Phase evolution in plasma sprayed Nb2O5 coatings

Nb₂O₅ polymorphism and defect chemistry depend on the temperature, pressure, atmosphere composition and the initial crystallography. Plasma spray of Nb₂O₅ is a pathway to form coatings with in-situ metastable and nonstoichiometric phases, however so far unexplored. This study aimed to understand the phase evolution of plasma sprayed Nb₂O₅ coatings, and its effect on their morphology and properties. Phase evolution from H-Nb₂O₅ in the feedstock, to T-Nb₂O₅, TT-Nb₂O₅, N-Nb₂O₅, H-Nb₂O₅, Nb₁₂O₂₉ and NbO₂ in the coatings depends on the plasma Ar/H₂ ratio and its related enthalpy. The microstructure shows a layered distribution of nonstoichiometric phases at the splat boundaries and splat cores composed of T-Nb₂O₅ or TT-Nb₂O₅. The presence and distribution of these phases are related to the thermomechanical and electrical properties. The mechanisms driving the formation of these coatings are based on the Nb₂O₅ incongruent vaporization which promote retention of nonstoichiometric phases and the rapid solidification of metastable phases.     

A new acousto-electro-optic improved resolution deflector for high frequency operation

The two main constrains on the characteristics of the acousto-optic deflector are the acoustic sound attenuation and velocity. These two parameters will determine the resolution and the radio frequency bandwidth. Due to a double degenerated phase matching condition on a specific acousto-optic deflector configuration, the possibility of an improvement on the resolution of the acousto optic deflector becomes evident. This degenerescence is the result of the action of a D.C. electric field by the electro-optic effect. This configuration presents several advantages upon the early related works based on optical activity of selected materials and enables a wideband interaction in such a way that the number of resolvable channels is kept high. This has implications on the acousto-optic spectrometers for wideband radio astronomy research.     

Test for a correlation between VΛ and the + y opponent-channel sensitivity

Rushtion and Baker have shown that the ratio of R to G cones varies between observers. We use this variability to ask if observers, say, who are rich in R-cone input to the flicker (VΛ) channel, are also likely to be rich in R-cone input to the long-wavelength half of the y-b channel. For the 8 observers tested, there is no correlation between cone inputs to +y and VΛ.     

Contribution of planar scintigraphy and SPECT with Ga-67 in the diagnosis of infectious complications after median sternotomy]

A phage-displayed combinatorial peptide library was used to define the specificity of one of the three Src homology 3 (SH3) domains in a novel cytoskeletal protein, named CAP, for Cbl Associated Protein. The C-terminal SH3 domain was used to affinity select peptides with the consensus, PXPPXRXSSL, from a library of X6PXXPX6 peptides. Peptide sequences resembling this consensus were identified in two signal transduction proteins, c-Cbl and son-on-sevenless (Sos), previously shown to interact with the C-terminal SH3 domain of CAP. Genetic fusion of 16 and 14 amino acid segments of c-Cbl and Sos, respectively, to bacterial alkaline phosphatase confirmed that these segments were potential ligand sites for the C-terminal SH3 domain of CAP. Alanine-scanning mutagenesis of the c-Cbl peptide ligand confirmed that most of the residues, which were conserved among the peptide ligands selected from the combinatorial peptide library, contributed to binding to the C-terminal SH3 domain of CAP.     

A graphical approach to relational reasoning

Relational reasoning is concerned with relations over an unspecified domain of discourse. Two limitations to which it is customarily subject are: only dyadic relations are taken into account; all formulas are equations, having the same expressive power as first-order sentences in three variables. The relational formalism inherits from the Peirce-Schröder tradition, through contributions of Tarski and many others.Algebraic manipulation of relational expressions (equations in particular) is much less natural than developing inferences in first-order logic; it may in fact appear to be overly machine-oriented for direct hand-based exploitation.The situation radically changes when one resorts to a convenient representation of relations based on labeled graphs. The paper provides details of this representation, which abstracts w.r.t. inessential features of expressions.Formal techniques illustrating three uses of the graph representation of relations are discussed: one technique deals with translating first-order specifications into the calculus of relations; another one, with inferring equalities within this calculus with the aid of convenient diagram-rewriting rules; a third one with checking, in the specialized framework of set theory, the definability of particular set operations. Examples of use of these techniques are produced; moreover, a promising approach to mechanization of graphical relational reasoning is outlined.     

Comparative susceptibility of Pyrenean and Brown Swiss calves to gastrointestinal nematodes in subclinical naturally acquired infections

The susceptibility of two common breeds of cattle in the Pyrenees, Brown Swiss and Pyrenean breed, to parasitism by gastrointestinal nematodes was studied. Twenty-two female calves (13 Brown Swiss and 9 Pyrenean), 3 months old with a mean weight of 112.8 +/- 18.33 and 103.3 +/- 17.11 kg respectively at the start of the study, were used. The calves began their first grazing season grazing with 200 cattle following the traditional grazing system for mountainous areas: Stabling during winter (December-April), grazing on harvesting meadows at an elevation of 900 m in the spring (May-June) and autumn (October-November), and grazing areas between 1200-2100 m during the summer (July-September). Faeces, blood samples and calves growth rate were taken at 2-week intervals throughout the grazing season. Faecal egg counts of gastrointestinal nematodes, level of serum pepsinogen, total serum protein and blood parameters were measured. The worm egg counts and Cooperia sp. counts were significantly smaller in the calves of Pyrenean breed than in Brown Swiss throughout the experiment. Numbers of eggs of the other genera of parasites found were smaller in the calves of Pyrenean breed than in calves of Brown Swiss breed, but no statistical differences were found. Blood was compared during two periods: the prepatent and patent periods. During the first period, no differences were found between the breeds for any parameter studied. However, during the patent period, Pyrenean animals had significantly greater numbers of erythrocytes, haemoglobin values and packed cell volume (PCV) values, and smaller numbers of eosinophils than animals of the Brown Swiss breed. No differences were found in the level of serum pepsinogen, total serum protein and live weight gains between the two breeds.     

Convexity and convex approximations of discrete-time stochastic control problems with constraints

We investigate constrained optimal control problems for linear stochastic dynamical systems evolving in discrete time. We consider minimization of an expected value cost subject to probabilistic constraints. We study the convexity of a finite-horizon optimization problem in the case where the control policies are affine functions of the disturbance input. We propose an expectation-based method for the convex approximation of probabilistic constraints with polytopic constraint function, and a Linear Matrix Inequality (LMI) method for the convex approximation of probabilistic constraints with ellipsoidal constraint function. Finally, we introduce a class of convex expectation-type constraints that provide tractable approximations of the so-called integrated chance constraints. Performance of these methods and of existing convex approximation methods for probabilistic constraints is compared on a numerical example.