Retardation effect of superplasticizer on different cement fractions

Cement hydration is a complex chemical process strongly influenced by the proportions of the various minerals present in the cement, admixtures, and the size of the cement particles. In this note, it is shows that naphthalene based superplasticizer, used at high dosage, does not affect the total heat of hydration but retards the hydration process of portland cement. This retardation, however, is most effective on the medium size fraction of the cement (4 – 30 μm in our case). The superplasticizer does not affect the hydration of the fine fraction (< 4 μm) to that extent due to its richer concentration of SO₃ and alkalies. The coarse fraction of the cement (30 – 72 μm) does not participate (with or without superplasticizer) in the heat evolution process.     

Hydration/dehydration characteristics of struvite and dittmarite pertaining to magnesium ammonium phosphate cement systems

Struvite, an important reaction product in magnesium ammonium phosphate cement systems, was synthesized in the laboratory. The elevated-temperature dehydration and then roomtemperature hydration characteristics of the dehydrated products were studied by thermogravimetric analyses and X-ray diffraction techniques. From isothermal experiments, struvite is found to be thermally unstable in air at temperatures above 50 C. Struvite can lose part or all of its ammonia and water molecules depending on the time and temperature of heat treatment, ultimately forming magnesium hydrogen phosphate. This decomposed product is X-ray amorphous and upon room-temperature rehydration can form struvite, unknown hydrates or newberyite, alone or in combination with each other, depending on the amount of ammonia left in the structure. However, when struvite is heated in excess water, it only loses its water of crystallization to form the monohydrate, dittmarite. Dittmarite is thermally more stable than struvite and like struvite also forms magnesium hydrogen phosphate on decomposition. At room temperature and in the presence of excess water, dittmarite can slowly transform to the hexahydrate, struvite. The consequence of structural similarities between struvite and dittmarite and conditions under which they may be present in cured cements are described.     

Lab-scale feasibility study on new elastomer comprising chloroprene and acrylonitrile for oil and gas applications

The limited options of suitable elastomers with adequate cost-performance balance drive the necessity to introduce new materials in the oil & gas (O&G) application space. The relevance of a recently developed copolymer of chloroprene and acrylonitrile (referred to as acrylonitrile–chloroprene rubber or NCR) to O&G applications is described in this technical contribution. The new elastomer demonstrates adequate physical properties and reasonably good high and low-temperature capabilities. It offers good resistance to several aqueous and non-aqueous fluids with low volume swelling and retains its physical properties to reasonable extents while exposed to hot test oils. Acrylonitrile–chloroprene rubber has been found to sustain “sour gas” exposure. Good abrasion resistance, high tear strength, and remarkably high flex-fatigue resistance coupled with low heat build-up reflect its durability under dynamic conditions. In addition, acrylonitrile–chloroprene rubber can very well withstand the rapid gas decompression test at 25°C. This unique combination of attributes may allow acrylonitrile–chloroprene rubber to be considered as a candidate material for high-performance O&G applications.     

Robustness measure of hybrid intra-particle entanglement,discord, and classical correlation with initial Werner state

Quantum information processing is largely dependent on the robustness of non-classical correlations, such as entanglement and quantum discord. However, all the realistic quantum systems are thermodynamically open and lose their coherence with time through environmental interaction. The time evolution of quantum entanglement, discord, and the respective classical correlation for a single, spin-1/2 particle under spin and energy degrees of freedom, with an initial Werner state, has been investigated in the present study. The present intra-particle system is considered to be easier to produce than its inter-particle counterpart. Experimentally, this type of system may be realized in the well-known Penning trap. The most stable correlation was identified through maximization of a system-specific global objective function. Quantum discord was found to be the most stable, followed by the classical correlation. Moreover, all the correlations were observed to attain highest robustness under initial Bell state, with minimum possible dephasing and decoherence parameters.     

Stable Scheduling Policies for Maximizing Throughput in Generalized Constrained Queueing Systems

We consider a class of queueing networks referred to as "generalized constrained queueing networks" which form the basis of several different communication networks and information systems. These networks consist of a collection of queues such that only certain sets of queues can be concurrently served. Whenever a queue is served, the system receives a certain reward. Different rewards are obtained for serving different queues, and furthermore, the reward obtained for serving a queue depends on the set of concurrently served queues. We demonstrate that the dependence of the rewards on the schedules alter fundamental relations between performance metrics like throughput and stability. Specifically, maximizing the throughput is no longer equivalent to maximizing the stability region; we therefore need to maximize one subject to certain constraints on the other. Since stability is critical for bounding packet delays and buffer overflow, we focus on maximizing the throughput subject to stabilizing the system. We design provably optimal scheduling strategies that attain this goal by scheduling the queues for service based on the queue lengths and the rewards provided by different selections. The proposed scheduling strategies are however computationally complex. We subsequently develop techniques to reduce the complexity and yet attain the same throughput and stability region. We demonstrate that our framework is general enough to accommodate random rewards and random scheduling constraints.     

Intergranular structure in dental amalgams

The existence of an intergranular precipitate that provides a structural basis of creep, intergranular corrosion and thermal instability in dental amalgams has been in dispute. Also in dispute is a related matter concerning the solid solubility of Sn in ₁. Both these aspects have been examined in this differential scanning calorimetry (DSC) study using the following materials: (a) a conventional ₂–containing amalgam, (b) six ₂–free amalgams, and (c) a series of ₁ specimens with up to 4 wt% Sn. It has been observed that the solid solubility of Sn in ₁ is about 1.0 wt%. Above this Sn concentration, an intergranular precipitate, identified as the ₂ phase of the SnHg system, appears in ₁. This phase is characterized by a low melting temperature (90°C). The existence of this phase in the conventional dental amalgam has been confirmed. It has been observed further that the ₂–free dental amalgams, depending on their nature and Hg contents, may contain ₂ either as a transient or a permanent phase.     

Why quality of life measures should be used in the treatment of patients with respiratory illness

Treatment of airways disease is directed towards improving patients' health and well-being. Measurements of airways function do not reflect all the disease activity present in the airways that may affect the patient. Spirometry correlates poorly with health. Physicians appear to estimate their patients' health using criteria different from the patients themselves. Quality of life questionnaires provide a method of quantifying the effect of disease on patients' lives. They can summarize a number of aspects of the disease and provide an overall estimate of the effect of disease and benefits due to therapy. They have the potential to identify a threshold response to treatment that may be considered "worthwhile", and allow comparison between therapies with respect to the health gain that each provides.     

Arthroscopic Bankart repair with the Suretac device. Part I: Clinical observations

Although arthroscopic Bankart repair has become an accepted surgical stabilization technique for anterior shoulder instability, the failure rate remains unacceptably high. Little information is available concerning healing of the Bankart repair. The purpose of this article is to clarify this issue by analyzing a cohort of 15 patients who underwent a "second-look" arthroscopy to evaluate and treat pain or recurrent instability following arthroscopic Bankart repair with the Suretac device (Acufex Microsurgical, Mansfield, MA). "Second-look" arthroscopy was performed at an average of 9 months following the index surgical procedure. The reasons for this second surgery were recurrent instability in 7, pain in 6, and pain and stiffness in 2. In the 7 patients with recurrent instability, the Bankart repair was found to be completely healed in 3 (43%), partially healed in 1 (14%), and had recurred in 3 (43%); however, 6 of 7 were observed to have lax capsular tissue. In 4 of these cases, retrospective review of the index surgical procedure showed that a technical error had been made during the repair. Two cases had biopsy of the repair site on "second-look" at 6 to 8 months, and this showed residual polyglyconate polymer debris surrounded by a histiocytic infiltrate. In the remaining 8 cases with stable shoulders, the Bankart repair had completely healed in 5 cases (62.5%) and partially healed in 3 cases (37.5%). The higher failure rate with this approach compared with open approaches appears to result from improper patient selection and errors in surgical technique. There is some question concerning healing strength of the Bankart repair, although complete healing of the Bankart does not seem to be a prerequesite for shoulder stability. Success of the procedure might be expected to improve by selecting only patients with unidirectional, posttraumatic, anterior instability who are found to have a discrete Bankart lesion and well-developed ligamentous tissue.     

Secrecy Trade-off at the Physical Layer over Mixed Fading Multicast Channels Employing Antenna Diversity

This paper deals with the secrecy performance analysis of a multicast network over mixed fading scenarios in which a cluster of passive eavesdroppers is trying to overhear the secret transmission. Our key contribution is to prevent this malicious attack of the illegitimate receivers. Rayleigh/ Rician mixed fading channels are considered to model alternately the multicast/ eavesdropper and eavesdropper/ multicast channels as such mixed fading scenarios are often encountered in cellular communication where only one link (either multicast or eavesdropper) undergo a line-of-sight propagation path. At first, we derive the probability density functions for the single-input-multiple-output multicast scenarios and then the secrecy analysis is carried out by obtaining closed-form expressions for the performance matrices such as the probability of non-zero secrecy multicast capacity, ergodic secrecy multicast capacity, and secure outage probability for multicasting. The derived expressions are beneficial to investigate how the antenna diversity can combat the detrimental impact of fading as well as the number of multicast users and eavesdroppers, and improve the secrecy level to the acceptable limit. Moreover, the best secure scenario in terms of the secrecy parameters is obtained when the multicast channels undergo Rician fading whereas the eavesdropper channels experience Rayleigh fading. Finally, the analytical expressions are justified via the Monte-Carlo simulations.