model-free control: Position control of a shape memory alloy active spring

Shape memory alloys (SMA) are being more frequently integrated into engineering applications. These materials with their shape memory effect enable the simplification of mechanisms and the reduction in size of actuators. SMA parts can easily be activated by Joule effect but their modeling and consequently their control remains difficult. It is principally due to their non-linear hysteretic thermomechanical behavior. Most of successful control strategies applied to SMA actuators are not often suitable for industrial applications: they are particularly heavy and use the Preisach model or neural networks to model the hysteretic behavior of these materials; this kind of model is difficult to identify and to use in real time. This paper deals with an application of the new framework of model-free control (MFC) of an SMA-spring based actuator. This control strategy relies on new results for fast derivative estimation of noisy signals. Their main advantages are: its simplicity and its robustness. Experimental results and comparisons with PI control are presented that demonstrate the efficiency of this new control strategy.     

Experimental investigation on the combustion behaviour of pre-dried Greek lignite

The present paper includes the results of the combustion tests with Greek dried lignite performed at a 1 MWth semi industrial scale pulverized coal combustion facility. Scope of the campaign is the investigation of the combustion behaviour of Greek lignite, i.e. temperature fields, ignition, burnout, emissions, as well as slagging and fouling tendency, while firing with varying levels of recirculated flue gas. Dry coal co-firing conditions in a large scale boiler are simulated by adjusting the volume flow of recirculated flue gas.Two test series representing different boiler operation modes are performed. During the first series the maximum flue gas temperature increase, when co-firing dry coal, is determined, while in the second test series the needed load decrease, in order to keep constant furnace outlet temperature in dry coal co-firing conditions is recorded. A detailed measurement set is carried out including temperature profiles, emissions, fuel, fly ash sampling and slagging and fouling investigations through the installation of dedicated deposition probes.The anticipated increase of the furnace temperature profiles by decreasing the inserted recirculated flue gas is confirmed by the experimental results. No clear trend of dry coal co-combustion on the emissions' behaviour is noticed, while dry coal firing appears to have a moderate effect on the deposition behaviour of Greek lignite. These preliminary investigations indicate that no significant operational problems are expected during a potential future demonstration of dry lignite co-firing in a Greek large scale boiler.