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71.
The frequency dependence of the electron-paramagnon spectrumP() in Pd is calculated within the finite bandwidth model. It is found that for an almost full band, the magnitude, the range, and the position of the peak frequency inP() are dramatically reduced compared to their values in the usual paramagnon theory. Also, we find that the frequency dependence of the spin-fluctuation contribution to the electron self-energy is strongly affected by a close proximity of the Fermi level to the top of the band. We speculate that an unusually large value of the Coulomb pseudopotential is probably partially responsible for the absence of superconductivity in Pd.  相似文献   
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74.
The efficiency of the process of refining technical boron nitride was assessed based on calculations of the chemical equilibrium in the B-N-O-C-Cl-H system. Three refining mixtures, CCl4 + H2, CCl4 + NH3 and CHCl3 + NH3, were considered. The analysis indicates that the use of ammonia-containing mixtures is more convenient, a lower residual oxygen content, lower contamination of the product by carbon and a better overall boron balance emerging. The calculations of the equilibrium composition of the solid phase enabled suitable technological conditions of the refining process (temperature and starting composition of the gaseous phase) to be established. The calculated results are compared with experimental data, and some observed differences are discussed.  相似文献   
75.
The formation of oxide phases in the system (1 -x) Fe2O3 +xGd2O3 was investigated for 0 x 1. On the basis of XRD measurements the distribution of oxide phases, -Fe2O3, Gd3Fe5O12, GdFeO3 and Gd2O3 was determined, as a function ofx. No solid solutions were observed with certainty even at the very ends of the concentration range. This was also confirmed by57Fe Mössbauer spectroscopy. New accurate crystallographic data for Gd3Fe5O12 are given. The formation of oxide phases in the system Fe2O3- Gd2O3 is compared with the data for analogous system Fe2O3-Eu2O3.  相似文献   
76.
This paper presents an empirical study of the relations between scientific output and collaboration performed on two scales: (1) an individual scale, for members of a study model, and (2) a group scale, for three samples varying in the level of productivity. The rank approach was applied in the preparation of the study model resulting in the selection of a set of the most prolific authors. In the course of that process, multiple authorship problem was solved by a dual approach, consisting of normal count and modified straight count procedures. As shown by the analysis of collaborative patterns, either on individual or on group scales, scientific output is highly dependent on the frequency of collaboration among the same authors. Expressed as the collaboration measure, it might serve as an indicator in comparative analyses of scientific productivity in a given field of science.  相似文献   
77.
This paper studies the behavior of motions of large-scale (LS) semistate systems (SSS) governed byP i (t)x i =M i (t,x i )x i +f i (t)+h i (t, x), i=1,2,...,s, =(x 1 T x 2 T x s T )T, where matricesP i (t) are singular. Using Lyapunov's approach and the tools for LS system analysis, a variant of attractivity and ultimate boundedness of appropriate time-variable sets are investigated. The results are based on a specific choice of the aggregate functions. It is assumed that the reduction of equations to a normal form of lower order is inconvenient. The aggregation-decomposition approach used in this paper reduces the dimensionality of an aggregate matrix of the system to the number of its systems. Motion properties of LS systems are deduced from the properties of its isolated subsystems, the character of interconnections, and the conditions imposed on the system aggregate matrix. Sufficient algebraic conditions for the above-mentioned motion properties are developed.  相似文献   
78.
The magnetic structure of a vortex in the presence of an anisotropic inhomogeneity distribution is calculated within the London model. The anisotropic supercurrent pattern consists of closed current loops, superimposed on a backflow pattern. The nonvanishing current density at the vortex core gives rise to an intrinsic Lorentz force identical with the pinning force resulting from the spatial variation of the vortex self-energy.  相似文献   
79.
Catalysis Letters - Industrial Cu/ZnO/Al2O3 or novel rate catalysts, prepared with a photochemical deposition method, were studied under functional CH3OH synthesis conditions at the set temperature...  相似文献   
80.
Exosomes are extracellular vesicles that contain nucleic acids, lipids and metabolites, and play a critical role in health and disease as mediators of intercellular communication. The majority of extracellular vesicles in the blood are platelet-derived. Compared to adults, neonatal platelets are hyporeactive and show impaired granule release, associated with defects in Soluble N-ethylmaleimide-sensitive fusion Attachment protein REceptor (SNARE) proteins. Since these proteins participate in biogenesis of exosomes, we investigated the potential differences between newborn and adult plasma-derived exosomes. Plasma-derived exosomes were isolated by ultracentrifugation of umbilical cord blood from full-term neonates or peripheral blood from adults. Exosome characterization included size determination by transmission electron microscopy and quantitative proteomic analysis. Plasma-derived exosomes from neonates were significantly smaller and contained 65% less protein than those from adults. Remarkably, 131 proteins were found to be differentially expressed, 83 overexpressed and 48 underexpressed in neonatal (vs. adult) exosomes. Whereas the upregulated proteins in plasma exosomes from neonates are associated with platelet activation, coagulation and granule secretion, most of the underexpressed proteins are immunoglobulins. This is the first study showing that exosome size and content change with age. Our findings may contribute to elucidating the potential “developmental hemostatic mismatch risk” associated with transfusions containing plasma exosomes from adults.  相似文献   
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