Anodic behavior of gold in 1-butyl-3-methylimidazolium methanesulfonate ionic liquid with chloride anion

The anodic behavior of gold has been investigated in presence of chloride and/or water in 1-butyl-3-methylimidazolium methanesulfonate (BMI CH₃SO₃) ionic liquid (IL). The cyclic voltammetry (CVs) in presence of chloride ions shows two waves attributed to the oxidation of the gold electrode which occurs under two steps: the first one is attributed to the electrochemical dissolution of gold into to gold(I), while the second one is attributed to an overlap of the chloride oxidation step as well as the oxidation of Au(I) to Au(III). Furthermore the determination of water and chloride content in IL allowed observing that the passive layer induced by water could be removed under chloride. Thanks to those results we were able to clarify the conditions of gold recovering in this kind of electrolyte.     

Rapid homogeneous esterification of cellulose extracted from Posidonia induced by microwave irradiation

In this article, we report on the synthesis of cellulose esters by the reaction of cellulose and some cyclic anhydrides, such as succinic, maleic, and phthalic anhydrides. For this, an esterification method was finalized. Indeed, cellulose extracted from Posidonia biomass was first solubilized in the solvent system lithium chloride (LiCl)/N,N‐dimethylacetamide and then esterified by cyclic anhydride in the presence of catalysts such as N,N‐dimethyl‐4‐aminopyridine, tripropylamine, tributylamine, and calcium carbonate. This method was fast and reproducible with the LiCl system as a solvent and with an efficient activation by controlled microwave power. In this way, the reaction time was reduced from several hours to just a few minutes. The reaction products were characterized by IR and solid‐state cross‐polarization/magic angle spinning ¹³C‐NMR spectroscopy. The degree of substitution (DS) and the grafted ester group content of the different products were obtained by alkali saponification followed by titration of the excess alkali. Two activation methods were compared, and the results show that the application of classical heating gave less successful results than those obtained by microwave activation. Indeed, with microwave activation, a higher DS (2.25) was obtained after 10 min. However, with classical heating, a value of DS equal to 1.2 was obtained after 12 h. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

n-pentane isomerization and disproportionation catalyzed by promoted and unpromoted sulfated zirconia

Isomerization and disproportionation of n-pentane were catalyzed by sulfated zirconia, Fe- and Mn-promoted sulfated zirconia, and Pt-, Fe-, and Mn-promoted sulfated zirconia in a flow reactor at temperatures of −25 to 50°C and n-pentane partial pressures of 0.005–0.01 atm. Incorporation of the Fe and Mn promoters increased the activity of the sulfated zirconia by two orders of magnitude at 50°C; addition of Pt to the latter catalyst increased the activity only slightly. The primary reactions, disproportionation (to give butanes and hexanes) and isomerization, occurred in parallel; secondary disproportionation reactions gave heptanes, propane, butanes, and pentanes. The data are consistent with acid-base catalysis and carbenium ion intermediates, and the isomerization is inferred to proceed both by unimolecular and bimolecular mechanisms. H₂ in the feed stream and Pt in the catalyst both led to reductions in the rate of catalyst deactivation. This revised version was published online in August 2006 with corrections to the Cover Date.     

Effects of rigor temperature and electrical stimulation on venison quality

The effects of rigor temperature and electrical stimulation on venison quality were assessed using venison longissimus dorsi muscle. In the first trial, effect of rigor temperature (0, 15, 25, 30, 35 and 42 °C) and time post-mortem (at rigor, 3, 7 and 14 days) on drip and cooking losses, % expressible water (water holding capacity, WHC), sarcomere length, protein solubility, meat tenderness and colour were investigated. In the second trial, the effects of rigor temperature (15 and 35 °C), electric stimulation (stimulated or not stimulated) and time (at rigor, 3 and 6 weeks post-mortem) on tenderness and colour were further investigated. Results of the first trial showed no clearly established trends of the effect of rigor temperature and time on the cooking and drip losses and protein solubility except venison muscles that went into rigor at 42 °C tended to have higher drip loss and lower protein solubilities compared to muscles that went into rigor at the other temperatures. Venison water holding capacity (WHC) decreased with the increase in rigor temperature (P < 0.001) and venison became more tender with time post-mortem. Venison colour improved with increasing rigor temperature. During display, samples that went into rigor at 15, 25 and 35 °C had the lowest and those at 0 and 42 °C had the highest rate of change of redness (a^*) value with time. In the second trial, tenderness was improved by stimulation (P = 0.01). Redness (a^*) values were affected by rigor temperature (P < 0.01) and post-mortem time (P < 0.001) but not by electrical stimulation. It is concluded that venison tenderness can be improved via the manipulation of rigor temperature to obtain acceptable level of tenderness early post-mortem with less damaging effect on colour stability.     

Investigation of the candesartan cilexetil antihypertensive drug microencapsulation by PLA-PVP K30 biodegradable polymers: Experimental optimization and release kinetics modelling

Candesartan is an angiotensin receptor blocker (ARB) used to treat hypertension. However, its poor aqueous solubility and oral bioavailability have limited its therapeutic applications. In order to increase bioavailability and control the release of candesartan condensation, microspheres containing biodegradable polymers (polyvinylpyrrolidone [PVP K30] and polylactic acid [PLA]) in different ratios were prepared by the o/o solvent evaporation method using Span 80 as a surfactant. In addition, the impact of encapsulation parameters (i.e., PVP K30 and PLA concentrations) on the encapsulation ratio and release percentage was investigated by the mixed factorial design method. The release kinetics of the microspheres was simulated by combining two methods, the Dragonfly algorithm and a support vector machine (DA-SVM). The experimental data were in good agreement with the predicted data, with a coefficient of determination close to unity and a mean square error close to zero. Fourier-transfer infrared spectrometry (FTIR) analysis revealed the presence of condensation in all formulations without reporting distortion in the spectra. Scanning electron microscopy (SEM) confirmed the successful synthesis of microspheres, whose sizes were between 12 and 26 μm. Formulations with a PLA-drug ratio of 6:1 (N15, N17, and N18) showed the highest encapsulation efficiency (68%, 71%, and 70%, respectively), while formulations that do contain PVP K30, such as N5, N4, and N3, showed a higher release (83%, 84%, and 89%, respectively), indicating that the agent (PVP K30) enhanced the bioavailability and release of candesartan. Overall, N3 showed a higher drug release rate at 12 h and important encapsulation efficiency, making it the optimal formulation obtained in this study.     

Towards Bayesian network methodology for predicting the equipment health factor of complex semiconductor systems

This paper presents a general methodology to improve risk assessment in the specific workshops of semiconductor manufacturers. We are concerned, in this case, with the problem of equipment failures and drifts. These failures are generally observed, with delay, during the product metrology phase. To improve the reactivity of the control system, we propose a predictive approach based on the Bayesian technique. Increased use of these techniques is the result of the advantages obtained. This approach allows early action to maintain, for example, the equipment before it can drift. Also, our contribution consists in proposing a generic model to predict the equipment health factor (EHF), which will define decision support strategies on preventive maintenance to avoid unscheduled equipment downtime. Following the proposed methodology, a data extraction and processing prototype is also designed to identify the real failure modes which will instantiate the Bayesian model. EHF results are decision support elements. They can be further used to improve production performance: reduced cycle time, improved yield and enhanced equipment effectiveness.     

The "sponge effect" hypothesis: an alternative explanation of the improvement in the waterholding capacity of meat with ageing

Bovine M. semimembranosus from different sexes of cattle were held at temperatures ranging from 0 to 35 °C until rigor and aged for up to 9 weeks. The waterholding capacity (WHC) of the beef increased with ageing as evidenced by the decline in drip loss measured gravimetrically, centrifugally and by pressure. Drip viscosity (P < 0.01), meat protein extractability (P < 0.05), spreadability (P < 0.01) and compressibility also increased with ageing. Evidence of structural changes was seen in SDS-PAGE confirming the physical changes. Meat spreadability under pressure and WHC were higher in samples with inherently higher pH relative to lower pH. The outcome of this study supports a hypothesis that the increase in WHC with ageing is due to the breakdown in meat structure and the creation of “sponge effect”, which disrupts the channels through which moisture is lost and physically entraps the free water in meat and reduce the amount that drips out.     

Single event upset mitigation by means of a sequential circuit state freeze

This paper describes a novel design technique for hardening sequential circuits against Single Event Transients (SETs) and Single Event Upsets (SEUs) in non-volatile FPGAs. Double Modular Redundancy (DMR) is used to detect the presence of a SET in a sequential circuit. However, DMR solutions are only able to detect SET’s and not mask or correct them. Therefore, extra functionality is required to mask and correct the error after it has been detected. The central idea of the method proposed is to “freeze” the sequential circuit at a particular state when a SET is detected. As soon as the SET dissipates, the circuit is “unfrozen” so that it can continue with normal operation. Due to the short SET lifetime versus much longer circuit clock periods, the “frozen” state will normally not last more than one clock period. The proposed scheme is suitable for delay-insensitive applications requiring minimal hardware overhead.The proposed DMR method is thoroughly tested on ITC99 benchmarks. With a small delay of one clock period whenever a SET is detected, the proposed method offers immunity against the errors caused by SETs in non-volatile FPGA systems.     

Functional stability of frozen normal and high pH beef

The functional properties of whole, diced or minced high and normal pH beef were determined after 0, 1, 2, 3 and 7 month’s storage. There was no interaction between pH, degree of comminution and storage time for most of the attributes measured. Regardless of storage time or comminution method, high pH meat had significantly (P < 0.001) higher sarcoplasmic protein solubility, water holding capacity, cooked batter torsion stress and strain, yield and emulsion stability than normal pH meat. Normal pH meat had significantly (P < 0.01) higher myofibrillar protein solubility and hue angle than high pH meat. Water holding capacity significantly (P < 0.01) decreased and hue angle increased with the increase in the degree of comminution. Protein solubility in raw meat and the cooked batter stress, strain, yield and emulsion stability of both high and normal pH meat deteriorated with time. However, this deterioration was faster in the normal pH meat compared to high pH meat except for total and myofibrillar protein solubility. Within the parameters of the present study, it is concluded that frozen high pH meat possesses superior functional attributes compared to normal pH meat regardless of the degree of comminution or storage time.     

Plastic deformation of low‐density polyethylene reinforced with biodegradable polylactide,Part 1: Microstructural analysis and tensile behavior at constant true strain‐rate

Blends of low‐density polyethylene (LDPE) and polylactide (PLA) were prepared by melt coextrusion. The plastic behavior of the LDPE/PLA blends was investigated at room temperature under uniaxial tension by means of a video‐controlled system. The constitutive behavior was analyzed in terms of the variations of true stress vs. true strain at constant true strain rate. With increasing concentrations of PLA, the blend show: (i) higher Young's modulus, (ii) stiffer viscoelastic response, (iii) increase of elastic limit stress, and (iv) earlier fracture. Particular attention was paid to the evolution of the volume strain with the applied strain. While dilatation begins very lately for the neat LDPE, the LDPE/PLA blends show increasing deformation damage as the PLA content is increased. Scanning electron microscopy of deformed specimens shows that cavitation occurs preferentially at the poles of the PLA particles whose adhesion to the LDPE matrix seems very weak despite the partial grafting of polyethylene chains with maleic anhydride. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers.