Water-soluble and amphiphilic polymers

Summary Three PEO-PSt-PEO triblock polymers and their parent ho-nopolystyrene have been studied by means of light scattering technique in chloroform, toluene and ethyl acetate. It has been found that the weight average molecular weights calculated by using the equation Mapp- were unbelievable negative values; and the largest deviation appeared for the sample with PEO mole content of about 50%. Data of PSt-PEO-PSt triblock polymers in literature have been quoted and discussed.     

光纤光栅传感器中磁场测量稳定性研究

为了减小光纤光栅磁场传感器中线性双折射和入射起偏角对系统稳定性的影响,提高测量系统的准确性,提出一种减小线性双折射和起偏角大小对系统输出影响的设计方案。研究了基于法拉第效应的光纤光栅磁场传感器系统,得出系统输出电压与磁场的关系式,并通过降低线性双折射和确定入射起偏角改善了系统的输出特性。仿真表明:该方法可以有效抑制测量过程中线性双折射造成的非线性关系,从而提高磁场测量的稳定性。     

镀液流速对碳化硅微粒与铜共沉积的影响

本文利用易于控制流速的旋转圆盘电极研究了SiC微粒与Cu的共沉积。得出了在不同镀液流动速度下镀得的复合镀层中微粒含量与镀液中微粒浓度以及与电流密度之间的关系曲线,进而探讨了镀液流速对Cu-SiC共沉积的影响。镀液流速通过影响微粒与阴极之间的弱吸附影响微粒在阴极表面的停留,从而对Cu-SiC复合电沉积过程产生很大影响。     

Morphology and properties of blends of polypropylene with ethylene-propylene rubber

Great attention has been paid to the toughening of isotactic polypropylene (PP) in recent years in order to make full use of this plastic. This paper presents the results of our study on the compatibility of PP with ethylene-propylene-diene rubber (EPT), polybutadiene rubber (PB) or styrene-butadiene rubber (SBR) through characterization of the blends' morphology, and on. the morphology and properties of binary blends of PP with EPT (EPT/PP) and ternary blends of PP, EPT, and polyethylene (PE) (EPT/PE/PP). Morphological structure of solution blends and the great improvement in low-temperature impact strength and other properties of the mechanical blends have shown the difference among EPT, PB, and SBR in compatibility with PP, the effectiveness of using EPT as PP's toughening agent, and the effect of EPT on EPT/PP blend as both toughening agent and compatibilizer. Addition of EPT to EPT/PP made interesting changes in morphology but no effect on properties was observed.     

基于引力搜索算法的分数阶变异时序回归GSA-TSGM(1,1)模型

为了利用分数阶累加算子在灰色短期预测中的高效性能,首次将分数阶累加算子引入变异时序回归模型以期取得更高的预测精度。主要方法如下：首先取湖北省链子崖某监测点1978—1987年的十年数据作为训练集并使用引力搜索算法确定最佳分数阶累加阶数,而1988—1993年的六年数据作为验证集验证提出的模型;其次对比了经典灰色模型GM(1,1)、分数阶累加灰色模型、变异时序回归模型TSGM(1,1)三种灰色模型。结果如下：首先修正了陈西江等人变异时序回归模型仿真时出现的错误,其次表明了相比于其他的模型,基于引力搜索算法的分数阶累加时序回归模型在进行灰色长期预测中具有较高的预测精度。因此,通过分数阶累加算子提高了灰色理论中长期预测模型的精度,为灰色长期预测提供了指导。     

C207甲醇合成铜基催化剂本征失活动力学

一、前言工业生产中广泛使用的甲醇合成铜基催化剂具有活性高、选择性好、起始活性温度低等优点。但铜基催化剂抗毒性能差,影响了它的使用寿命。铜基催化剂的主要毒物是原料气中所含的 H_2S。铜基催化剂 H_2S 中毒失活研究,国内未见报道,美国的 Wood 等和 Rdvodic 等作过一些研究。本文通过对国产 C207铜基催化剂硫化氢中毒失活动力学的研究,建立描述活性衰退过程的失活动力学方程,得到活性与硫化     

羟基烷基磺酸镀液电镀Sn—Pb合金的研究

我国自行研制生产的羟基烷基磺酸电镀Sn-Pb合金镀液已经在部分厂家投产使用.生产实践证明,该镀液能获得不同铅含量的、可焊性优良且镀层结晶细致而光亮的Sn-Pb合金镀层.本研究重点测定了该镀液的电化学性能,如阴极电流效率、分散能力及深镀能力.并对添加剂的作用进行了研究探讨.     

普钙产品转化率的数值计算方法

对影响普钙产品转化率的各种因素进行了分析,利用MATLAB 软件包得到了转化率的计算公式,提出了确定未分解磷矿的比例和由倍半氧化物引起的有效磷退化幅度的方法,为生产系统的预测和调整提供了一种途径。     

金安金沙江悬索桥隧道式锚碇变形破坏机制研究

隧道式锚碇的变形破坏机制涉及到结构与围岩的协同作用问题。以华丽高速公路金安金沙江悬索桥两岸隧道锚变形破坏机制为研究对象,利用工程类比法评价了其稳定性控制要素,设计了超载数值试验。根据塑性区的扩展过程确定了施工安全监测和需要采取预加固的重点部位,确定了隧道锚围岩的破坏模式。根据锚面监测点位移由mm到cm量级突变确定的两岸锚岩系统极限荷载均为6~8倍设计缆力,则锚岩系统的设计承载力取3倍设计缆力下变形安全是有保障的。丽江岸塑性区在10 P下贯通;华坪岸塑性区在14 P下贯通。设计缆力作用下,丽江岸锚碇最大位移1.5 mm、围岩1.2 mm、地表0.5 mm;华坪岸锚碇最大位移1.7 mm、围岩1.5 mm、地表0.7 mm,其响应顺序为后锚面监测点前锚面监测点锚碇中间岩体地表点,可作为后期结构及围岩安全监测布点和预警的参考,也证明当前设计缆力下变形和强度均是安全的。     

Formation of Polymeric Lewis Acid–Lewis Base Complexes with Well-defined Organoboron Polymers

The binding of Lewis bases to organoboron polymeric Lewis acids has been studied and the parameters that determine the complexation equilibrium have been investigated, which include (i) the strength of the individual Lewis acids and Lewis bases, (ii) concentration, and (iii) temperature. While the strongly Lewis acidic borane polymers poly(4-bis(pentafluorophenyl)borylstyrene) (PS-BPf) and poly(4-(di-2-thienylboryl)styrene) (PS-BTh) form isolable complexes with strong Lewis bases such as 4-t-butylpyridine (^tPy), a temperature dependent equilibrium is established with weaker bases such as THF. Similarly, the weakly Lewis acidic boronate polymer poly(4-diethoxyborylstyrene) (PS-BOEt) undergoes a temperature dependent equilibrium with the strong Lewis base 4-dimethylaminopyridine (DMAP), while poly(4-pinacolatoborylstyrene) (PS-BPin) does not significantly bind to pyridine bases. Decomplexation of PS-BTh· ^t Py is achieved by treatment with the stronger Lewis acid, B(C₆F₅)₃, thereby confirming the reversible nature of the polymeric Lewis acid–base adducts. This paper is dedicated to Professor Ian Manners in gratitude of his guidance throughout the years and recognition of his scientific accomplishments