聚合转化率对硫调型氯丁胶结构与性能的影响

研究了硫调型氯丁橡胶乳液聚合中转化率对产晶结构与性能的影响.结果表明,随单体转化率的提高,聚合物的凝胶量及其交联密度增大,致使断链速度减慢,所得断链胶的门尼粘度上升,残存凝胶量增加,分子支化程度增大,分子量分布变宽,焦烧时间缩短。而相应硫化胶的拉伸强度、撕裂强度、冲击弹性和硬度等提高,扯断伸长率和永久变形下降。这些变化一般在转化率为80——85％时有明显转折.综合考虑产量与质量,聚合转化率控制在82±2％较为适宜。     

Shape‐memory polyurethane/multiwalled carbon nanotube fibers

Shape‐memory polyurethane/multiwalled carbon nanotube (SMP–MWNT) composites with various multiwalled carbon nanotube (MWNT) contents were synthesized, and the corresponding SMP–MWNT fibers were prepared by melt spinning. The influence of the MWNT content on the spinnability, fracture morphology, thermal and mechanical properties, and shape‐memory behavior of the shape‐memory polymer was studied. The spinning ability of SMP–MWNTs decreased significantly with increasing MWNT content. When the MWNT content reached 8.0 wt %, the fibers could not be produced because of the poor rheological properties of the composites. The melt‐blending, extrusion, and melt‐spinning processes for the shape‐memory fiber (SMF), particularly at low MWNT contents, caused the nanotubes to distribute homogeneously and preferentially align along the drawing direction of the SMF. The crystallization in the SMF was promoted at low MWNT contents because it acted as a nucleation agent. At high MWNT contents, however, the crystallization was hindered because the movement of the polyurethane chains was restricted. The homogeneously distributed and aligned MWNTs preserved the SMF with high tenacity and initial modulus. The recovery ratio and recovery force were also improved because the MWNTs helped to store the internal elastic energy during stretching and fixing. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

再生丁基橡胶与非极性不饱和橡胶共混物的性能研究

对再生丁基橡胶(RIIR)与非极性不饱和橡胶共混物的性能进行了研究。结果表明,RIIR易以填料的形式加入到非极性不饱和橡胶中使用,当RIIR以填料的形式加入到NR、BR及SBR中时,不仅使它们的耐热氧老化性及耐屈挠龟裂性得到明显改善,而且使NR及BR的撕裂强度及扯断伸长率提高;RIIR作为生胶与BR及NR共混,可改善BR的耐热氧老化性,提高NR的撕裂强度;SBR与RIIR共混,均使拉伸强度及撕裂强度降低;非极性不饱和二烯类橡胶与RIIR共混后,均使耐磨性降低。     

Robust Control of Networked System and Its Application

International Journal of Control, Automation and Systems - In this paper, the stability issue of networked system with dynamical topology in intelligent vehicle is studied. The systems are...     

柴油机自动减压起动装置的有限元分析

分析了柴油机自动减压装置的工作原理,针对在潍柴WP10型柴油机上加装的减压装置,利用Solidworks Simulation对压板进行了静力分析,找出了应力最大的部位和最大值,并按照Von Mises准则,判别压板满足刚度要求。     

Polybrominated Diphenyl Ethers in Surface Sediment from Songhua River Basin, Northeast of China

Sixty sediment samples were collected from the main Songhua River in three years. Twelve polybrominated diphenyl ether ( PBDE) congeners ( BDE17, 28, 47, 66, 99, 100, 153, 154, 138, 183, and BDE?209) w...     

德惠断陷下白垩统碎屑岩储层特征及控制因素分析

德惠断陷下白垩统登娄库组、营城组、沙河子组储层物性差,勘探风险大.利用岩心观察、铸体薄片鉴定、扫描电镜分析、黏土X线衍射分析等方法,分析储层基本特征、储层成岩作用和控制因素.结果表明:德惠断陷下白垩统碎屑岩储层成分成熟度和结构成熟度较低,储层孔隙类型主要有残余原生孔、次生孔和混合孔,储层物性和孔隙结构较差;压实作用是导致储层物性变差的主要原因,溶蚀作用改善储层物性;纵向上发育2个次生孔隙带,主要形成于中成岩期,次生孔隙带的形成与有机质生烃排酸和断裂有关.研究结果为德惠断陷下白垩统进一步油田勘探提供地质依据,对其他地区类似储层研究有一定借鉴意义.     

粘土砂旧砂再生效果与其含水量的关系

在影响粘土砂旧砂再生效果的诸多因素中,旧砂中水分含量是最重要的因素。本文就水分含量对再生效果的影响规律、再生效果最佳的水分含量等进行了研究和分析,得出了如下结论:并非含水量越低再生效果就越好,而是存在一个去泥率低谷区;再生效果最佳的适宜水分含量为1～2%。     

基于Event-B和Rodin开展形式化软件工程教学

形式化软件工程是软件工程的重要组成部分。Event-B方法是一种软件形式化开发方法,Rodin是支持Event-B方法的开放工具集。基于Event-B方法和Rodin开展形式化软件工程教学,有益于学生正确理解精化等重要的软件工程概念,理解并掌握开发可信软件的方法,是软件工程教学的重要补充。