Electrochemical behaviour of indium ions in molten equimolar CaCl2–NaCl mixture at 550 ∘C

The stability of indium chloride and oxide as well as the electrochemical behaviour of indium ions have been studied in the equimolar CaCl2–NaCl melt at 550 C by X-ray diffraction (XRD) and different electrochemical techniques, using molybdenum and tungsten wires as working electrodes. Voltammetric and chronopotentiometric studies showed signals attributed to the presence of three oxidation states of indium, i.e. 0, i and iii. The standard potential of the redox couples, as well as the solubility products of indium oxides have been determined, showing that In(iii) ions are completely reduced to monovalent indium by the indium metal according to the reaction: In () + 2 In 3 In () and that In₂O is a strong oxide donor according to the reaction: In₂O(s) 2 In() + O^2- These results have allowed the construction of E-pO2– equilibrium diagrams summarising the properties of In–O compounds. The electrodeposition of indium was uncomplicated at Mo and W electrodes. Very good adherence of liquid indium to the electrode materials was observed, with the formation of Na–In alloys at highly reducing potentials, and there was no evidence of indium dissolution into the melt. Moreover, the voltammograms corresponding to the electrochemical In(iii)/In(i) exchange were well defined. The two electrochemical steps were found to be quasi-reversible, and the values of the kinetic parameters, ko and , for both reactions, as well as the diffusion coefficients, DIn(III) and DIn(I) were calculated.     

Silphinene Sesquiterpenes as Model Insect Antifeedants

Silphinene sesquiterpenes are established chrysomelid antifeedants. In this work, nine silphinene analogs, 11-acetoxy-5-angeloyloxysilphinen-3-one (1), 11-acetoxy-5-tigloyloxysilphinen-3-one (2), 11-acetoxy-5-iso- butyryloxysilphinen-3-one (3), 11-hydroxy-5-angeloyloxysilphinen-3-one (4), 11,5-dihydroxysilphinen-3-one (5), 11,5-diacetoxysilphinen-3-one (6), 5,11-diisobutyryloxysilphinen-3-one (7), silphinen-3,5,11-trione (8), and O-methyl-5-epicantabrenolic acid methyl ester (10), and a presilphiperfolane sesquiterpene (9) were tested against several divergent insect species, including the lepidopteran Spodoptera littoralis, the chrysomelid Leptinotarsa decemlineata, and five aphid species, and their antifeedant effects were compared with those of picrotoxinin, a GABA-antagonist, and thymol, an allosteric modulator for insect GABA receptors. All insects tested responded to at least one silphinene analog and/or GABA antagonist. Compound 3 and thymol were effective antifeedants against all species tested except S. littoralis, with varying potencies according to their feeding ecologies. The toxicity of these compounds was species-dependent and did not correlate with their antifeedant effect.     

Comparative study of the physical aging of the epoxy systems BADGE n = 0/m‐XDA and BADGE n = 0/m‐XDA/PEI

The physical aging of the epoxy network consisting of a diglycidyl ether of bisphenol A, m‐xylylenediamine, and polyetherimide was studied by differential scanning calorimetry. The glass transition temperature and the variation of the specific heat capacities have been calculated using the method, based on the intersection of both enthalpy–temperature lines for glassy and liquid states. The apparent activation energy (E_H) was calculated using a single method that involved separate temperature and excess enthalpy dependency. All calorimetric data were compared with those obtained for the epoxy network without thermoplastic. thermoplastic. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3931–3935, 2006     

Composition of phospholipids of white muscle of six tuna species

A comparative study of the phospholipids of white muscle of six of the comercially utilized tuna species, including quantitative analyses of phospholipid classes and studies of the acyl composition of the major components. Plasmalogen compounds also were identified and quantified. Choline and ethanolamine glycerophospholipids were the most abundant classes in all the samples, as well as the only molecules containing plasmalogens (16∶0, 18∶0, and 18∶1 alkenyl ether chains). The patterns of fatty acid distribution within each of the phospholipid classes showed general similarities in the species analyzed. However, ratios between certain saturated and polyunsaturated fatty acids in different phospholipid classes showed remarkable diffences. The high content of n−3 polyunsaturated fatty acids in the principal phospholipids, such as the plasmalogens, and taking into account the fatty acids possible importance in human nutrition, indicates that the white muscle of tuna species may be a potentially important dietary item.     

Chemical analysis of ozonized theobroma fat

Ozonized theobroma fat is used as raw material in the manufacture of pessaries and cosmetic creams. Ozonization of theobroma fat with water was carried out at different applied ozone dosages, and the resultant PV, acid value, iodine value, total hydroperoxide content, and FA content were determined. PV and total hydroperoxide content showed a notable increase with applied ozone dosage up to 35.7 mg/g. Acid value varied slightly from 4.1 to 9.9 mg KOH/g, and the iodine value fell to zero. PV and total hydroperoxide content increased slightly with a higher applied ozone dosage. The comparison of total hydroperoxide measurement using ferrous oxidation in xylenol orange assay and traditional iodometric assay for PV determination showed a significant linear correlation. Small amounts of oleic acid were found in ozonized theobroma fat samples with iodine value equaling zero, which demonstrated that iodine value determination is an inexact assay. During ozonization of theobroma fat, an increase in acid value of 18.9-fold with respect to the initial value was observed owing to decomposition of peroxide.     

Scandinavian Thins on Top of Cake: New and Improved Algorithms for Stacking and Packing

We show how to compute the smallest rectangle that can enclose any polygon, from a given set of polygons, in nearly linear time; we also present a PTAS for the problem, as well as a linear-time algorithm for the case when the polygons are rectangles themselves. We prove that finding a smallest convex polygon that encloses any of the given polygons is NP-hard, and give a PTAS for minimizing the perimeter of the convex enclosure. We also give efficient algorithms to find the smallest rectangle simultaneously enclosing a given pair of convex polygons.     

An empirically validated simulation for understanding the relationship between process conformance and technology skills

Software development is a fast-paced environment where developers need constant update to ever-changing technologies. Furthermore, process improvement initiatives have been proven useful in increasing the productivity of a software organization. As such, these organizations need to decide where to invest their training budget. As a result, training in technological update to their workforce or training in process conformance with its productive processes become conflicting alternatives. This paper presents a system dynamics simulation of a software factory product line. The objective of this simulation is to understand the changes in behavior when selecting either one of the above-training alternatives. The system dynamics model was validated with an expert panel, and the simulation results have been empirically validated—using statistical process control—against the performance baseline of a real software development organization. With the simulation under statistical control and performing like the baseline, the independent variables representing process conformance (process training) and technology skills (skills training) were modified to study their impact on product defects and process stability. Our results show that while both variables have positive impact on defects and process stability, investment in process training results in a process with less variation and with fewer defects.     

Applying black-box testing to UML/OCL database models

Most Unified Modeling Language (UML) computer-aided software engineering tools have been insufficient in the development process because they provide little support for conceptual model testing. Model testing aims to ensure the correctness of a UML/OCL class diagram, or, in other words, that a given class diagram can perfectly meet the user’s requirements. This study proposes the validation of class diagrams with black-box testing, a technique used to test software without focusing on the software’s implementation or structure. An approach is proposed for the automatic transformation of the constraints of a UML/OCL class diagram into test cases. Following the creation of the test cases, they are executed with JUnit and the results produced are shown to the tester. To demonstrate the applicability of this approach, an effectiveness evaluation and an efficiency evaluation are performed here. Evaluation studies show that all faults included in a class diagram have been detected within an efficient time.