Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide in presence of activated carbon prepared from olive stones

This work is dedicated to the removal of the very toxic free cyanide from aqueous solution by oxidation with hydrogen peroxide H₂O₂ in the presence of activated carbon prepared from olive stones. Effects of the initial molar ratio [H₂O₂]₀/[CN^?]₀, the initial cyanide concentration, the activated carbon concentration and the temperature on cyanide removal have been examined. The removal of free cyanide in absence of activated carbon showed very slow kinetics. The presence of activated carbon has increased the reaction rate showing thus a catalytic activity. The kinetics of cyanide removal has been found to be of pseudo-first-order with respect to cyanide and the rate constants have been determined for different values of the aforementioned parameters. The apparent activation energy has been determined from tests carried out at three different temperatures. It was found equal to 46.2 kJ/mol in the presence of activated carbon, which is about half of the 82.7 kJ/mol found for the oxidation in absence of the activated carbon.This process can be interesting for the cyanide removal from processed solutions because it does not use soluble metal catalyst and it consumes only hydrogen peroxide as chemical product.     

Influence of process variables on growth of ZnO nanowires by cathodic electrodeposition on zinc substrate

Influence of the deposition duration and electrolyte concentration on the structural and morphological features of the ZnO thin films, grown by cathodic electrodeposition on zinc substrate followed by annealing in air at 400 °C, have been investigated. The surface morphology of the as-synthesized films shows two distinct features, presence of ‘2-dimensional nanosheets’ on the area near the electrolyte-air interface and ‘granular’ nanostructures, below the interface region. However, upon annealing, the formation of ZnO nanowires, possessing length of several microns and diameter less than 20 nm, on the entire substrate is observed. The X-ray and selected area electron diffraction patterns clearly confirm the polycrystalline nature of the ZnO nanowires.     

Cross-Well Radar. I: Experimental Simulation of Cross-Well Tomography and Validation

This paper explains and evaluates the potential and limitations of conducting cross-well radar (CWR) in sandy soils. Implementing the experiment and data collection in the absence of any scattering object, and in the presence of an acrylic plate [a representative of dielectric objects, such as dense nonaqueous phase liquid (DNAPL) pools, etc.], as a contrasting object in a water-saturated soil is also studied. To be able to image the signature of any object, more than one pair of receiving and transmitting antennas are required. The paper describes a method to achieve repeatable, reliable, and reproducible laboratory results for different transmitter-receiver combinations. Different practical methods were evaluated for collecting multiple-depth data. Similarity of the corresponding results and problems involved in each method are studied and presented. The data show that the frequency response of a saturated coarse-grained soil is smooth due to the continuous and dominant nature of water in saturated soils. The repeatability and potential symmetry of patterns across some borehole axes provide a valuable tool for validation of experimental results. The potential asymmetry across other borehole axes is used as a tool to evaluate the strength of the perturbation on the electromagnetic field due to hidden objects and to evaluate the feasibility of detecting dielectric objects (such as DNAPL pools, etc.) using CWR. The experimental simulation of this paper models a real-life problem in a smaller scale, in a controlled laboratory environment, and within homogeneous soils that are uniformly dry or fully water saturated, with a uniform dielectric property contrast between the inclusion and background. The soil in the field will not be as homogeneous and uniform. The scaling process takes into consideration that as the size is scaled down; the frequency needs to be scaled up. It is noteworthy that this scaling process needs to be extensively studied and validated for future extension of the models to real-field applications. For example, to extend the outcome of this work to the real field, the geometry (antenna size, their separation and inclusion size) needs to be scaled up back to the field size, while soil grains will not. Therefore, soil, water, and air coupling effects and interactions observed at the laboratory scale do not scale up in the field, and may have different unforeseen effects that require extensive study.     

Intelligent detection of unstable power swing for correct distance relay operation using S-transform and neural networks

The conventional power swing schemes used in distance relay operation are not fast enough to detect and distinguish a fault, stable swing and unstable swing and this may lead to unintended tripping of protection devices. Therefore, there is a need for fast detection of unstable swings so as to improve the reliability of distance relay operation. This paper presents an intelligent approach for detecting unstable swings during distance relay operation using the S-transform signal processing technique and artificial neural networks. To illustrate the effectiveness of the proposed approach, simulations were carried out on the IEEE 39 bus test system using the PSS/E software. Test results showed that the proposed approach using S-transform, multi layer perceptron network and probabilistic neural network can accurately detect and classify fault, stable swing, unstable swing, fault clearance and post fault events for correct distance relay operation.     

Computer Analysis of Impedance Effects in Large Grounding Systems

In large plants with high primary fault levels, the whole plant must be considered as forming the ground grid for the return of primary fault current. The internal impedance of the equivalent ground grid must be taken into account in grid potential rise calculations, as grid potentials transferred from one area of the plant may cause hazardous touch potentials at other locations. Field measurements and computer analyses to calculate the distribution of grid potential rise in a large grounding system are presented.     

Effect of polysorbates on atenolol release from film-coated tablets

The effects of different concentrations of various polysorbates on the release rate of atenolol from film-coated tablets were evaluated. The release profile of atenolol showed that increasing the concentration of polysorbate resulted in an increase in the release rate of atenolol. The type of polysorbate had less effect on the release rate of atenolol. This study revealed that the release kinetic of atenolol from these film-coated tablets was a function of polysorbate concentration. Correlation coefficients of kinetic models could not solely determine the suitability of the models; the sum of the least square of differences also should be calculated when different kinetic models have similar correlation coefficients.     

Image thresholding based on the EM algorithm and the generalized Gaussian distribution

In this paper, a novel parametric and global image histogram thresholding method is presented. It is based on the estimation of the statistical parameters of “object” and “background” classes by the expectation-maximization (EM) algorithm, under the assumption that these two classes follow a generalized Gaussian (GG) distribution. The adoption of such a statistical model as an alternative to the more common Gaussian model is motivated by its attractive capability to approximate a broad variety of statistical behaviors with a small number of parameters. Since the quality of the solution provided by the iterative EM algorithm is strongly affected by initial conditions (which, if inappropriately set, may lead to unreliable estimation), a robust initialization strategy based on genetic algorithms (GAs) is proposed. Experimental results obtained on simulated and real images confirm the effectiveness of the proposed method.     

Analysis of deformations and stresses in balanced and unbalanced adhesively bonded single-strap joints

Adhesively bonded joints are increasingly being used in joining various structural components. Adequate understanding of the behaviour of adhesively bonded joints is necessary to ensure efficiency, safety and reliability of such joints. While several joint configurations, such as the single- and double-lap joints have received considerable consideration, the single-strap joint configuration has received little attention, partly because earlier studies have shown it to be the least efficient.

One of the objectives of this paper is to demonstrate that strap joints can be as efficient as lap joints, as long as they are properly designed. This will be done through a detailed analytical investigation into influence of the parameters that govern peak stresses in the adhesive. The next objective is to produce simple equations by which the design of strap joint could be facilitated in an effective manner. For this, the developed analytical expressions are simplified and shown to provide accurate results. The derived solutions provide better insight into understanding the parameters that most influence the edge forces.