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141.
A series of borotungstate glasses was prepared. The glass formation was confirmed by using X-ray diffraction measurements on the powder samples then measured using Mo¨ssbauer, differential thermal analysis (DTA), infra-red (IR) and d.c. conductivity. The iron in the alkali borate tungstate glass was found in the ferric state only. The introduction of tungsten to replace 25 mol % sodium tetraborate in the glass samples caused a little shift in the IR bands toward the lower frequency. The iron ions may act as a glass modifier whereas the tungsten ions may act as network former. The electrical conduction increased in the presence of tungsten due to the hopping mechanism between the two sites of tungsten (W5+, W6+).  相似文献   
142.
A new model of the equations of generalized thermoviscoelasticity for a thermally, isotropic and electrically conducting half-space solid whose surface is subjected to a thermal shock is given. The formulation is applied to the generalized thermoelasticity based on the Green and Naghdi (GN) theory under the effect of rotation, where there is an initial magnetic field parallel to the plane boundary of the half-space. The medium is deformed because of thermal shock and due to the application of the magnetic field, it results in induced magnetic and electric fields in the medium. The normal mode analysis is used to obtain the expressions for the variables considered. The distributions of temperature, displacement, stress, induced magnetic and electric fields are represented graphically. Comparisons are made with the results predicted by the types II and III in the presence and absence of rotation.  相似文献   
143.
    
The major factors affecting the removal efficiency of sulfamethazine (SMT) by photocatalysis process in the presence of TiO2 P25 or ZnO, namely the pH, the amount of catalyst and the initial SMT concentration were examined. The obtained results showed the absence of adsorption of SMT on the catalysts and the absence of degradation of SMT by direct photolysis under UV light in the absence of catalyst. The variation of the pH solution in the range 4–9 did not cause any significant degradation of SMT. The optimal amounts of each catalyst were, respectively, 0.5 and 0.25 g/L for TiO2 P25 and ZnO. Increasing the initial SMT concentration impacted negatively the removal efficiency, which decreased from 31% to 13% and from 100% to 27% in the presence of TiO2 P25 and ZnO in the presence of 10 mg/L and 50 of SMT after 30-min reaction time, respectively. The obtained results showed better efficiency of ZnO than TiO2 P25 regarding both removal efficiency and chemical oxygen demand (COD) abatement. However, removal efficiency and COD abatement were not complete, even after 7 h of photocatalysis, about 92% and 41%, respectively. The biodegradability was examined after photocatalysis performed in the following conditions: [SMT]0 = 50 mg/L, pH = 6, T = 25°C, ω = 360 rpm and 0.5 g/L of TiO2 P25 or 0.25 g/L of ZnO. In these conditions, the removal efficiencies were, respectively, 26% and 41% in the presence of TiO2 P25 and 55 and 92% in the presence of ZnO after 4 and 7 h of pretreatment times, respectively. The BOD5/COD ratio increased substantially and, respectively, from 0 to 0.25 and from 0 to 0.16 in the presence of TiO2 P25 and ZnO after 7 h of irradiation. Even if the limit of biodegradability (0.4) was not achieved, a subsequent biological treatment was considered in the presence of TiO2 P25, leading to 58% COD abatement after a 28-day culture.  相似文献   
144.
    
Quantitative analysis of the Upper Campanian-Maastrichtian foraminiferal assemblages in Hawashiya and Umm Omeiyied exposed sections at Wadi Qena, Eastern Deseret, Egypt is reconstructed to study the paleoenvironments and relative sea level changes. This study recognizes eight planktonic biozones from CF8 to CF2. The preservation of the studied samples ranging from moderate to good and is dominated by small-sized of Heterohelix spp. and Globigerinelloides spp. reflecting nutrient-rich/eutrophic marine environments. Eleven benthonic foraminiferal biofacies are recorded and reflected inner to outer neritic environments. Three sea level drops are noted at the Upper Campanian/Early Maastrichtian; Early/Middle Maastrichtian and Maastrichtian/Paleocene boundaries. These sea level drops match well with the eustatic sea level drops which are tectonically effect especially at the Cretaceous/Paleogene (K/Pg) boundary due to the absence of CF1 to P4a subzones.  相似文献   
145.
    
Microscale processes offer a substantial advantage to the process industry as separation is conducted rapidly and efficiently. However, the effectiveness of the separation depends on the stability of the flow regime. Experimental and numerical analysis was carried out to characterize the flow patterns of polyethylene glycol 200 (PEG200) and diesel fuel at several flow ratios in order to achieve optimal conditions for a stable pattern. Computational fluid dynamics (CFD) was employed using the volume-of-fluid (VOF) model and the results were validated with the experimental data. Both experimental and numerical outcomes revealed two-phase flow patterns. These findings enable the application of the simulated module for further liquid-liquid mass transfer studies where sulfuric compounds exist as solutes in the fuel.  相似文献   
146.
    
Molecular crystals are promising anisotropic optical transducing media for next‐generation optoelectronic microdevices that will be capable of secure transduction of information and impervious to external electromagnetic interference. However, their full potential has not been explored yet due to their poor processability, low mechanical compliance, pronounced brittleness and high proneness to cracking that often result in irrecoverable damage. These issues are detrimental to their ability to transduce light. Here, a novel strategy is presented based on 3D epitaxial crystal growth of organic/inorganic crystals based on charge‐assisted hydrogen bonds that can be used to efficiently weld broken molecular single‐crystalline optical waveguides and restore their light‐transducing capability. This approach can also be applied to prepare asymmetric multidomain crystalline heterostructures starting from isostructural molecular tectons, resulting in novel opto/electro/mechanical functionalities in the hybrid materials. It also removes an important obstacle toward wider application of molecular crystals in the next‐generation optoelectronics.  相似文献   
147.
The behaviour of phenols and nitrophenols in the atmosphere is of concern for environmental research as these are known to be toxic to humans and wildlife. To increase the knowledge about these compounds, the concentrations of 20 phenols and nitrophenols in rainwater were studied in an urban (Strasbourg) and a rural (Erstein) site in Eastern France.The wet rain samples were collected on a weekly basis between January 2002 and July 2003, and analyzed for phenols and nitrophenols using SPME and gas chromatography coupled to mass spectrometry. The compounds were derivatized with MDBSTFA directly in the injection port of the gas chromatograph.Total concentrations ranged from 0 to 1383 µg L− 1 in Strasbourg and from 0 to 1215 µg L− 1 in Erstein. These concentrations are in the same range than those measured in other studies, but considerably higher than the concentrations measured for pesticides (about 10 times) and polycyclic aromatic hydrocarbons (about 1000 times) on the same sites and at the same period.Phenols, except for o-cresol, were generally less concentrated than nitrophenols. o-Cresol was one of the major compounds, probably due to its role as raw material in pesticide production. The concentrations of phenols and nitrophenols were found to vary with time. No seasonal trend was observed, but significant correlations with rainfall amount were identified.  相似文献   
148.
This paper deals with a pick and place robotic system design problem. The objective is to present an efficient method which is able to optimize the performances of the robotic system. By defining the suitable combination of scheduling rules, our method allows each robot to perform the assigned pick and place operations in real time in order to maximize the throughput rate. For that, we have developed different resolution methods which define the scheduling rule for each robot in order to seize the products from the first side of the system and to place them on the second side. We suggest three metaheuristics which are the ant colony optimization, the particle swarm optimization and the genetic algorithm. Then, we try to select the best algorithm which is able to get the best solutions with the lowest execution times. This is the main advantage of our methods compared to exact methods. This fact represents a great interest taking in consideration that our methods must respect a strong industrial constraint regarding the functioning of a real industrial robotic system. This constraint states that the answer time to manage the seizing strategies of the robots must be less than 1 second. Numerical results show that the different algorithms perform optimally for the tested instances in a reasonable computational time.  相似文献   
149.
In recent years, decision makers give more importance to the maintenance function, viewing its substantial contribution to business productivity. However, most literature on scheduling studies does not take into account maintenance planning when implementing production schedules. The achievement of production plan without taking into account maintenance activities increases the probability of machine breakdowns, and inversely, considering maintenance actions in production planning elongates the achievement dates of orders and affects deadlines. In this paper, we propose a bi-objective model to deal with production scheduling and maintenance planning problems simultaneously. The performance criteria considered for production and maintenance are, respectively, the total tardiness and the unavailability of the production system. The start times of preventive maintenance actions and their number are not fixed in advance but considered, with the execution dates of production tasks, as decisions variables of the problem. The solution of the integrated model is based on multi-objective ant colony optimization approach. The proposed algorithm (Pareto ant colony optimization) is compared, on the basis of several metrics, with well-known multi-objective genetic algorithms, namely NSGA-II and SPEA 2, and a hybrid particle swarm optimization algorithm. Interesting results are obtained via empirical study.  相似文献   
150.
In this study, ternary MWCNTs/CoFe2O4/FeCo nanocomposite coated with conductive PEDOT-polyaniline (PA@MW/F/C) co-polymers were synthesized by microwave-assisted sol-gel followed in-situ polymerization methods. The phases, crystal structures, morphologies, magnetic and electromagnetic features of the as-prepared samples were identified via XRD, SEM, XPS, VSM, and VNA respectively. Absorption characteristics were investigated in the frequency (12–18 GHz) Ku band. XRD, VSM and SEM analysis confirmed the partial reduction process of CoFe2O4 and successfully decorated magneto-dielectric particles with co-polymers. By measuring electromagnetic features of the samples, it was found that coating magneto-dielectric particles with conductive co-polymers improved the permittivity and dielectric constant, accordingly affecting the impedance matching characteristic and attenuation constant performance. Moreover, exchange coupling behavior was found significant impacts on the microwave absorption properties. PA@MW/F/C coated nanocomposite revealed the maximum reflection loss of ?90 dB at 13.8 GHz with 4 GHz effective bandwidth and 1.5 mm thickness. Due to the enhanced interfacial polarization, impedance matching and exchange coupling effects of the as-prepared nanocomposite, it owns excellent microwave absorption properties, which can be applied as an absorber with distinguishing features (strong absorption, thin thickness, and broadest effective bandwidth).  相似文献   
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