Synthesis and Characterizations of Triphenylamine End-Functionalized Polymers via Reversible Addition-Fragmentation Chain Transfer Polymerization

A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA) group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers. The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE as the RAFT agent. Number-average molecular weight (M_n,GPC) increased linearly with monomer conversion, and molecular weight distributions were relatively narrow (PDI< 1.50). The results of chain-extension reaction, ¹H NMR spectra and UV/Vis spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine (TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated.     

状如琼，凝为脂

在我们喝的饮料粒粒橙中，为什么那些细小的橙子颗粒是悬浮在橙汁中的呢？果冻和布丁为什么是透明，且柔软有弹性的呢？去看看成分表，我们不难发现共同之处，看似不同的食品都添加了一种共同的成分——琼脂。[编者按]     

无纸化建造

本文通过分析先锋建筑师借鉴汽车制造领域的无纸化技术进行的建造实践,揭示了无纸化建造的操作过程,并探讨了无纸化建造的意义,那就是无纸化不仅改变了传统的设计方法,而且改变了传统的建造方式,这将是人类的建造技术发展史上的一场伟大的变革.文章最后探讨了无纸化建造在中国的实践意义.     

基于作业测定技术的后桥壳生产线工艺评价及优化

以某企业后桥壳生产线为研究对象,运用作业测定技术中的时间研究法,测定后桥壳各工序的标准时间,评价工艺及找到瓶颈工序;运用"5W1H"提问技术,根据"ECRS"原则,同时结合工艺设计及企业资源情况,对后桥壳生产线现有工艺进行评价及优化,改善后,使生产线的产能每天提高了10件,生产能力提高了33.57%.     

探讨某高级车库设计需要注意的几点问题

广州市现在每天增加的小汽车数量就在400辆以上，这种迅猛的增长势头除了对城市的交通运输网络造成很大的压力外，城市的停车缺口也在不断扩大，现在广州市的停车位缺口就在30万辆左右。针对这种情况，地方政府正在加大解决城市停车难问题的力度．其中一项措施就是增加建设停车库。     

从关联分析法看如何改善沥青抗老化性能

用灰色关联分析法研究了沥青抗老化性能与沥青化学组成之间的关联程度，结果表明，影响再生沥青性质的主要因素是沥青中的芳烃和胶质的含量。通过添加芳香组分能改善沥青四组分之间的配伍性，从而可以改善再生沥青的抗老化性能。并通过对再生剂进行富芳处理，验证了上述结论。     

镍氢电池负极用低成本储氢合金的研究

研究了ABS型储氢合金在低Co含量条件下，随B组元替代元素Co，Al，Si等含量的变化对合金电化学性能的影响规律，同时研究了A组元中不同La／Ce比对合金电化学性能的影响情况。结果表明，随合金中Co含量的降低，合金的活化性能和放电容量得以改善，但合金的循环寿命下降也比较明显；在试验范围内，随Al元素的加入，合金的循环寿命得以改善，但材料的放电容量和活化性能均有所下降；随合金La／Ce比的降低，合金的放电容量略有下降，但其循环寿命和放电电压平台有较大提高。     

Simulating a Smartboard by Real-Time Gesture Detection in Lecture Videos

Gesture plays an important role for recognizing lecture activities in video content analysis. In this paper, we propose a real-time gesture detection algorithm by integrating cues from visual, speech and electronic slides. In contrast to the conventional “complete gesture” recognition, we emphasize detection by the prediction from “incomplete gesture”. Specifically, intentional gestures are predicted by the modified hidden Markov model (HMM) which can recognize incomplete gestures before the whole gesture paths are observed. The multimodal correspondence between speech and gesture is exploited to increase the accuracy and responsiveness of gesture detection. In lecture presentation, this algorithm enables the on-the-fly editing of lecture slides by simulating appropriate camera motion to highlight the intention and flow of lecturing. We develop a real-time application, namely simulated smartboard, and demonstrate the feasibility of our prediction algorithm using hand gesture and laser pen with simple setup without involving expensive hardware.      

稀土改善09CuPTiRE耐候钢耐蚀性的作用机理

应用扫描电镜(SEM)、离子探针(IMA)、X射线光电子能谱(XPS)和交流阻抗法研究含不同稀土耐候钢稀土提高耐大气腐蚀作用机理。结果表明,合适的稀土含量可显著提高钢的耐腐蚀性,稀土能促进Si、Cu和P在内锈层中以Si~(4+)、Cu~+和P~(5+)形态富集,并观察到锈层中的稀土。钢中加入稀土形成了致密连续厚而粘附性好的含硅铜稀土的复合铁锈层,从而提高了抗大气腐蚀性能。     

美国钢铁企业的并购浪潮及特点分析

介绍了最近美国大型钢铁企业发生的主要并购活动。并对这些并购活动的特点进行了分析。