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排序方式: 共有1100条查询结果,搜索用时 9 毫秒
81.
Solange Kazue Utimura Santiago Justo Arevalo Carlos Gonzalo Alvarez Rosario Mauro Quiones Aguilar Jorge Alberto Soares Tenrio Denise Crocce Romano Espinosa 《加拿大化工杂志》2019,97(11):2920-2927
In this study, the feasibility of using a biohydrometallurgical technique for selective metals recovery from electronic waste (e‐waste) by bacterial bioleaching was investigated. Acidithiobacillus was identified in coal mining acid mine drainage (AMD). The microorganism was studied using specific sequencing of a 16s rDNA fragment. The potential for the dissolution of copper from waste printed wire boards (PWBs) using the isolated Acidithiobacillus ferrooxidans (A. ferroxidans) was evaluated. The bioleaching experiments were performed in an orbital shaker at 30 °C and 170 rpm, with 10 % (v/v) inoculum and a pulp density of 30 g/L. The copper concentration was determined by energy dispersive x‐ray fluorescence (XRF). The result shows that copper recovery from PWBs using our A. ferrooxidans strain was 95 % after 8 days, which showed the feasibility of this process. 相似文献
82.
Carlo Dal Lin Claudia Maria Radu Giuseppe Vitiello Paola Romano Albino Polcari Sabino Iliceto Paolo Simioni Francesco Tona 《International journal of molecular sciences》2021,22(1)
Mechanical vibrations seem to affect the behaviour of different cell types and the functions of different organs. Pressure waves, including acoustic waves (sounds), could affect cytoskeletal molecules via coherent changes in their spatial organization and mechano-transduction signalling. We analyzed the sounds spectra and their fractal features. Cardiac muscle HL1 cells were exposed to different sounds, were stained for cytoskeletal markers (phalloidin, beta-actin, alpha-tubulin, alpha-actinin-1), and studied with multifractal analysis (using FracLac for ImageJ). A single cell was live-imaged and its dynamic contractility changes in response to each different sound were analysed (using Musclemotion for ImageJ). Different sound stimuli seem to influence the contractility and the spatial organization of HL1 cells, resulting in a different localization and fluorescence emission of cytoskeletal proteins. Since the cellular behaviour seems to correlate with the fractal structure of the sound used, we speculate that it can influence the cells by virtue of the different sound waves’ geometric properties that we have photographed and filmed. A theoretical physical model is proposed to explain our results, based on the coherent molecular dynamics. We stress the role of the systemic view in the understanding of the biological activity. 相似文献
83.
Ana Caroline Lustosa de Melo Carvalho Thiago de Sousa Fonseca Marcos Carlos de Mattos Maria da Concei??o Ferreira de Oliveira Telma Leda Gomes de Lemos Francesco Molinari Diego Romano Immacolata Serra 《International journal of molecular sciences》2015,16(12):29682-29716
Biocatalysis offers an alternative approach to conventional chemical processes for the production of single-isomer chiral drugs. Lipases are one of the most used enzymes in the synthesis of enantiomerically pure intermediates. The use of this type of enzyme is mainly due to the characteristics of their regio-, chemo- and enantioselectivity in the resolution process of racemates, without the use of cofactors. Moreover, this class of enzymes has generally excellent stability in the presence of organic solvents, facilitating the solubility of the organic substrate to be modified. Further improvements and new applications have been achieved in the syntheses of biologically active compounds catalyzed by lipases. This review critically reports and discusses examples from recent literature (2007 to mid-2015), concerning the synthesis of enantiomerically pure active pharmaceutical ingredients (APIs) and their intermediates in which the key step involves the action of a lipase. 相似文献
84.
Corien deGraaff Barry Oppelaar Olivier Pruch Christophe M. L. VandeVelde Beatrice Bechi Nicholas J. Turner Eelco Ruijter Romano V. A. Orru 《Advanced Synthesis \u0026amp; Catalysis》2016,358(10):1555-1560
We disclose the highly diastereoselective combination of monoamine oxidase‐catalyzed oxidation of meso‐pyrrolidines and aza‐Friedel–Crafts reactions in aqueous buffer to give valuable enantioenriched 2‐substituted pyrrolidines in a formal double C H activation process. A range of secondary as well as tertiary amines were shown to be suitable substrates for the biocatalytic oxidation and subsequent addition of a variety of C‐nucleophiles.
85.
Denis Prodius Fliur Macaev Valeriu Mereacre Sergiu Shova Yurii Lutsenco Eugenia Styngach Patricia Ruiz Dmitry Muraviev Janusz Lipkowski Yurii A. Simonov Constantin Turta 《Inorganic chemistry communications》2009,12(7):642-645
The novel μ3-oxo-bridged heterotrinuclear iron(III)-copper(II) trichloroacetates of the composition [Fe2CuO(CCl3COO)6(THF)3] (1a) and [Fe2CuO(CCl3COO)6(4-DMAP)3] (1b) have been synthesized and characterized by X-ray crystallography, IR and Mossbauer spectroscopy. These clusters were used as precursors for the synthesis of the nanosized catalytic system (~5–6 nm of γ-Fe2O3/CuO), which works as an efficient organic phase catalyst (~0.02 mol%) in a one-pot three component Biginelli synthesis. 相似文献
86.
Gassan Hodaifa Mª Eugenia Martínez Sebastián Sánchez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(10):1550-1558
BACKGROUND: The use of olive‐oil mill wastewater (OMW) from a three‐phase centrifugation process used in the olive‐oil industry, has been studied in relation to the production of the microalga Scenedesmus obliquus CCAP 276/3A. The chemical characteristics of OMW indicated nitrogen deficiency. RESULTS: S. obliquus is able to assimilate nutrients present in a culture medium (water‐OMW 5%) and grow at its maximum specific growth rate of 0.026 h?1, both under mixotrophic as well as heterotrophic conditions. The different daily doses of light (DDL) used, in the range 0–36 E m?2 d?1, determined light‐limited and light‐inhibited cultures. The light‐inhibited mixotrophic cultures bore characteristics similar to those of the heterotrophic cultures, and became more so when the dose of light received was higher. The low protein yield (258 mg g?1) and high percentage of carbohydrates of the biomass (65.8%) confirmed a nutritional‐stress situation associated with nitrogen limitation. CONCLUSION: The similarity between the fatty‐acid composition of the heterotrophic and mixotrophic cultures strongly inhibited by light appeared to indicate the cancelling of the photosynthetic behaviour of the cells at high DDL values. The biomass generated can be used for biofuels. The maximum elimination of biological oxygen demand (BOD5) per unit of biomass was achieved in the heterotrophic cultures. Copyright © 2009 Society of Chemical Industry 相似文献
87.
88.
José Ortiz-Landeros Maria Eugenia Contreras-García Heriberto Pfeiffer 《Journal of Porous Materials》2009,16(4):473-479
Macroporous ZrO2–Al2O3 mixed oxides with mesoporous walls were synthesized. The three-dimensional interconnected macroporous structures, of inorganic
zirconia–alumina mixed oxides containing different alumina compositions (25, 50, 100 wt%), were prepared by sol–gel method
from inorganic precursors and using polystyrene microspheres with diameters of 685 and 1520 nm as templates. The final porous
arrays with controllable pore size in the submicrometer range could be obtained by calcination of the organic template. The
structural characteristics are discussed. The physicochemical characterization of the samples was carried out by N2 physisorption (SBET), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission
electron microscopy (TEM). The shrinkage of pore diameter was approximately 35%, and the wall thickness of inorganic framework
varied between 135 and 154 nm. The specific surface areas, of the samples, were between 123 and 287 m2/g, obtaining the largest surface area with the highest alumina contents and the smallest templates. 相似文献
89.
Model oil-in-water emulsions containing epicatechin (EC) and epigallocatechin gallate (EGCG) showed a synergistic increase in stability in emulsions containing added albumin. EGCG showed a stronger synergy (35%) with ovalbumin than did EC. Oxidation of the oil was monitored by determining peroxide values and hexanal contents. The effect of bovine serum albumin (BSA) on model oil-in-water emulsions containing each of the green tea catechins [epicatechin gallate (ECG), EGCG, EC and epigallocatechin (EGC)] was studied during storage at 30 °C. The green tea catechins showed moderate antioxidant activity in the emulsions with the order of activity being ECG ≈ EGCG > EC > EGC. Although BSA had very little antioxidant activity in the absence of phenolic antioxidants, the combination of BSA with each of the catechins showed strong antioxidant activity. BSA, in combination with EC, EGCG or EGC, showing the strongest antioxidant activity with good stability after 45 days storage. Model experiments with the catechins stored with BSA in aqueous solutions confirmed that protein–catechin adducts with antioxidant activity were formed between the catechins and protein. The antioxidant activity of the separated protein–catechin adducts increased strongly with storage time and was stronger for EGCG and ECG than for EC or EGC. 相似文献
90.
双重图形需要更新更苛刻的刻蚀能力,要求低于1.5nm CD均匀性、图形收缩和原位多层刻蚀。 相似文献