首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   386篇
  免费   11篇
  国内免费   1篇
电工技术   12篇
综合类   2篇
化学工业   82篇
金属工艺   14篇
机械仪表   21篇
建筑科学   24篇
能源动力   29篇
轻工业   21篇
水利工程   1篇
石油天然气   2篇
无线电   36篇
一般工业技术   60篇
冶金工业   11篇
原子能技术   9篇
自动化技术   74篇
  2024年   9篇
  2023年   10篇
  2022年   7篇
  2021年   32篇
  2020年   28篇
  2019年   32篇
  2018年   33篇
  2017年   21篇
  2016年   37篇
  2015年   12篇
  2014年   22篇
  2013年   39篇
  2012年   18篇
  2011年   30篇
  2010年   20篇
  2009年   11篇
  2008年   7篇
  2007年   5篇
  2006年   4篇
  2005年   3篇
  2004年   3篇
  2002年   1篇
  2000年   1篇
  1999年   1篇
  1998年   1篇
  1997年   1篇
  1996年   1篇
  1994年   3篇
  1993年   1篇
  1991年   1篇
  1990年   1篇
  1988年   1篇
  1983年   1篇
  1982年   1篇
排序方式: 共有398条查询结果,搜索用时 31 毫秒
101.
    
This article aims to appraise the effect of microstructure comprising molecular weight distribution and chemical composition distribution on the mechanical properties of high-density polyethylene (HDPE). HDPE resins were synthesized using several titanium–magnesium-supported Ziegler–Natta catalysts in the industrial gas phase reactor under the same polymerization condition. Gel permeation chromatography and crystallization elution fractionation (CEF) were conducted on the resins to characterize the molecular weight and comonomer distribution. Crystallization, thermal and rheological behavior were evaluated following differential scanning calorimetry, polarization light microscopy, and rheometric mechanical spectrometry. The resins with higher soluble fraction in trichlorobenzene below 80°C (highly branched low molecular weight chains) exhibited longer crystallization time based on the crystallization kinetic obtained from the Avrami model. Rheological determination of the molecular weight between entanglements (Me) and the average lamella thickness based on the Gibbs–Thomson equation revealed that the entanglement density and impact strength decreased, and the average lamella thickness increased with an increase in the ratio of CEF eluted fraction below 80°C to the crystallizable fraction in the range of 80–90°C.  相似文献   
102.
    
Surfaces with micro/nano-structures significantly enhance the critical heat flux of nucleate boiling by increasing the wickability of the liquid phase to delay film boiling. An alternative strategy, of removing surface bubbles at smaller sizes, is largely ignored. Here, they fabricate a rationally designed micro-structured surface that enables the coalescence-induced departure of microscopic vapor bubbles during the pool boiling of water at diameters an order of magnitude smaller than single-bubble buoyant departure. Arrays of micro-cavities or micro-grooves serve as tailored nucleation sites to nucleate close-packed vapor bubbles, which coalesce at unusually small sizes compared to a homogeneous surface. Two different modes of coalescence-induced bubble departure are observed and modeled: capillary-inertial jumping for smaller micro-bubbles and buoyant-inertial liftoff for larger micro-bubbles. Capillarity-enhanced pool boiling on micro-structured surfaces has the potential to dramatically enhance the heat transfer coefficient and critical heat flux of pool boiling.  相似文献   
103.
    
Polyethylene oxide (PEO) solid electrolytes are regarded as a promising candidate for all-solid-state lithium batteries owing to their high safety and interfacial compatibility. However, PEO electrolyte is plagued by relatively weak structural strength and unsatisfactory Li+ conductivity. Herein, a mechanically strong and Li+ conductively favorable cellulosic scaffold of PEO is fabricated through amino (-NH2) modification and g-C3N4 (CN) incorporation of bacterial cellulose (BC) under a microbial circumstance. The biologically -NH2 modified BC (B-NBC) is entangled with CN nanosheets (CN@B-NBC) through an in situ secretion of nanocellulose followed by hydrogen bond-induced self-assembly. The -NH2 groups from B-NBC weaken the complexation of Li+ with its counterpart, thus facilitating the release of more free Li+. CN with strong C-N covalence and extra lone electrons of N further strengthens the BC skeleton and meanwhile offers sufficient anchors for Li+ migration. After infiltrating by LiTFSI/PEO (LP), the LP/CN@B-NBC composite solid electrolyte (CSE) exhibits high lithium transference number and ionic conductivity. Upon coupling with LiFePO4 cathode, the full battery exhibits a remarkably high specific capacity, superior rate capability, and decent cycling stability. This work pioneers the attempts of chemical decoration and ingredient incorporation of BC architecture in CSE with the aid of a bottom-up biosynthetic avenue.  相似文献   
104.
    
Plastic waste pollution is a growing environmental concern due to the increased use of conventional plastics. This study investigates the techno-economics of biodegradable, bio-based plastics, i.e. polylactic acid (PLA) and polybutylene succinate (PBS), as potential substitutes for conventional plastics, to identify the most viable one to be produced in a biorefinery annexed to a typical sugar mill. Six potential biorefinery scenarios were simulated in Aspen Plus®, in which PLA or PBS is derived from sugarcane molasses (1G scenarios), bagasse and harvesting residues (2G scenarios) or a mixture of molasses, bagasse, and harvesting residues (1G2G scenarios). The economic feasibility of the PLA and PBS scenarios was evaluated by means of the minimum selling prices (MSP) for an acceptable return on investment. The PLA scenarios showed lower MSPs than PBS with the 1G2G scenario having the lowest MSP (2965 US$ t–1), comparable to the commonly available PLA from corn grain (5140 US$ t–1). Polylactic acid benefited from lower process energy demands (5.5–5.8 MJ kg–1 of biomass or sugars processed) compared to PBS (5.1–8.2 MJ kg–1), which plays a crucial role in an energy self-sufficient biorefinery. Furthermore, a 1G-biorefinery was identified producing a fully biobased PBS at an MSP of 2980 US$ t–1 that is price competitive against fossil-derived PBS (2380 US$ t–1) and partially bio-derived PBS (4730 US$ t–1). To date, this was the first study to evaluate the detailed techno-economics of a fully biobased and biodegradable PBS biorefinery in an energy self-sufficient context, which was demonstrated to be cost-competitive against both partial bio-derived PBS and fully bio-derived PBS. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd  相似文献   
105.
    
Juniper species contain abundant compounds that are used in the medicine, cosmetic, and wood industry. Furthermore, these components protect the genus against herbivores, pathogens and detrimental abiotic conditions. Stains and specific reagents can be used individually or simultaneously to mark cell shape, arrangement and the material they are made from. Microchemical analyses using specific reagents and stains under light microscopy are helpful for the characterization of chemical compounds present in plant tissues. The autofluorescence of endogenous fluorophores is used to enable their localization in plant cells and tissues. This paper aims to investigate the cytochemical and histochemical traits of the shoots (leaves and stems) and female cones (berries) of Juniperus seravschanica. Light and florescent microscopy techniques were used to analyze the cytology and localization of different compounds for the first time. Microscopy-based histochemical analyses revealed various products in terms of composition and distribution among the shoots and female cones. These specific compounds contained lignin, tannins, polysaccharides, starch, phenolic compounds, chlorophyll, terpenoids, neutral lipids, and proteins. However, the anatomical position of each metabolite and its concentration was different among leaf, stem, and female cone. Phenolic cells of young cones were differentiated into sclereid cells during development. The density of phenolic cells, sclereid cells, and resin glans was higher in female cones than leaves and stems. The high levels of various components can be related to high resistance of the species against biotic and abiotic stresses, confirm its industrial, pharmaceutical and agricultural applications and is useful for identification of diagnostic taxonomic traits.  相似文献   
106.
    
The objective of this paper is to develop a method for fault detection and approximation of linear impulsive systems exposed to actuator faults. Utilizing proposed sliding mode observer, states of the impulsive system are estimated. It is proved that estimation error dynamical system is asymptotically stable between jumps. In addition, an upper bound of the state estimation errors at jump instants has been derived explicitly. State estimations are used to reconstruct the fault signal. Furthermore, an upper bound of the fault estimation errors is obtained. Proficiency of the proposed method is evaluated under different fault scenarios using numerical simulations. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
107.
Recently, a large number of studies have addressed lot splitting as a means to reduce flow times as well as improve due date performance. Furthermore, a number of studies have examined scheduling policies in cellular manufacturing systems. These studies have been conducted under a variety of experimental factors, shop structures and operational assumptions. This study examines scheduling cellular manufacturing systems in the presence of lot splitting. In addition, we utilize various scheduling policies to test formally the underlying principles of the synchronous manufacturing philosophy. This is accomplished by utilizing exhaustive and non-exhaustive scheduling heuristics simultaneously at bottleneck and non-bottleneck workcentres. The results indicate that, under certain conditions, performing additional set-ups before the bottleneck can improve due date performance without an adverse effect on average flow time. Furthermore, we show that incurring additional set-ups after the bottleneck does not improve due date performance and may deteriorate flow time performance. These results conflict with some of the tenets of the synchronous manufacturing philosophy.  相似文献   
108.

In this critical note, the thermal stability behavior of ultra-fine grained (UFG) and nano-structured (NS) metals and alloys produced through severe plastic deformation (SPD) techniques is reviewed. For this case, the common engineering metals with body-centered cubic (BCC), face-centered cubic (FCC), and hexagonal close-packed (HCP) crystal structures such as aluminum, copper, nickel, magnesium, steel, titanium, and their relating alloys were assessed. Microstructural evolution in these severely deformed materials following post-processing annealing treatment was investigated for various times and temperatures below the recrystallization point. The microstructure development reported in the literature was studied in terms of the stable grain structures correlated with different levels of plastic straining. The stacking fault energy (SFE) is noted to be a key issue which has a critical influence in predicting the coalescence or coarsening behavior of ultra-fine and nanoscale grains after SPD treatment by controlling the cross-slip phenomenon for screw dislocations.

Graphical Abstract
  相似文献   
109.
110.
Graph G is the square of graph H if two vertices x,y have an edge in G if and only if x,y are of distance at most two in H. Given H it is easy to compute its square H 2, however Motwani and Sudan proved that it is NP-complete to determine if a given graph G is the square of some graph H (of girth 3). In this paper we consider the characterization and recognition problems of graphs that are squares of graphs of small girth, i.e. to determine if G=H 2 for some graph H of small girth. The main results are the following.
  • There is a graph theoretical characterization for graphs that are squares of some graph of girth at least 7. A corollary is that if a graph G has a square root H of girth at least 7 then H is unique up to isomorphism.
  • There is a polynomial time algorithm to recognize if G=H 2 for some graph H of girth at least 6.
  • It is NP-complete to recognize if G=H 2 for some graph H of girth 4.
These results almost provide a dichotomy theorem for the complexity of the recognition problem in terms of girth of the square roots. The algorithmic and graph theoretical results generalize previous results on tree square roots, and provide polynomial time algorithms to compute a graph square root of small girth if it exists. Some open questions and conjectures will also be discussed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号