Metathesis of methyl soyate with ruthenium catalysts

Three ruthenium catalysts were investigated for the metathesis reaction of methyl soyate. Dichlorotris (triphenylphosphine) ruthenium II and bis (tricyclohexyl phosphine) benzylidine ruthenium (IV) dichloride displayed no reactivity at 40 °C and atmospheric pressure. However, ruthenium [1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene] dichloro (phenylmethylene) tricyclohexylphosphine, Grubbs second generation catalyst, exhibited high activity at these mild conditions. After 2 h, 46% of the unsaturated methyl esters in a commercial methyl soyate were metathesized. This suggests a method to modify the structure of methyl soyate to improve diesel fuel performance properties.     

A lighting coordinate database for 3D art objects

Artists making three-dimensional art objects have an idea in their minds about how to illuminate their creations. For museums and galleries to illuminate these objects successfully according to the ideas of the artist, the types of light sources and their locations must be known. To fulfil this requirement, we propose a lighting coordinate database (LCD) to establish the coordinates of light sources. We describe two possible methods of obtaining data for this database: a computer software method and a hardware method. The head of Michelangelo's David is used to test the applicability of the two methods. In the software method, the scanned image of David's head is illuminated on the computer screen and data for the location of light sources are created. In the hardware method, a second set of data is created by illuminating a scale model of David using light emitting diodes (LED).     

Meta-heuristics for a complex push–pull production system

Hybrid push/pull production systems have received recent attention in the literature. This paper investigates a hybrid push/pull system originating from a foundry. The aim is to determine safety stock and replenishment levels for a large inventory situated at the junction point between component production and assembly operations. Components are produced according to a make-to-stock policy and are received into inventory when completed. Assembled goods are made-to-order, pulling components from the inventory when required. Classical techniques cannot be used in such a complex environment because they are based on invalid assumptions. This study proposes heuristically controlled simulations for attaining good solutions to the problem. Experimental results demonstrate and compare the proposed methods.     

A dynamic theory for polarizable and magnetizable magneto-electro thermoviscoelastic,electrically and thermally conductive anisotropic solids having magnetic symmetry

A unified dynamic theory for polarizable and magnetizable magneto-electro thermoviscoelastic. electrically and thermally conducting anisotropic solids possessing magnetic symmetry is developed for time-dependent electromagnetic fields. Considering the Chu formulation of the Maxwell equations, the balance equations of nonrelativistic continuum mechanics and the boundary conditions together with the constitutive equations for anisotropic materials are given. It is shown that the entropy, polarization. magnetization and the nondissipative part of stress are derivable from a potential while the dissipative part of stress, electric current and heat flux vectors satisfy a residual inequality. The theory developed for a general anisotropy and interaction is applied to special cases.     

In vitro cytotoxicity of monticellite based bioactive ceramic powder synthesized from boron derivative waste

The cytotoxicity of monticellite based bioactive ceramic powder, which was synthesized from boron derivative waste has been determined by in vitro assays of MTT, NRU, and JC-1 staining. The toxicity of powder on different mammalian cell lines (3T3-L1, HUVEC, CRL-2120) was evaluated at the concentrations of 10, 100, 200, 400 and 800?µg/mL to justify its potential for biomedical applications. The obtained results showed that monticellite based bioactive ceramic powder possesses not only bioactive feature but also biocompatible characteristic at the concentration range of 10–200?µg/mL. Hence, monticellite based bioactive ceramics have high potential as a bone graft substitute for bone void filling and coating applications.     

Susceptor-assisted fast microwave sintering of TiN reinforced SiAlON composites in a single mode cavity

In the present study, 17 wt % TiN reinforced α-β SiAlON composites were sintered at low temperature by susceptor-assisted microwave heating. The effect of TiN addition on dielectrical properties of starting powders, as well as the influence of sintering temperature on phase evolution, microstructure development and mechanical properties of α/β-SiAlON-TiN composites were investigated. The obtained results showed that TiN addition increased the microwave absorbing properties which is reflected in the peak sintering temperature. Thus, the α:β ratio decreased and mechanical properties were improved, especially the fracture toughness of the composites. Furthermore, an estimate of energy consumption during microwave assisted sintering at the laboratory scale is presented. As a result, the highest values for relative density (97.1%), Vickers hardness (13.35 ± 0.47 GPa), and fracture toughness (7.52 ± 0.54 MPa m^1/2) were obtained by microwave sintering for 30 min at 1300 °C.     

A New Slip-Line Field Modeling of Orthogonal Machining with a Rounded-Edge Worn Cutting Tool

In this study, a new slip-line field model and its associated hodograph for orthogonal cutting with a rounded-edge worn cutting tool are developed using Dewhurst and Collins's matrix technique. The new model considers the existence of dead metal zone in front of the rounded-edge worn cutting tool. The ploughing force and friction force occurred due to flank wear land, chip up-curl radius, chip thickness, primary shear zone thickness and length of bottom side of the dead metal zone are obtained by solving the model depending on the experimental resultant force data. The effects of flank wear rate, cutting edge radius, uncut chip thickness, cutting speed and rake angle on these outputs are specified.     

Continuous front propagation-based overhang control for topology optimization with additive manufacturing

Additive manufacturing enables the nearly uncompromised production of optimized topologies. However, due to the overhang limitation, some designs require a large number of supporting structures to enable manufacturing. Because these supports are costly to build and difficult to remove, it is desirable to find alternative designs that do not require support. In this work, a filter is presented that suppresses non-manufacturable regions within the topology optimization loop, resulting in designs that can be manufactured without the need for supports. The filter is based on front propagation, can be evaluated efficiently, and adjoint sensitivities are calculated with almost no additional computational cost. The filter can be applied also to unstructured meshes and the permissible degree of overhang can be freely chosen. The method is demonstrated on several compliance minimization problems in which its computational efficiency and flexibility are shown. The current applications are in 2D, and the proposed method is readily extensible to 3D.     

Polymerization of vegetable oils and their uses in printing inks

Ink vehicles were prepared by the polymerization of vegetable oils. By controlling the polymerization conditions, the desired viscosity, color and molecular weight could be achieved for a variety of vegetable oils with a broad range of iodine values and fatty acid compositions. The effect of temperature and catalyst on polymerization rates were evaluated, and polymerization rate constants were calculated. Of the oils tested, the polymerization rate constant of safflower oil was the highest, followed by soybean, sunflower, cottonseed and canola oils in decreasing order. Use of a catalyst shortened the heating time by about 25–50% or lowered the polymerization temperature requirement by 25–30°C.     

Biodegradation of estolides from monounsaturated fatty acids

Mono- and polyestolides, made from oleic acid, meadowfoam oil fatty acids and erucic acid, were subjected to biodegradation with mixed cultures of Penicillium verucosum, Mucor racemosus, and Enterobacter aerogenes. Fermentations were continued for 3, 5, 10, 15, 20, or 30 d. Meadowfoam oil and its fatty acids, oleic acid and soybean oil were also biodegraded under the same conditions. After 10 d, oleic acid and soybean oil were degraded 99.8 and 99.2%, respectively; meadowfoam oil and its fatty acids were degraded 89.0 and 97.7%, respectively. After 30 d, oleic acid-derived poly- and monoestolides were degraded 98.6 and 90.0%, respectively, meadowfoam estolides were degraded 75.7%, and erucic acid estolides were degraded 84.0%.