Kinetic Energy Approach to Dissolving Axisymmetric Multiphase Plumes

A phenomenological kinetic energy theory of buoyant axisymmetric multiphase plumes is constructed, with particular attention to the modeling of the dispersed phase. The dissolution is treated by means of the Ranz-Marshall equation involving a mass-transfer coefficient dependent on the plume properties. The model is compared with various experiments, yielding satisfactory agreement. A central ingredient in the model is the turbulent correlation parameter I, playing a role analogous to the conventional entrainment coefficient α. We use experimental data to suggest a relationship between I, the initial gas flux at the source, and the depth of the gas release.     

Influence of the growth conditions on the defect density of single-walled carbon nanotubes

The influence of the temperature and precursor pressure on the defect density of single-walled carbon nanotubes (SWCNTs) grown by catalytic chemical vapor deposition was studied for several catalyst–precursor couples. The SWCNT defect density was assessed by studying the Raman D band. In situ Raman monitoring was used to determine experimental conditions allowing the preparation of samples free of pyrolytic carbon and not altered by air exposure. The most striking feature is that the Arrhenius plots of the I_G/I_D ratio systematically display a convex shape, i.e. the apparent activation energy decreases with increasing temperature. From HRTEM observations and oxidation experiments, this evolution of the D band features is ascribed to the catalytic growth of long SWCNTs with few defects at high temperature and of short and defective SWCNTs and carbon structures at low temperature. The convex Arrhenius behavior is well accounted by two kinetic models: (i) a model considering a change of intermediate states as a function of the temperature (for instance due to a phase transition of the catalyst particle or a change of intermediate carbon species) and (ii) a model considering a high-temperature process of defect creation (for instance by reaction with reactive gas species).     

Methodological issues in the validation of implicit measures: Comment on De Houwer, Teige-Mocigemba, Spruyt, and Moors (2009).

J. De Houwer, S. Teige-Mocigemba, A. Spruyt, and A. Moors’s (see record 2009-05290-001) normative analysis of implicit measures provides an excellent clarification of several conceptual ambiguities surrounding the validation and use of implicit measures. The current comment discusses an important, yet unacknowledged, implication of J. De Houwer et al.’s analysis, namely, that investigations addressing the proposed implicitness criterion (i.e., does the relevant psychological attribute influence measurement outcomes in an automatic fashion?) will be susceptible to fundamental misinterpretations if they are conducted independently of the proposed what criterion (i.e., is the measurement outcome causally produced by the psychological attribute the measurement procedure was designed to assess?). As a solution, it is proposed that experimental validation studies should be combined with a correlational approach in order to determine whether a given manipulation influenced measurement scores via variations in the relevant psychological attribute or via secondary sources of systematic variance. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Goal-directed responding is sensitive to lesions to the prelimbic cortex or basolateral nucleus of the amygdala but not to their disconnection.

The current view of instrumental conditioning indicates that performance in the early stage of training is maintained by a representation of the outcome, as indexed by its sensitivity to changes in the value of the reward. In the present study, the authors tested the effects of a disconnection of the prelimbic cortex (PL) and the basolateral nucleus of the amygdale (BLA), using an asymmetric lesion procedure, to determine whether these structures interact sequentially as part of a corticolimbic system. In marked contrast to the effects of bilateral lesions of the PL or the BLA, which both altered rats' sensitivity to outcome devaluation, the disconnection of these 2 brain areas was without an effect on outcome devaluation. These results demonstrate that the PL and the BLA mediate different aspects of outcome representation in goal-directed responding. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Special Economic Zones in South Africa: Reflections from International Debates

South Africa’s experience with spatial economic interventions has had a chequered history with the Industrial Development Zone programme most recently failing to generate anticipated development. Current policy has shifted to the imminent launch of Special Economic Zones (SEZs) as tools for national (re)industrial development and supporting underdeveloped regions. This paper reflects on recent South African experience with spatial economic interventions and international experience with SEZs paying particular attention to their strengths, weakness and key establishment considerations. It is argued that unfolding South African SEZ planning can be strengthened by learning from the ‘good’ and ‘bad practice’ of international SEZs.     

Registration and real-time visualization of transcranial magnetic stimulation with 3-D MR images

This paper describes a method for registering and visualizing in real-time the results of transcranial magnetic stimulations (TMS) in physical space on the corresponding anatomical locations in MR images of the brain. The method proceeds in three main steps. First, the patient scalp is digitized in physical space with a magnetic-field digitizer, following a specific digitization pattern. Second, a registration process minimizes the mean square distance between those points and a segmented scalp surface extracted from the magnetic resonance image. Following this registration, the physician can follow the change in coil position in real-time through the visualization interface and adjust the coil position to the desired anatomical location. Third, amplitude of motor evoked potentials can be projected onto the segmented brain in order to create functional brain maps. The registration has subpixel accuracy in a study with simulated data, while we obtain a point to surface root-mean-square error of 1.17+/-0.38 mm in a 24 subject study.     

Constant-distance mode scanning potentiometry. 1. Visualization of calcium carbonate dissolution in aqueous solution

Constant-distance mode scanning potentiometry was established by integrating potentiometric microsensors as ion-selective scanning probes into a SECM setup that was equipped with a piezoelectric shear force-based tip-to-sample distance control. The combination of specially designed micrometer-sized potentiometric tips with an advanced system for tip positioning allowed simultaneous acquisition of both topographic and potentiometric information at solid/liquid interfaces with high spatial resolution. The performance of the approach was evaluated by applying Ca(2+)-selective constant-distance mode potentiometry to monitor the dissolution of calcium carbonate occurring either at the (104) surface of calcite crystals or in proximity to the more complex surface of cross sections of a calcium carbonate shell of Mya arenaria exposed to slightly acidic aqueous solutions. Micrometer-scale heterogeneities in the apparent calcium activity profiles have successfully been resolved for both samples.     

Using bottom surface reflectance to map coastal marine areas: a new application method for Lyzenga's model

Remote sensing is widely used in coastal management. Lyzenga's model has been traditionally used to explain the relationship between bottom surface reflectance and the radiance level measured by satellite. Due to its central assumption, this model lacks accuracy compared with the other radiative transfer models. Nonetheless, it enables, with a single and simple equation, representation of the multiple optical processes taking place in coastal areas. Mapping processes associated with this model may include radiometric correction, a technique previously pointed out as a major driver of mapping accuracy. Radiometric correction is generally based on a depth-invariant index, efficient for clear waters (Jerlov water type I to II) but largely unsuitable when transparency decreases (Jerlov water type II to III). In order to overcome this problem, we developed a new index for radiometric correction, which combines bathymetry data with attenuation coefficients. The improved efficiency of our model with regard to the traditional depth invariant index was demonstrated through two case studies: Funakoshi Bay (Japan; Jerlov water type II) and the Gabes Gulf part located off Mahares (Tunisia; Jerlov water type II to III).     

SPOT5-HRS digital elevation models and the monitoring of glacier elevation changes in North-West Canada and South-East Alaska

Monitoring the response of land ice to climate change requires accurate and repeatable topographic surveys. The SPOT5-HRS (High Resolution Stereoscopic) instrument covers up to 120 km by 600 km in a single pass and has the potential to accurately map the poorly known topography of most glaciers and ice caps. The acquisition of a large HRS archive over ice-covered regions is planned by the French Space Agency (CNES) and Spotimage, France during the 2007–2008 International Polar Year (IPY). Here, we report on the accuracy and value of HRS digital elevation model (DEM) over ice and snow surfaces.

A DEM is generated by combining tools available from CNES with the PCI Orthoengine^SE software, using HRS images acquired in May 2004 over South-East Alaska (USA) and northern British Columbia (Canada). The DEM is evaluated through comparison with shuttle radar topographic mission (SRTM) DEM and ICESAT data, on and around the glaciers. A horizontal shift of 50 m is found between the HRS and SRTM DEMs and is attributed to errors in the SRTM DEM. Over ice-free areas, HRS elevations are 7 m higher than those of SRTM, with a standard deviation of ± 25 m for the difference between the two DEMs. The 7-m difference is partly attributed to the differential penetration of the electromagnetic waves (visible for HRS; microwave for SRTM) in snow and vegetation.

We also report on the application of sequential DEMs (SRTM DEM in February 2000 and HRS DEM in May 2004) for the monitoring of glacier elevation changes. We map the topographic changes induced by a surge of one tributary of Ferris Glacier. Maximum surface lowering of 42 (± 10) m and rising of 77 (± 10) m are observed in the 4 years time interval. Thinning rates up to 10 (± 2.5) m/yr are observed at low altitudes and confirm the ongoing wastage of glaciers in South-East Alaska.