Crystallization kinetics of poly(vinylidene fluoride)

Specimens of poly(vinylidene fluoride) were crystallized isothermally at a series of temperatures in the vicinity of the melting point. The -form was the only crystalline polymorph present in the crystallized samples. Crystallization rates have been measured by differential scanning calorimetry. The results were analysed in terms of the Avrami equation. The rates of crystallization depend upon the undercooling and the data agree with a process of growth of spherulites controlled by a secondary surface coherent nucleation mechanism. The equilibrium melting temperature, the Avrami exponent, the free energy of formation of a nucleus of critical dimensions and the surfaces free energy of the lamellar crystallites were determined.     

Effects of storage conditions on rat brain ethanolamine glycerophospholipids,cerebrosides, and cholesterol

The effects of storage on rat brain lipid composition were studied in terms of ethanolamine glycerophospholipid, cerebrosides, and cholesterol. Rat brains were stored at several combinations of temperature and time. Storage conditions were: 2 hr at room temperature, 12 hr of refrigeration, and a sequence of both of these conditions. Two-dimensional thin layer chromatography followed by colorimetric analyses of eluted lipids were used to determine molar ratios of phosphatidylethanolamine, ethanolamine plasmalogen, lysophosphatidylethanolamine, and cerebrosides. Cholesterol was also determined. These studies revealed small but significant increases in lysophosphatidylethanolamine in all three cases. A slight increase was also noted in the apparent molar proportion of cholesterol.     

Influence of low molecular weight polyoxyethylene on bulk crystallization and melting behaviour of poly(oxymethylene diacetate)

The effects of low molecular weight polyoxyethylene (POE) on crystallization kinetics, radial growth rate of spherulites and crystallite long period of melt crystallized poly(oxymethylene diacetate) (POMDA) have been investigated with different techniques (optical microscope, calorimetry, small-and wide-angle X-ray scattering). The results obtained suggest that the POE affects both the crystallization kinetics and equilibrium thermodynamic quantities of fusion of POMDA. This influence can probably be attributed to the lower concentration of defects in the crystalline layers of the polyoxymethylene lamellae and interaction of part of the additive with the amorphous phase.     

Strain-rate behavior in tension of the tempered martensitic reduced activation steel Eurofer97

The tensile properties of the high-chromium tempered martensitic reduced activation steel Eurofer97 were determined from tests carried out over a wide range of strain-rates on cylindrical specimens. The quasi-static tests were performed with a universal electro-mechanical machine, whereas a hydro-pneumatic machine and a JRC-split Hopkinson tensile bar apparatus were used for medium and high strain-rates respectively. This tempered martensitic stainless steel showed significant strain-rate sensitivity. The constitutive behavior was investigated within a framework of dislocations dynamics model using Kock’s approach. The parameters of the model were determined and then used to predict the deformation range of the tensile deformation stability. A very good agreement between the experimental results and predictions of the model was found.     

Asymptotic Capacity of Static Multiuser Channels Under Optimal User Identification and Data Detection

We examine a multiple-access communication system in which multiuser detection is performed without knowledge of the number of active interferers. Using a statistical-physics approach, we compute the single-user channel capacity and spectral efficiency in the large-system limit and derive their limiting values for high SNR.     

End‐functional polymers,thiocarbonylthio group removal/transformation and reversible addition–fragmentation–chain transfer (RAFT) polymerization

This review focuses on processes for thiocarbonylthio group removal/transformation of polymers synthesized by radical polymerization with reversible addition‐fragmentation‐chain transfer (RAFT). A variety of processes have now been reported in this context. These include reactions with nucleophiles, radical‐induced reactions, thermolysis, electrocyclic reactions and ‘click’ processes. We also consider the use of RAFT‐synthesized polymers in the construction of block or graft copolymers, functional nanoparticles and biopolymer conjugates where transformation of the thiocarbonylthio group is an integral part of the process. This includes the use of RAFT‐synthesized polymers in other forms of radical polymerization such as atom transfer radical polymerization or nitroxide‐mediated polymerization, and the ‘switching’ of thiocarbonylthio groups to enable control over polymerization of a wider range of monomers in the RAFT process. With each process we provide information on the scope and, where known, indicate the mechanism, advantages and limitations. Copyright © 2011 Society of Chemical Industry     

Thermodynamic analysis and experimental investigation of a CO2 household heat pump dryer

Carbon dioxide is regarded as an optimal working fluid for heat pump dryers. The transcritical cycle well fits the closed-loop drying process which requires dehumidification and re-heating according to high temperature lift of the air stream.In this paper, the transcritical CO₂ cycle is compared with a sub-critical R134a cycle. The theoretical analysis is based on fixed temperature approach values at the heat exchangers. The study considers optimal high pressure for the transcritical cycle and optimal refrigerant subcooling for the sub-critical cycle. The theoretical analysis investigates the energy performance of the thermodynamic cycle as a function of the temperature and mass flow rate of the drying air. The optimisation of the operating conditions for CO₂ involves lower air temperature than in the case of R134a; this conditions can be satisfied by a suitable design of the appliance, whose thermal balance is achieved when the dissipated heat corresponds to the work spent by the compressor and the fan; the air temperature is a floating variable that adjusts its value to comply with the thermal balance. Experimental results, conducted on a prototype, give a positive assessment for CO₂ as working fluid for heat pump dryers: a negligible decrease in the electric power consumption, with a limited (+9%) increase in the cycle time, is shown in comparison with the reference R134a heat pump dryer.     

V2V protocols for traffic congestion discovery along routes of interest in VANETs: a quantitative study

One of the most interesting and promising challenges for Intelligent Transportation Systems (ITSs) relates to the traffic congestion problem. Congestion is a relevant issue for transportation because it reduces the efficiency of infrastructure and increases travel time, air pollution, and fuel consumption. Nowadays, the most promising technology in support of ITSs is found in the domain of Vehicular Ad Hoc Networks (VANETs). In this paper, we propose three protocols that are able to transmit traffic information for routes of interest on VANETs without any Road Side Unit (RSU) support. The proposed protocols adopt strategies to improve the performance of packet routing based on the density and location of vehicles; moreover, they enable an interesting comparison of the performance achievable with either reactive or proactive approaches. The extensive performance results reported show how it is possible to limit the congestion monitoring overhead along Routes of Interest (ROIs), while maintaining a sufficiently high performance in terms of traffic reporting. This may be done by employing context‐aware data delivery techniques that autonomously adapt to runtime conditions. Copyright © 2016 John Wiley & Sons, Ltd.