Advanced oxidation processes are defined as those which involve the generation of hydroxyl radicals in sufficient quantity to affect water purification. The theoretical and (practical yield of OH from O3 at high pH, 03/H202, O3/UV and H2O2/UV systems is reviewed. New data is presented which illustrates the importance of direct photolysis in the O3/UV process, the effect of the H202:03 ratio in the O3/H2O2 process, and the impact of the low extinction coefficient of H2O2 in the H202/UV process. 相似文献
Summary The chemical process of preparing poly(vinylchloride)-polypyrrole composite films with high electrical conductivity and transparency has been studied. Pyrrole has been diffused into the poly(vinylchloride) matrix in the swelling medium of n-hexane and acetone mixture. The oxidative polymerization of the diffused pyrrole in the binary solvent system of acetonitrile and methanol gives high conductivity of the polypyrrole as well as the good penetration of the oxidant into the PVC polymer matrix. The analytical testing of the composite film shows the formation of homogeneous mixture of polypyrrole and poly(vinylchloride) conductive layer within the 1.0m of thickness on the film surface. The transparency of the composite film showed about 50–60% at 500 nm. The electrical conductivity of the composite was about 20 s/cm. 相似文献
In this paper, a robust video zero-watermarking scheme for copyright protection using a combination of convolutional neural network (CNN) and self-organizing map (SOM) in polar complex exponential transform (PCET) space is presented. The scheme is developed not only to remedy the existing problems of lacking in some performance assessments but also to enhance the robustness. It starts with extracting the content feature of each frame by CNN and then some significant frames are selected using SOM clustering and maximum entropy. Secondly, the PCET is applied to all selected frames to abstract invariant moments, and further, is scrambled by a chaotic logistic map and is reduced in dimensions by singular value decomposition (SVD). Next, a binary sequence is generated by comparing adjacent values of the obtained compact PCET moments in the previous step, and further is permuted to produce a binary matrix. Finally, a bitwise exclusive-OR operation is imposed on the binary matrix and the encrypted watermark by the chaotic map to generate a zero-watermark signal. Experimental results demonstrate that the proposed scheme has adequate equalization and distinguishability of zero-watermarks as well as strong robustness against common signal processing, geometric, compression, and inter-frame attacks. Also, compared with existing video zero-watermarking and traditional video watermarking methods, the proposed scheme exhibits superior robustness.
This paper presents a power-smoothing scheme of a variable-speed wind turbine generator (VSWTG) that employs separate control gains for the over-frequency section (OFS) and under-frequency section (UFS). In the proposed scheme, an additional proportional control loop based on the system frequency deviation operating in conjunction with maximum power point tracking operation is used. In the OFS, to improve the energy-storing capability, the scheme suggests the gain of the frequency deviation control loop, which is set to be monotonously decreasing with the rotor speed while being significantly larger than that in the UFS. In the UFS, to improve the energy-releasing capability while preventing over-deceleration, the gain of the frequency deviation control loop is set to be a linear function of the rotor speed. The simulation results under continuously varying wind speeds with different wind patterns and wind speeds clearly demonstrate that the proposed scheme significantly mitigates the output power fluctuations of a VSWTG. The proposed scheme keeps the frequency within a narrow range, thereby reducing the required primary frequency control reserve for regulating the frequency under normal operations.
