A growth mark method for studying growth mechanism of carbon nanotube arrays

A novel and simple growth mark method was developed to make marks during the growth process of carbon nanotube arrays. These marks can be read out under scanning electron microscope or optical microscope. Based on this method, the growth rates at different temperatures and under different acetylene partial pressures were measured, from which the activation energy and the order of reaction were determined. Based on our experimental results, the growth of carbon nanotube arrays in our experimental condition could not be diffusion-limited. The measured activation energy could possibly be attributed to the heterogeneous decomposition of acetylene over the catalyst particle. Furthermore the marked array with special segmental structure may be found some applications in the future.     

The kinetics of B‐a and P‐a type copolybenzoxazine via the ring opening process

The structure of benzoxazines is similar to that of phenolic resin through thermal self‐curing of the heterocyclic ring opening reaction that neither requires catalyst nor releases any condensation byproduct. These polybenzoxazine resins have several outstanding properties such as high thermal stability and high glass transition temperature. To better understand the curing kinetics of this copolybenzoxazine thermosetting resin, dynamic and isothermal differential scanning calorimetry measurements were performed. Three models, the Kissinger method, the Flynn–Wall–Osawa method, and the Kamal method, were used to describe the curing process. Dynamic kinetic activation energies based on Kissinger and Flynn–Wall–Osawa methods are 72.11 and 84.06 KJ/mol, respectively. The Kamal method based on an autocatalytic model results in a total order of reaction between 2.66 and 3.03, depending on curing temperature. Its activation energy and Arrhenius preexponential are 50.3 KJ/mol and 7959, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 730–737, 2005     

Mathematical model of deoxidization with post stirring in a combined blowing converter

Dissolved oxygen in the steel at the terminal of the converter smelting process is the main cause for the formation of oxide inclusions, and the high terminal oxygen content worsens the steel cleanness. However, post stirring in a combined blowing converter can promote the carbon-oxygen reaction in the liquid steel and reduce the dissolved oxygen content at the terminal of the converter smelting process. Thus, the mathematical model of deoxidization in the post stirring process was obtained, and the rationa...     

稳定路径的Ad hoc网络QoS路由算法

移动Ad hoc网络中节点移动或能量耗尽会使得建立的QoS路径断裂而需重构路由,造成通信中断,对实时业务造成严重影响,提出了一种基于路径稳定性的QoS路由算法.该算法采用网络探测技术,综合考虑链路和节点稳定性,选择一条最稳定的路径进行通信,并实时监测路径状态变化,有效降低通信中断的概率.仿真表明,该算法有效改善了分组传送成功率、时延抖动等网络性能.     

确定土壤背景值的Hazen概率法——以铜陵矿区Pb为例

本文选取已知土壤背景含量的铜陵矿区,基于Hazen概率曲线,探讨了土壤污染重金属元素Pb背景含量与污染叠加含量的区分方法.得到Pb元素的背景含量为28.5μg/g,与该区深层土壤样中Pb元素含量的平均值(34μg/g)比较接近.还得到了Pb元素污染叠加含量与背景含量的界线点51μg/g.基于Hazen概率曲线区分铜陵矿区土壤Pb元素背景含量与污染叠加含量的方法是有效的,有必要将该方法推广到土壤中其它重金属污染元素、其它地区作进一步研究.     

AHP综合排序算法分析及其改进

层次分析法(AHP)是分析多目标评价、多指标决策问题时的一种常用的算法工具,但是传统AHP在进行综合排序时,却存在一定的算法缺陷,AHP不能保持各方案之间的独立性,导致当某些方案的指标值或者备选方案数量发生变化时,即使在同一评价标准下,AHP法也不能始终保证方案的排序的一致.针对这一问题,分析了AHP产生排序不一致的具体原因,指出其算法会导致最底层相对重要值会随着方案的数量的增加逐渐减少.提出用各方案与理想方案之间的相对效用指标代替传统AHP的综合排序指标,以使其能够始终保持各方案排序的一致性.给出的算例验证新方法的有效性.     

桁架结构形状优化的粒子群优化算法

为解决有应力约束、几何约束以及局部稳定性约束的桁架结构的形状优化设计,将粒子群优化(PSO)算法应用于桁架结构的形状优化设计.首先详细介绍了原始PSO算法的基本原理,然后引入压缩因子改进了原始的PSO算法,并提出了合理的参数设置值.优化计算过程中,综合考虑了节点坐标和截面面积等两类不同性质的设计变量.最后对几个经典问题进行了求解,并与传统的优化算法进行了比较.数值结果表明,改进的PSO算法具有良好的收敛性和稳定性,可以有效地进行桁架结构的形状优化设计.     

三等径圆管曲面连接的连续性研究及实现的方法

本文详细叙述和分析了曲线和曲面连接的位置连续(GO)、相切连续(G1)和曲率连续(G2),得出曲率连续(G2)光滑度最高的结论.最后举例说明了三等径圆管如何实现G2曲面连接的方法.     

冷再生结构层力学响应分析

通过研究冷再生结构层受力分析,在室内试验数据基础上,采用有限元BISAR软件对冷再生结构层以及常规半刚性路面结构层进行力学响应分析,得出了常规半刚性基层与冷再生基层力学响应的差异、冷再生层合理厚度、冷再生基层路面铣刨深度以及冷再生基层路面的使用条件.该研究对冷再生结构层设计与施工具有一定的借鉴作用.     

建设工程涉外设计合同风险防范

中国参加WTO后,在扩大对外开放、拉动内需保增长政策指导下,一大批重点建设工程陆续上马,有许多外国设计企业及其在华机构加入中国建设工程的设计,其中,国有独资项目占据很大的比重。笔者结合参与全国十运会场馆一南京奥体中心以及江苏省人民医院扩建、南京图书管等多个大型项目工程全程法律保障实践,就工程设计合同风险防范,一舒管见。