Corrosion protection of cold-rolled steel by zinc-rich epoxy paint coatings loaded with nano-size alumina supported polypyrrole

High porosity and intense galvanic function related low electrolytic barrier profile and fast delamination of zinc-rich paints (ZRPs) are addressed by the utilisation of intimately structured, highly dispersed, polypyrrole (PPy) deposited alumina particles (PDAPs) embedded zinc-rich hybrid paints. The more globular but less-packed structure type PPy-contained water-solvent-prepared PDAPs-composited hybrids comprising spherical zinc pigment at 70 wt.%, provided moderate galvanic function with enhanced electrolytic barrier properties. In addition, the less globular structured but well-packed PPy-comprised aqueous ethanol-solvent-prepared PDAPs-composited hybrid coatings indicated highly efficient suppressed galvanic function and improved barrier properties, realising solid performance improvement over conventional ZRPs in immersion and salt-spray chamber tests. Furthermore, the application of highly dispersed PDAPs at a content of 3.2 wt.% while PPy incorporated into zinc-rich hybrids at 0.16 wt.% is proposed to result in emerging additional functionalities increasing long-term anticorrosive performance of ZRPs by inhibiting sacrificial and self-corrosion of zinc and scavenging oxidative radicals thereby hindering oxidative degradation of the organic binder.     

Telepresence, soundscapes and technological expectation: putting the observer into the equation

In an experiment exploring the impact of sound on sensations of telepresence, 126 participants watched a video clip using either headphones or speakers. The results illustrate that sound is an important factor in stimulating telepresence responses in audiences. Interactions between soundscape and screen size were also revealed. A traverse interaction between aural/visual congruency and soundscapes was evident. A second data set of 102 participants was collected to illuminate the effect of technological expectation that emerged in the first study. Expectations had been mentioned in other studies, and the data support the notion that people have an expectation of the technological quality of a presentation. The results suggest that examining expectations could assist in future conceptualizations of telepresence.     

Affective incoherence: When affective concepts and embodied reactions clash.

In five studies, the authors examined the effects on cognitive performance of coherence and incoherence between conceptual and experiential sources of affective information. The studies crossed the priming of happy and sad concepts with affective experiences. In different experiments, these included approach or avoidance actions, happy or sad feelings, and happy or sad expressive behaviors. In all studies, coherence between affective concepts and affective experiences led to better recall of a story than did affective incoherence. The authors suggest that the experience of such experiential affective cues serves as evidence of the appropriateness of affective concepts that come to mind. The results suggest that affective coherence has epistemic benefits and that incoherence is costly in terms of cognitive performance. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Learners' questions and comprehension in a tutoring setting.

Three experiments, presented within the framework of Activity Theory, deal with the relationship between adult learners' questions and subsequent comprehension in a tutorial learning setting. Students were first given verbal instructions (acquisition) to a novel card game and then asked to play one hand with the teacher (implementation). In Experiment 1, there was no correlation between number of questions asked during acquisition and comprehension, but questions during implementation were negatively correlated with comprehension. In Experiment 2, learners whose questions were answered during acquisition scored higher than those whose questions were not answered. In Experiment 3, learners whose questions were answered during implementation showed greater gains in comprehension than those whose questions were answered during acquisition. Individual differences in question-asking during implementation but not acquisition were significantly related to comprehension. The results confirm the view that questions answered during knowledge implementation more effectively aid comprehension than those answered during acquisition. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Anatomical,Morphological, and Phytochemical Effects of Inoculation with Plant Growth- Promoting Rhizobacteria on Peppermint (<Emphasis Type="Italic">Mentha piperita</Emphasis>)

Plant growth-promoting rhizobacteria (PGPR) generally exert their effects through enhancement of plant nutrient status and/or phytohormone production. The effects of PGPR on aromatic plant species are poorly known. We measured plant growth parameters, chlorophyll content, trichome density, stomatal density, and levels of secondary metabolites in peppermint (Mentha piperita) seedlings inoculated with PGPR strains Bacillus subtilis GB03, Pseudomonas fluorescens WCS417r, P. putida SJ04, or a combination of WCS417r?+?SJ04. The treated plants, in comparison with controls, showed increases in shoot biomass, root biomass, leaf area, node number, trichome density, and stomatal density, and marked qualitative and quantitative changes in monoterpene content. Improved knowledge of the factors that control or affect biosynthesis of secondary metabolites and monoterpene accumulation will lead to strategies for improved cultivation and productivity of aromatic plants and other agricultural crops without the use of chemical fertilizers or pesticides.     

Next-Generation Sequencing Workflow for NSCLC Critical Samples Using a Targeted Sequencing Approach by Ion Torrent PGM? Platform

Next-generation sequencing (NGS) is a cost-effective technology capable of screening several genes simultaneously; however, its application in a clinical context requires an established workflow to acquire reliable sequencing results. Here, we report an optimized NGS workflow analyzing 22 lung cancer-related genes to sequence critical samples such as DNA from formalin-fixed paraffin-embedded (FFPE) blocks and circulating free DNA (cfDNA). Snap frozen and matched FFPE gDNA from 12 non-small cell lung cancer (NSCLC) patients, whose gDNA fragmentation status was previously evaluated using a multiplex PCR-based quality control, were successfully sequenced with Ion Torrent PGM™. The robust bioinformatic pipeline allowed us to correctly call both Single Nucleotide Variants (SNVs) and indels with a detection limit of 5%, achieving 100% specificity and 96% sensitivity. This workflow was also validated in 13 FFPE NSCLC biopsies. Furthermore, a specific protocol for low input gDNA capable of producing good sequencing data with high coverage, high uniformity, and a low error rate was also optimized. In conclusion, we demonstrate the feasibility of obtaining gDNA from FFPE samples suitable for NGS by performing appropriate quality controls. The optimized workflow, capable of screening low input gDNA, highlights NGS as a potential tool in the detection, disease monitoring, and treatment of NSCLC.     

13.3% efficient solution deposited Cu(In,Ga)Se2 solar cells processed with different sodium salt sources

In this work, we obtain the highest reported power conversion efficiency (13.3%) for sulfur‐free CIGSe solar cells by solution processing. Intentional sodium incorporation is achieved directly by dissolving sodium salts in the ink. The effect on solar cell properties of three sodium sources is investigated: NaCl, NaHCO₂, and NaSCN. A comparison is made with absorbers grown on soda‐lime glass substrates and in the absence of sodium sources. The incorporation via sodium salts yields significantly better results, which is attributed to enhanced‐sodium availability. A comparison with identically annealed sputtered metal precursor layers capable of delivering 15.1% module efficiency suggests that the cell results are limited by the selenization procedure. Copyright © 2015 John Wiley & Sons, Ltd.     

Toxic metals in the atmosphere in Lahore, Pakistan

Aerosol mass (PM₁₀ and PM_2.5) and detailed elemental composition were measured in monthly composites during the calendar year of 2007 at a site in Lahore, Pakistan. Elemental analysis revealed extremely high concentrations of Pb (4.4 μg m^− 3), Zn (12 μg m^− 3), Cd (0.077 μg m^− 3), and several other toxic metals. A significant fraction of the concentration of Pb (84%), Zn (98%), and Cd (90%) was contained in the fine particulate fraction (PM_2.5 and smaller); in addition, Zn and Cd were largely (≥ 60%) water soluble. The 2007 annual average PM₁₀ mass concentration was 340 μg m^− 3, which is well above the WHO guideline of 20 μg m^− 3. Dust sources were found to contribute on average (maximum) 41% (70%) of PM₁₀ mass and 14% (29%) of PM_2.5 mass on a monthly basis. Seasonally, concentrations were found to be lowest during the monsoon season (July-September). Principle component analysis identified seven factors, which combined explained 91% of the variance of the measured components of PM₁₀. These factors included three industrial sources, re-suspended soil, mobile sources, and two regional secondary aerosol sources likely from coal and/or biomass burning. The majority of the Pb was found to be associated with one industrial source, along with a number of other toxic metals including As and Cr. Cadmium, another toxic metal, was found at concentrations 16 times higher than the maximum exposure level recommended by the World Health Organization, and was concentrated in one industrial source that was also associated with Zn. These results highlight the importance of focusing control strategies not only on reducing PM mass concentration, but also on the reduction of toxic components of the PM as well, to most effectively protect human health and the environment.     

Electrospinning: A Novel Method to Incorporate POSS Into a Polymer Matrix

The effectiveness of electrospinning as a simple approach to disperse POSS into a polymer matrix at a nm‐level has been assessed. Electrospun and cast films were prepared by dissolving CA and epoxycyclohexylisobutyl POSS in the solvent mixture acetone/DMAc. The membranes were characterized by SEM, TEM and WAXD. Whereas films produced by casting showed µm‐sized POSS crystals, thus suggesting a small affinity between the polymer matrix and the POSS molecules, those prepared by electrospinning were characterized by a nanometric POSS distribution. This is explained by considering the peculiar solvent evaporation mechanism, occurring during the electrospinning process, which allows to produce nanofibers characterized by a silsesquioxane dispersion similar to that present in solution.

     

Sustainability and property valuation: a risk-based approach

The proportion of sustainable property in the total building stock remains small. One reason is that the financial added value resulting from sustainability is not sufficiently taken into account in property valuation due to the tendency of valuations to lag behind market trends. Quantitative information is provided to integrate those aspects of sustainability relating to value into valuations and thereby contribute to the reduction of valuation lag. The Centre for Corporate Responsibility and Sustainability (CCRS) Economic Sustainability Indicator (ESI) measures the risk of property to lose value and the opportunity to gain value due to future developments (e.g. climate change or rising energy prices). Five groups of value-related sustainability features were identified: flexibility and polyvalence; energy and water dependency; accessibility and mobility; security; and health and comfort. By minimizing the risk of loss in value through future developments, those sustainability features contribute to the property value. Their effects on property value were quantified by risk modelling. As an indicator for future-oriented property risk, the ESI is integrated into the discount rate of discounted cash flow valuations. The approach was tested for plausibility and practicability on more than 200 properties.

La proportion de biens immobiliers durables dans le parc immobilier total demeure faible. L'explication tient pour une part au fait que la valeur ajoutée financière résultant de la durabilité n'est pas suffisamment prise en compte dans l'évaluation des biens immobiliers en raison du fait que les évaluations tendent à avoir du retard sur les tendances du marché. Des informations quantitatives sont fournies afin d'intégrer les aspects de la durabilité liés à la valeur dans les évaluations et de contribuer ainsi à la réduction du retard dans les évaluations. L'Indicateur de Durabilité Economique (ESI) du Centre pour la Responsabilité et la Durabilité en Entreprise (CCRS) mesure le risque de perte de valeur des biens immobiliers et la possibilité d'en accroître la valeur du fait des évolutions futures (par ex. changement climatique et hausse des prix énergétiques). Cinq groupes de fonctions de durabilité liées à la valeur ont été identifiés: flexibilité et polyvalence, dépendance vis-à-vis de l'énergie et de l'eau; accessibilité et mobilité; sécurité; santé et confort. En minimisant le risque d'une perte de valeur causée par les évolutions futures, ces fonctions de durabilité contribuent à la valeur des biens immobiliers. Leurs effets sur la valeur des biens immobiliers ont été quantifiés par une modélisation des risques. En tant qu'indicateur du risque prospectif pour les biens immobiliers, l'ESI est intégré au taux d'actualisation des flux de trésorerie actualisés. Cette approche a été testée quant à sa plausibilité et sa praticabilité sur plus de 200 biens immobiliers.

Mots clés: flux de trésorerie actualisés, indicateur de durabilité économique, évaluation des biens immobiliers, modèle de risque, fonctions de durabilité, durabilité, bâtiments durables