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991.
We have developed a two-step technique for synthesizing dichlorosuccinyl peroxide at room temperature, starting from succinic anhydride. It reacts with silanated glass fabric or beads at room temperature. The macroinitiator thus formed can be used for the polymerization of methyl methacrylate, MMA. We show that the MMA is grafted to the surface of glass giving a chemically bonded ultrathin coating, as confirmed by the FTIR analysis and electron micrography. 相似文献
992.
Carlos Guerra Sarvesh Kumar Fernando Aguilar-Galindo Sergio Díaz-Tendero Ana I. Lozano Mnica Mendes Juan C. Oller Paulo Limo-Vieira Gustavo García 《International journal of molecular sciences》2022,23(3)
In this study, novel experimental total electron detachment cross sections for O2− collisions with benzene molecules are reported for the impact energy range (10–1000 eV), as measured with a transmission beam apparatus. By analysing the positively charged species produced during the collision events, relative total ionisation cross sections were derived in the incident energy range of 160–900 eV. Relative partial ionisation cross sections for fragments with m/z ≤ 78 u were also given in this energy range. We also confirmed that heavier compounds (m/z > 78 u) formed for impact energies between 550 and 800 eV. In order to further our knowledge about the collision dynamics governing the fragmentation of such heavier molecular compounds, we performed molecular dynamics calculations within the framework of the Density Functional Theory (DFT). These results demonstrated that the fragmentation of these heavier compounds strongly supports the experimental evidence of m/z = 39–42, 50, 60 (u) cations formation, which contributed to the broad local maximum in the total ionisation observed from 550 to 800 eV. This work reveals the reactivity induced by molecular anions colliding with hydrocarbons at high energies, processes that can take place in the interstellar medium under various local conditions. 相似文献
993.
Resolving Deep Sub-Wavelength Scattering of Nanoscale Sidewalls Using Parametric Microscopy 下载免费PDF全文
Nagendra Parasad Yadav Ji-Chuan Xiong Wei-Ping Liu Wei-Ze Wang Yun Cao Ashish Kumar Xue-Feng Liu 《电子科技学刊:英文版》2021,19(3):233-242
The quantitative optical measurement of deep sub-wavelength features with sub-nanometer sensitivity addresses the measurement challenge in the semiconductor fabrication process. Optical scatterings from the sidewalls of patterned devices reveal abundant structural and material information. We demonstrated a parametric indirect microscopic imaging (PIMI) technique that enables recovery of the profile of wavelength-scale objects with deep sub-wavelength resolution, based on measuring and filtering the variations of far-field scattering intensities when the illumination was modulated. The finite-difference time-domain (FDTD) numerical simulation was performed, and the experimental results were compared with atomic force microscopic (AFM) images to verify the resolution improvement achieved with PIMI. This work may provide a new approach to exploring the detailed structure and material properties of sidewalls and edges in semiconductor-patterned devices with enhanced contrast and resolution, compared with using the conventional optical microscopy, while retaining its advantage of a wide field of view and relatively low cost. 相似文献
994.
Dushyant Kumar 《分离科学与技术》2020,55(15):2844-2854
ABSTRACT In this study, electrocoagulation (EC) was used to determine the optimum conditions on the basis of maximum chemical oxygen demand (COD) and color removal. At the optimum conditions chlorophenols (CPs), biological oxygen demand and total organic carbon (TOC) were determined. The biodegradability of wastewater was increased significantly with 63% COD, 98% color, 61% TOC and overall 65.51% reductions in CPs. Further, the electro-coagulated sludge was characterized by using different analytical techniques to assist the physicochemical and elemental phases, to find-out better management option, reusability for plant growth and safe disposal. Additionally, aluminum content (70.62%) was successfully recovered from sludge. 相似文献
995.
Junali Handique Joly Gogoi Jayashree Nath Swapan Kumar Dolui 《Polymer Engineering and Science》2020,60(1):140-150
This investigation reports the effective use of the Diels–Alder (DA) click reaction in the preparation of self-healing bio-based dendritic methacrylates having reactive furfuryl functionality. Bio-based methacrylates were synthesized by modifying tannic acid with glycidyl methacrylate and furfuryl functionality was introduced by atom transfer radical polymerization with varied amount of furfuryl methacrylate monomer. The thermoreversible network was successfully achieved by DA and retro-DA reaction between the furfuryl groups and a bifunctional maleimide crosslinker, bismaleimide. This process was studied by nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and solvent exposure tests. Differential scanning calorimetry analysis was used to determine the endothermic retro-DA reaction in the DA adduct. The self-healing property of the above crosslinked material was demonstrated by monitoring the repair of a scratch in the polymer film upon heating and cooling. This was analyzed by scanning electron microscopy. POLYM. ENG. SCI., 60:140–150, 2020. © 2019 Society of Plastics Engineers 相似文献
996.
Mingxuan Lu Prabhakar V. Gulgunje Pedro J. Arias-Monje Jeffrey Luo Jyotsna Ramachandran Yudhisthira Sahoo Sandip Agarwal Satish Kumar 《Polymer Engineering and Science》2020,60(9):2143-2151
Bi-component, polyacrylonitrile (PAN)/carbon nanotube (CNT) fibers were processed, at different core-sheath area ratios, by gel spinning. A percolated CNT network at 10 wt% CNT in the sheath enhanced electrical conductivity as compared to the neat PAN fiber, while PAN polymer in the core contributed to the good mechanical properties. Fibers with relatively thin sheath allowed overall CNT loading as low as 3.7 wt% to be made with good electrical conductivity, and PAN stabilization by Joule heating was demonstrated. Such fibers with combined good mechanical properties and electrical conductivity can also potentially be used for electrical heating of fabrics, for making smart textiles, and for electromagnetic interference shielding. 相似文献
997.
Antony Cyril Arulrajan Palaniappan Subramanian Ramesh Kumar Singh Alex Schechter 《Israel journal of chemistry》2020,60(5-6):563-569
Developing Pt-free catalysts for hydrogen oxidation reaction (HOR) in alkaline solution is becoming a key challenge in the development of anion exchange membrane fuel cells and electrochemical reactors. Herein, we present the preparation, HOR activity, and stability of Pd-decorated tungsten (Pd-d-W) catalysts. The Pd-d-W catalysts were prepared by the chemically activated surface of tungsten nanoparticles by Pd ions. The resultant bimetallic catalysts consisted of crystalline phases of both Pd and W nanoparticles. The CO stripping voltammograms and H-desorption (Hdes) peak potential of hydrogen desorption in Pd suggests that the enhancement of HOR catalytic activity observed in Pd-d-W catalyst can be ascribed to the modification of electronic property of Pd and availability of OHad near-surface Pd atoms. 相似文献
998.
Selvi Jayaraj Parthasarathy Vellaichamy Mahalakshmi Sehar Anbarasan Ramasamy Daramola Michael O. Senthil Kumar Ponnusamy 《Iranian Polymer Journal》2020,29(5):411-422
Iranian Polymer Journal - Poly(vinyl alcohol) (PVA) nanocomposites incorporated with ZnO nanofiller were prepared and examined to study the influence of nanofiller on their properties. All the... 相似文献
999.
Kiran Tiwari Rudramani Singh Vinai Kumar Singh Manoj Kumar Krishnamoorthi S. Kumar Krishna 《Iranian Polymer Journal》2020,29(7):615-623
Iranian Polymer Journal - In our recent work, we have reported on hydrogels devoid of cross-linkers. After observing the successful swelling and water retention properties, we have introduced... 相似文献
1000.
Bhogal Sangeeta Sharma Gaurav Kumar Amit Sharma Shweta Naushad Mu. Alam Manawwer Stadler Florian J. 《Topics in Catalysis》2020,63(11-14):1272-1285
Topics in Catalysis - In the present study, Ag2O–Al2O3–ZrO2 based trimetallic oxide nanocatalyst was designed using simple microwave assisted reduction method. It was characterized... 相似文献