Imprecise Reliability of General Structures

This paper discusses the important aspects of the reliability of systems with an imprecise general model of the structure function. It is assumed that the information about reliability behavior of components is restricted by the mean levels of component performance. In this case the classical reliability theory cannot provide a way for analyzing the reliability of systems. The theory of imprecise probabilities may be a basis in developing a general reliability theory which allows us to solve such problems. The basic tool for computing new reliability measures is the natural extension which can be regarded as a linear optimization problem. However, the linear programming computations will become impracticable when the number of components in the system is large. Therefore, the main aim of this paper is to obtain explicit expressions for computing the system reliability measures. We analyze the reliability of general structures and typical systems. The numerical examples illustrate the usefulness of the presented approach to reliability analyzing.     

Variation among and within mountain birch trees in foliage phenols,carbohydrates, and amino acids,and in growth ofEpirrita autumnata larvae

Leaf quality of the mountain birch (Betula pubescens ssp.tortuosa) for herbivores was studied at several hierarchical levels: among trees, among ramets within trees, among branches within ramets, and among short shoots within branches. The experimental units at each level were chosen randomly. The indices of leaf quality were the growth rate of the larvae of a geometrid,Epirrita autumnata, and certain biochemical traits of the leaves (total phenolics and individual phenolic compounds, total carbohydrates and individual sugars, free and protein-bound amino acids). We also discuss relationships between larval growth rate and biochemical foliage traits. Larval growth rates during two successive years correlated positively at the level of tree, the ramet, and the branch, indicating that the relationships in leaf quality remained constant between seasons both among and within trees. The distribution of variation at different hierarchical levels depended on the trait in question. In the case of larval growth rate, ramets and short shoots accounted for most of the explained variation. In the case of biochemical compounds, trees accounted for most of the variance in the content of total phenolics and individual low-molecular-weight phenolics. In the content of carbohydrates (total carbohydrates, starch, fructose, glucose, and sucrose) and amino acids, variation among branches was generally larger than variation among trees. Variation among ramets was low for most compounds. No single leaf trait played a paramount role in larval growth. Secondary compounds, represented by phenolic compounds, or primary metabolites, particularly sugars, may both be important in determining the suitability of birch leaves for larvae. If phenols are causally more important, genet-specific analyses of foliage chemistry are needed. If sugars are of primary importance, within-genet sampling and analysis of foliage chemistry are necessary.     

Outdoor attractancy of males ofMatsucoccus josephi (Homoptera: Matsucoccidae) andElatophilus hebraicus (Hemiptera: Anthocoridae) to synthetic female sex pheromone ofMatsucoccus josephi

The active component of the sex pheromone ofMatsucoccus josephi is (2E,6E,8E)-5,7-dimethyl-2,6,8-decatrien-4-one; the chemical is also a powerful kairomone of adult males and females of the bugElatophilus hebraicus the principal predator ofM. josephi. The presence of theZ isomer (2E,6Z,8E)-5,7-dimethyl-2,6,8-decatrien-4-one does not interfere with the attractancy of the activeE component forM. josephi males or the bug. Our results show a clear dose-response between trap catch ofM. josephi males andE. hebraicus. Conversely, increasing amounts of theZ isomer in the mixture did not affect the attraction of the scale insect males or the bug. The catch ofM. josephi males did not differ significantly among traps of different color, and was significantly higher with traps attached to the tree trunk than those suspended between trees. Comparison of the catch ofM. josephi among the three forests and between pine species suggests that the level of infestation ofPinus halepepsis andPinus brutia ssp.brutia is similar, despite the fact that the latter pine is resistant to the scale insect. Both sexes ofE. hebraicus were trapped in much lower numbers at the more infested sites. This may be related to interference with the activity ofE. hebraicus due to deterioration and drying of parts of the tree crowns and heavy colonization by generalist predators in injured trees.     

Hydrogels of polyvinylpyrrolidone (PVP) and poly(acrylic acid) (PAA) synthesized by photoinduced crosslinking of homopolymers

A novel method of covalent crosslinking between polyvinylpyrrolidone (PVP) and poly(acrylic acid) (PAA) resulting in hydrogels has been developed. The hydrogels were formed by photocrosslinking in oxygen-free aqueous solutions containing hydrogen peroxide as a source of hydroxyl radicals. The crosslinking was achieved via irradiation within the broad wavelength range from 200 to 800 nm, as well as by the light cut-off at λ > 300 nm. The obtained PAA-PVP gels were sensitive to pH. Protonation of the PAA carboxylic groups with decreasing pH promoted hydrogen bonding between the PAA and PVP segments within the crosslinked structure and caused the gel to collapse. This property enabled the use of the hydrogels as a simple chemical sensor. When loaded with glucose oxidase, the PAA-PVP gel's opacity and sedimentation due to the clearly observable phase separation were triggered by the presence of glucose due to a drop in pH caused by the enzymatic reaction.     

Titania and titania-silver nanoparticle deposits made by Liquid Flame Spray and their functionality as photocatalyst for organic- and biofilm removal

Titania and titania-silver nanoparticle deposits were made by Liquid Flame Spray technique, in which the liquid precursor is injected into a high temperature flame, where it will evaporate and nucleate to nanosize particles. One-step and two-step methods were used for preparation of titania-silver deposits. The amount of silver added was 1 wt%. The deposits were collected in the flame zone on steel and glass surfaces and were analyzed by TEM, EDS, XPS and SAXS. The titania deposits consisted of porous nanosized titania agglomerates of primary particles (~10 nm). With silver addition, small spherical silver metal particles (~2 nm) were detected on the agglomerates. An increase in the photocatalytic activity was verified by stearic acid decomposition and biofilm removal using Deinococcus geothermalis as the model organism.     

Variation of total phenolic content and individual low-molecular-weight phenolics in foliage of mountain birch trees (Betula pubescens ssp.tortuosa)

We studied seasonal and between-tree variation in the composition and content of total and individual low-molecular-weight phenolics (LMWP) in leaves of mountain birch trees (Betula pubescens ssp.tortuosa). The major phenolic compounds were chlorogenic acid, quercetin-3-O--D-glucuronopyranoside, myricetin-3-O-(5-acetyl)-L-rhamnopyranoside, and 1-O-galloyl--D-(2-O-acetyl)-glucopyranose. The content of total phenolics, as well as the sum of individual LMWP, varied only slightly among trees while variation in contents of individual LMWP was large. Concentrations of almost all phenolics decreased during the growing season but pairwise correlations between individual phenolics remained similar over the whole season indicating tree-specific LMWP profiles over the season. Among flavonoids, the between-tree component of variation was 2.6 times as large as the seasonal component, while for variation of nonflavonoids the between-tree component was larger than the seasonal one. To explain the significant correlations within both flavonoid and nonflavonoid compounds, we discuss the biogenesis of LMWP in birch leaves, as well as their ecological role.     

Recovery of manganese from iron containing sulfate solutions by precipitation

Worldwide consumption of manganese is increasing, nevertheless huge amounts of manganese from hydrometallurgical processes still end up as waste since the recovery of manganese from multi-metal solutions at low concentrations is not considered feasible. Poor iron control typically prevents the production of high purity manganese. This work studies a number of precipitants in manganese recovery and iron separation from sulfate solutions. The precipitation reagents were compared from the point of view of selectivity and economy. Carbonate precipitation is a fast and effective method for the recovery of manganese from bulk solutions. Subsequent leaching of metal carbonate is also easier and consumes less acid than, for example, hydroxide or sulfide precipitates. In order to avoid gypsum formation, soda ash should be used instead of limestone. It was found that efficient selective iron removal from MnSO₄ solutions is achieved with combined O₂ or air oxidation and CaCO₃ precipitation at pH >5.8 and at a redox potential of >200 mV. Effective mixing and sufficient retention time are essential to make the method technically efficient and economically feasible.     

Fluorescent dye labeled bacteriophages--a new tracer for the investigation of viral transport in porous media: 1. Introduction and characterization

A new method for the study of pathogen transport in porous media is presented. The method is based on conjugation of fluorescent dyes to target bacteriophages and application of the modified bacteriophages for tracer studies. We demonstrate that the relevant transport determining properties of Rhodamine and several fluorescein-labeled phages are practically identical to those of the native bacteriophages. The advantages of the proposed method relative to direct enumeration of bacteriophages by plaque forming unit method, turbidity, fluorescent microspheres, and other alternative tracers are discussed. Notable advantages include simple quantitation by optical methods, unbiased signals even when virus aggregates are formed, and the ability to decouple inactivation kinetics from transport phenomena. Additionally, the signal reflects the removal and transport of the studied microorganism and not a surrogate.     

Model of a miniature pig catheterized for pharmacokinetic and pharmacodynamic studies of anti-infective agents

The purpose of this study was to examine the role of sleep problems in the etiology of nursing caries. Two-hundred mothers of children (104 with nursing caries and 96 caries free) from ages 2 to 4.5 years were surveyed to determine whether difficulty with child sleep and ensuing sleep-associated feeding might be related to the presence of nursing caries. Differences were noted between these two groups regarding: average number of nights the child slept through the night (P < 0.001); total hours of sleep per night (P < 0.05); frequency of night waking episodes (P < 0.01); feeding on demand upon waking (P < 0.01); using a bottle to assist with falling asleep at night (P < 0.001); and feeding in association with nap time (P < 0.001). Differences also were noted in regard to average age of weaning (P < 0.001). Our findings suggest that sleep problems among young children are a behavioral risk factor for night-time bottle use and early childhood caries.     

ON BROADWAY

On Broadway represents life in the 21st century city through a compilation of images and data collected along the 13 miles of Broadway that span Manhattan. The result is a new type of city view, created from the activities and media shared by hundreds of thousands of people. The project uses approximately 40 million data points and images and includes an application and an interactive installation.