Conversion of acrylonitrile-based precursors to carbon fibres

The progress of stabilization of two compositions of acrylic fibres with various orientations has been followed by a variety of techniques. The thermooxidative treatments for stabilization have been carried out in a continuous process and also in a batch process under free shrinkage, constant length and constant tension conditions. The morphological model of acrylic fibres consists of an alternating sequence of laterally ordered and laterally disordered regions along the fibre direction. This structure is consistent with the observations based on small-angle X-ray scattering of copper- impregnated precursor fibres and thermomechanical response, thermal stress development, calorimetry, wide- and small-angle X-ray scattering and sonic modu-lus measured at different extents of stabilization. Lateral as well as orientational order in these fibres can be increased markedly through a high-temperature deformation process prior to stabilization. An increase in perfection and extent of order is observed in the early stages of stabilization. There is also a simultaneous decrease in the orientation of the disordered phase at this stage and the extent of this decrease depends on the axial constraints imposed on the fibre. Little difference in the rate of stabilization is observed as measured by density or oxygen uptake for fibres with different extents of orientation, lateral order or restraint. Fibres containing itaconic add, a stabilization catalyst did show an increased rate of stabilization. Inferences have been drawn regarding additional research pertaining to achieving high order in precursor fibres, minimizing orientational relaxation during oxidative stabilization, and the techniques for monitoring the extents of the stabilization treatment and the changes in relevant morphological parameters.     

Long-term transients in a reactor under forced concentration cycling

In the approach to a cycle-invariant state in the forced feed concentration cycling of the CO oxidation over a NiO catalyst, a very long transient has been observed lasting 80 ks or more. This transient appears to be associated only with CO pretreatment of the catalyst and is not a general phenomenon. The slow convergence to the cycle-invariant state reported in certain modelling calculations in the literature appears to have a different cause.     

Delay Analysis of Interacting Queues with an Approximate Model

An approximate model of coupled Markov chains is proposed and analyzed for a slotted ALOHA system with a finite number of buffered nodes. This model differs from earlier ones in that it attempts to capture the interdependence between the nodes. The analytical results lead to a set of equations that, when solved numerically, yield the average packet delay. Comparison between computational and simulation results for a small number of nodes show excellent agreement for most throughput values, except for values near saturation. Numerical comparisons for a two-node system show that a nonsymmetric loading of the system provides better delay-throughput performance than a symmetric one.     

Low-cost, high-efficiency quasi-planar array of waveguide-fed circularly polarized microstrip antennas

A low-cost quasiplanar Ku-band array of circularly polarized microstrip antennas benefiting from a low-loss waveguide feed network is demonstrated (patent pending). The 32 elements of the array which are arranged in a 2-by-16 configuration are subdivided into four two-by-four subarrays. To maintain feed losses and thus the overall noise temperature at a minimum, the subarrays are excited using a one-by-four corporate feed network of hollow metallic waveguides. This network is composed of E-plane components such as Tee-junctions and bends and is manufactured out of only two metallic pieces that accommodate the feed network in the form of milled grooves. Because of insensitivity of the exploited E-plane components to air gaps or slight misalignments, the pieces are secured together with only four screws without welding, braising, or conducting adhesives. Owing to a low-loss foam substrate, the array elements show high circular polarization gain of 9 dBic and wide relative bandwidth of 4%. To achieve circular polarization, use is made of circular patches with two nearly perpendicular perturbations. Using sequential rotation of the elements along with quadrature phase shifting, the axial ratio of the array is reduced to 1 dB over 4% of bandwidth. The measured circular polarization gain of the array amounts to 23 dBic with an aperture efficiency of 63% in the Ku-band of frequencies. The achieved efficiency, which is higher than the reported efficiency for comparable planar arrays with microstrip feed networks, can be credited to the low losses of only 0.2 dB in its waveguide corporate feed. The paper also presents measurement results for an arrangement of two inclined single arrays mounted in parallel. This configuration which has a measured circular polarization gain of 25.7 dBic with an axial ratio of 1 dB is desirable for mobile low-profile antenna systems.     

Prediction of thermal comfort in a building during a cold spell

The comfort diagrams and the so-called PMV-PPD values are already used today directly and indirectly in a wide field in technical practice, even at a standard level. This theory is known also in Hungary, and the PMV-PPD values have been used by us for the solution of a design problem. The task was to elaborate a calculation method, an index number suitable for the determination of the thermal confort effect in the case of occasional underheating of residential and communal buildings in winter.The results of this work are presented in this paper.     

A review of the methods of calculation of added resistance for ships in a seaway

Most recent studies of performance and assessment of auxillary wind powered ships have been based primarily upon the calm water resistance of the ships hull. This resistance is then used as a first estimate of the power required to drive the ship in a seaway. Some allowance has been made to this estimate for weather and seaway via a ‘weather margin’. For many years theoreticians have produced methods for the calculation of this weather margin of a ship in a random seaway due to the induced rigid body motions. This paper sets out to review the present day methods that are used to calculate ‘added resistance’ as it is often termed. This will allow, hopefully, designers and practitioners of wind powered vessels to discriminate between the different methods that are now available.     

Wavelength-switchable fiber laser using acoustic waves

We report a wavelength-switchable fiber ring laser that includes a Bragg grating-based acoustooptic superlattice modulator. Wavelength switching of the laser emission is achieved by controlling the peak reflectivity of the different reflection bands that appear on both sides of the Bragg wavelength when a longitudinal acoustic wave propagates along the grating.     

Photoconductive Terahertz antenna with radial symmetry

It has been demonstrated recently that it is possible to guide broadband Terahertz pulses utilising a novel coaxial waveguide. This technique is hindered by the difficulty in exciting the radially polarised fundamental mode of the waveguide. To optimise mode matching, a novel radially symmetric photoconductive Terahertz antenna is proposed. Using finite element method simulations and analytical calculations, it is shown that this antenna can generate the desired radial polarisation.     

Retention of Escherichia coli in municipal sewage by means of planted soil filters in two-stage pilot plant systems.

Different types of constructed wetlands in a pilot-plant system were fed with identical municipal waste water to compare the sanitisation process in two-stage systems. With combinations of a vertical and a horizontal flow filter an E. coli reduction of 5 log10 with an E. coli influent concentration of 10(7) MPN/100 ml was achieved. Using different filter materials in each stage the total performance of the two-stage system was independent from the sequence of these materials. However, using coarser filter material in the first stage makes the filter less prone to clogging and is thus the preferential option with regard to operational reliability.