Zinc Oxide Nanowire Decorated Single‐Use Electrodes for Electrochemical DNA Detection

The surfaces of pencil graphite electrodes (PGEs) were decorated with zinc oxide nanowires (ZnO NWs) for the electrochemical detection of nucleic acids. ZnO NWs were synthesized through simple hydrothermal method. PGEs decorated with ZnO NWs (ZnO NW/PGEs) were electrochemically characterized through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) following morphological characterization through transmission (TEM) and scanning electron microscopy (SEM). Enhanced sensor response obtained using ZnO NW/PGEs contrary to the bare PGE (control) samples. Our preliminary results simply reveal the potential of combining ZnO NWs with disposable sensor technology for the electrochemical detection of DNA.     

The interplay between leadership and organizational culture in the Turkish construction sector

Organizational culture and leadership are purported to be deeply integrated and intertwined within an organization. Although there is a substantial amount of research demonstrating the importance of the interplay of culture and leadership, there exist few empirical examinations of the nature of this link. To examine this link, based on Cameron and Quinn's Organizational Culture Assessment Instrument and Hofstede's Values Survey Module, a questionnaire survey was conducted. The sample consists of 499 managerial personnel out of 107 contracting firms. With the aim of achieving a better understanding of how leadership style is influenced by organizational culture, Multinomial Logistic Regression was used. The findings demonstrate that managers in the contracting companies with different cultural characteristics tend to adopt different leadership styles to lead their employees to succeed in their business. Information contained in this paper will feed into country-specific understanding of leadership and organizational culture within the construction industry.     

All Solution‐Based Fabrication of Copper Oxide Thin Film/Cobalt‐Doped Zinc Oxide Nanowire Heterojunctions

Versatile and intriguing solution‐based processes are utilized to synthesize nanostructured materials for device applications to reduce material production and device fabrication costs. This study presents results on the fabrication and characterization of copper oxide (CuO) coated cobalt‐doped zinc oxide nanowires (Co‐doped ZnO NWs)‐based heterojunction diodes prepared by a two‐step synthesis route through combined hydrothermal growth and sol–gel spin coating. Highly dense, well‐ordered, undoped, and Co‐doped ZnO NWs were successfully grown by hydrothermal method. Complementary CuO thin films were synthesized by sol–gel method and subsequently coated onto both undoped and Co‐doped ZnO NWs through spin‐coating technique. Enhanced diode properties with a rectification ratio of 10³ at ±2 V and an ideality factor of n = 2.4 (in dark) were obtained for Co‐doped ZnO NWs‐based heterojunction diodes. The obtained results demonstrated that the investigated heterojunction diode structure fabricated by facile and cost‐effective solution‐based processes can be a promising candidate for the next generation optoelectronic devices.     

Modelling the impact of land-cover change on potential soil loss in the Taita Hills,Kenya, between 1987 and 2003 using remote-sensing and geospatial data

In sub-Saharan Africa, natural vegetation is being transformed into agricultural lands at a fast rate, endangering ecosystem services and increasing soil-loss potential, which may trigger land degradation. For the Taita Hills study area in Kenya, multi-temporal land-cover models of 1987, 1999 and 2003, derived from Satellite Pour l'Observation de la Terre (SPOT) imagery using a multi-scale segmentation/object relationship modelling (MSS/ORM) methodology and a rainfall layer, a digital elevation model (DEM) and a digital soil map were applied to model potential soil loss. Population growth in the area has led to a shortage of agricultural land and movement of people to the lowlands, evidenced by a 39% (9.3 km²) increase in croplands from 30% to 41% of the study area during the research time frame. Expansion took place mostly in surrounding foothills and lowlands, at the expense of natural shrubland and grassland, but also occurred in the hills. Universal soil-loss equation (USLE) model results showed a 60% (4 km²) increase in the area of very high potential soil loss, from 7% of the study area in 1987 to 12% in 2003, due mainly to very high soil-loss potential in croplands. Whilst the area of croplands as a whole increased, the relative proportion of very high soil-loss potential in croplands remained 20%, both in 1987 and in 2003, indicating that newly cleared agricultural lands with vulnerable soils are the most at-risk areas.     

Packet Reservation Window Multiple Access for Microcellular Voice/Data Transmission

We propose a new packet reservation multiple access (PRMA) scheme for the joint transmission of voice and data traffics in a microcellular medium. The collision resolution protocol within the system is based on a modification of the window random access algorithm, which has superior properties compared to the conventional slotted Aloha. The proposed algorithm, which we call packet reservation window multiple access (PRWMA), works in distinct modes for voice and data without prioritization, and the user performs slightly different operations depending on the information type. Simulation results show that PRWMA outperforms PRMA by a significant margin in terms of voice user capacity.     

Quantitative atomic 3-D imaging of single/double sheet graphene structure

Graphene sheets can be regarded as base structure of many carbon nanostructures, and atomic arrangements and variations in the atomic structure have a drastic impact on their unique properties. Using a single/double layer graphene model structure, we present a strategy to “see” single carbon atoms in 3-D. In high-resolution transmission electron microscopy, exit-wave images are essential to obtain and to understand 3-D atomic structure. Using electrons at 80 kV not only minimizes the knock-on damage, but also improves the detection sensitivity due to the higher scattering power of carbon at lower acceleration voltage of the electron. Using experiments and image simulations, positions of individual carbon atoms in a single/double layer structure in graphene have been identified.     

Adaptive random access algorithm with improved delay performance

We propose an adaptive random access algorithm for mobile environments with capture. The algorithm has a dynamic window size which is updated according to the traffic intensity. The packet arrival rate is tracked by employing sequential detection procedures. Simulations indicate that reducing the window size adaptively under heavy load conditions improves the average delay significantly. Copyright © 2001 John Wiley & Sons, Ltd.     

Preparation and characterization of thermally conductive thermoplastic polyurethane/h‐BN nanocomposites

Polyurethane nanocomposites are versatile engineering polymers with unique properties. In this study, nano hexagonal boron nitride containing thermoplastic polyurethane elastomers were prepared via melt blending and hot‐pressing techniques. The nanocomposites were characterized using Fourier transform infrared, differential scanning calorimetry, thermal gravimetric analysis, tensile tests, and thermal conductivity measurements. The surface morphology of the TPU/h‐BN composites was characterized by scanning electron microscopy. The optical properties of the composites were determined by UV transmittance measurements and as the amount of h‐BN increased, optical transparencies decreased dramatically. Nanocomposites displayed higher E‐modulus values and lower elongation at break values than the pure TPU elastomer. Char yields of TPUs increased with increasing h‐BN percentage. Moreover, thermal conductivity of the composite materials improved with the incorporation of h‐BN. POLYM. COMPOS., 35:530–538, 2014. © 2013 Society of Plastics Engineers     

Large deformation of thermally bonded random fibrous networks: microstructural changes and damage

A mechanical behaviour of random fibrous networks is predominantly governed by their microstructure. This study examines the effect of microstructure on macroscopic deformation and failure behaviour of random fibrous networks and its practical implication for optimisation of its structure by using finite-element simulations. A subroutine-based parametric modelling approach—a tool to develop and characterise random fibrous networks—is also presented. Here, a thermally bonded polypropylene nonwoven fabric is used as a model system. Its microstructure is incorporated into the model by explicit introduction of fibres according to their orientation distribution in the fabric. The model accounts for main deformation and damage mechanisms experimentally observed and provides the meso- and macro-level responses of the fabric. The suggested microstructure-based approach identifies and quantifies the spread of stresses and strains in fibres of the network as well as its structural evolution during deformation and damage. Its simulations also predict a continuous shift in the distribution of stresses due to structural evolution and progressive failure of fibres.     

Influence of thermal annealing on microstructural,morphological, optical properties and surface electronic structure of copper oxide thin films

In this study, effect of the post-deposition thermal annealing on copper oxide thin films has been systemically investigated. The copper oxide thin films were chemically deposited on glass substrates by spin-coating. Samples were annealed in air at atmospheric pressure and at different temperatures ranging from 200 to 600°C. The microstructural, morphological, optical properties and surface electronic structure of the thin films have been studied by diagnostic techniques such as X-ray diffraction (XRD), Raman spectroscopy, ultraviolet–visible (UV–VIS) absorption spectroscopy, field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). The thickness of the films was about 520 nm. Crystallinity and grain size was found to improve with annealing temperature. The optical bandgap of the samples was found to be in between 1.93 and 2.08 eV. Cupric oxide (CuO), cuprous oxide (Cu₂O) and copper hydroxide (Cu(OH)₂) phases were observed on the surface of as-deposited and 600 °C annealed thin films and relative concentrations of these three phases were found to depend on annealing temperature. A complete characterization reported herein allowed us to better understand the surface properties of copper oxide thin films which could then be used as active layers in optoelectronic devices such as solar cells and photodetectors.