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91.
92.
Woźnica E Wójcik MM Wojciechowski M Mieczkowski J Bulska E Maksymiuk K Michalska A 《Analytical chemistry》2012,84(10):4437-4442
For the first time, application of a membrane composed of gold nanoparticles decorated with complexing ligand for potentiometric sensing is shown. Gold nanoparticles drop cast from a solution form a porous structure on a substrate electrode surface. Sample cations can penetrate the gold nanoparticles layer and interact with ligand acting as a charged ionophore, resulting in Nernstian potentiometric responses. Anchoring of complexing ligand on the gold surface abolishes the necessity of ionophore application. Moreover, it opens the possibility of preparation of potentiometric sensors using chelators of significantly different selectivity patterns further enhanced by the absence of polymeric membrane matrix. This was clearly seen, for example, for gold nanoparticles stabilizing the applied ligand-dithizone-thiol conformation leading to a high potentiometric selectivity toward copper ions, much higher than that of ionophores typically used to induce selectivity for polymeric ion-selective membranes. 相似文献
93.
Beata Zielińska Ewa Borowiak-PalenBarbara Grzmil Ryszard J. Kalenczuk 《Journal of Alloys and Compounds》2011,509(17):5414-5419
Titanate nanorods with high photocatalytic activity was successfully synthesized through a simple catalyst-free hydrothermal method. The photocatalytic degradation of a model organic dye (Reactive Red 198) was accelerated by the calcination of the nanorods prior the reaction. The calcination of nanorods did not modify their morphology, however the crystallinity of the samples was significantly improved. Therefore, the quality of the samples is a key parameter determining their activity in the investigated photocatalytic process. The as-produced and annealed catalysts were characterized by high-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), Diffuse Reflectance (DR) UV-Vis and resonance Raman spectroscopy. 相似文献
94.
The effect of different cooking times on the GLS content in white cabbage (Brassica oleracea L. var. capitata f. alba) was determined. Cooking of cabbage for 5-30 min caused a gradual decrease in the GLS content. The most efficient reduction of the GLS content (by about 35%) occurred during the first minutes of cooking. As the cooking time was extended by another 5 min, each time the GLS content decreased by 10-15%. Higher losses in indole GLS, as compared to those of aliphatic ones, resulted from more efficient diffusion of those compounds to cooking water. The GLS content in cooking water, irrespective of the cooking time of white cabbage, remained rather stable, whereas the content of indole GLS was between 3.5- and 4-fold higher in comparison to that of aliphatic GLS. Taking into consideration the rate of changes in the content of particular GLS in cabbage and the GLS content in cooking water, it can be stated that glucoiberin was more thermolabile than other GLS. 相似文献
95.
Ewa Jakubczyk Ewa Ostrowska‐Ligeza Ewa Gondek 《International Journal of Food Science & Technology》2010,45(12):2515-2523
The aim of this study was to characterise the influence of different foam‐mat‐drying methods on the moisture sorption characteristics and glass transition temperatures of apple puree powder. Apple puree was foamed with the addition of 2.5% egg albumin and 0.5% methylcellulose. Convective air‐drying and microwave‐drying techniques were used. Also foamed puree with and without maltodextrin (6% or 15% w/w) was freeze‐dried. Moisture equilibrium data of powders were determined by using a static desiccator method in a water activity range of 0.0–0.903. Modulated differential scanning calorimetry (MDSC) was used to obtain the glass transition temperature. No effect of drying method on sorption properties and glass transition temperatures of apple puree powders was observed. The addition of maltodextrin to the apple puree caused an increase in Tg by 10–30 °C depending on the amount of incorporated additive. Addition of maltodextrin significantly reduced the hygroscopicity of apple puree powders. 相似文献
96.
Ryszard Siuda Andrzej Grabowski Leszek Lenc Maria Ralcewicz Ewa Spychaj‐Fabisiak 《International Journal of Food Science & Technology》2010,45(12):2596-2604
The paper aims to enlarge the current knowledge about the dependence of technological traits of wheat grain on its degree of infestation (DI) with fusariosis. Samples of grain of four wheat cultivars were obtained from naturally grown crops (control) and from crops inoculated with Fusarium culmorum from which three degrees of kernel infestation were selected. Samples were determined for thousand kernels weight (TKW), total protein, starch and wet gluten (WG) contents, Hagberg falling number (HFN) and sedimentation value (SV). Content of protein and wet gluten showed higher values for moderately infested kernels (up to 15 and 25%, respectively, when compared to control grain) than for kernels lightly or heavily infested. All the remaining traits had values lower than that for control grain and showed a decrease with increasing DI. Decrease for the heaviest infestation was on average: 8, 29, 31 and 34% for starch, TKW, HFN and SV, respectively. 相似文献
97.
The influence of thermal treatment, pickling and fermentation on the content of glucobrassicin and its selected breakdown products in broccoli and cauliflower was investigated. The highest content of glucobrassicin and the lowest content of its breakdown products were found in vegetables which underwent thermal treatment such as boiling and steam cooking. The lowest content of glucobrassicin and the highest content of its breakdown products were present in raw, pickled and fermented vegetables in which the myrosinase remained active. Ascrobigen was the major glucobrassicin breakdown product and its content was negatively correlated with glucobrassicin content in broccoli and cauliflower. After heating of vegetables in 60 °C for 20 min (causing thermal deactivation of epithiospecific protein) no presence of indole-3-acetonitrile was found. 相似文献
98.
Study of self-stratifying compositions 总被引:2,自引:0,他引:2
Helena Kuczyńska Ewa Langer Elżbieta Kamińska-Tarnawska Dmitry A. Kulikov Eugene A. Indeikin 《Journal of Coatings Technology and Research》2009,6(3):345-352
Paint applied as a single layer, and its spontaneous separation to form a primer and a top coat, is one of the newest concepts
of the effective and economical application of two layers in one step. The influence of the molecular weight of epoxy oligomer
and acrylic polymer and their ratio on self-stratification was investigated. The degree of stratification depending on molecular
weight and their mutual ratio was determined using ATR-FTIR spectroscopy, differential scanning calorimetry, microscopy techniques,
adhesion tests, and surface tension measurements. Phase separation and self-stratification of two-component homogenous mixtures
were followed using FTIR technique and surface tension measurements. As a result of these investigations, optimal oligomeric/polymeric
composition was selected. The obtained coating system showed good mechanical properties, gloss, and interlayer adhesion. 相似文献
99.
The peroxide-initiated copolymerisation of an unsaturated polyester with zinc acrylate, diallyl phthalate prepolymer and a solid vinyl ester resin was investigated. The curing was followed by means of gelation curves and differential scanning calorimetry. The studies showed that zinc acrylate has the highest reactivity. 相似文献
100.