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1.
Celia Nieto Milena A. Vega Eva M. Martín del Valle 《International journal of molecular sciences》2021,22(6)
Ferroptosis is gaining followers as mechanism of selective killing cancer cells in a non-apoptotic manner, and novel nanosystems capable of inducing this iron-dependent death are being increasingly developed. Among them, polydopamine nanoparticles (PDA NPs) are arousing interest, since they have great capability of chelating iron. In this work, PDA NPs were loaded with Fe3+ at different pH values to assess the importance that the pH may have in determining their therapeutic activity and selectivity. In addition, doxorubicin was also loaded to the nanoparticles to achieve a synergist effect. The in vitro assays that were performed with the BT474 and HS5 cell lines showed that, when Fe3+ was adsorbed in PDA NPs at pH values close to which Fe(OH)3 begins to be formed, these nanoparticles had greater antitumor activity and selectivity despite having chelated a smaller amount of Fe3+. Otherwise, it was demonstrated that Fe3+ could be released in the late endo/lysosomes thanks to their acidic pH and their Ca2+ content, and that when Fe3+ was co-transported with doxorubicin, the therapeutic activity of PDA NPs was enhanced. Thus, reported PDA NPs loaded with both Fe3+ and doxorubicin may constitute a good approach to target breast tumors. 相似文献
2.
3.
TeMxMo1.7O mixed oxides (M = V and/or Nb; x = 0-1.7) have been prepared by calcination of the corresponding salts at 600 °C in an atmosphere of N2. A new crystalline phase, with a Te/V/Mo atomic ratio of 1/0.2-1.5/1.7, has been isolated and characterised by XRD and IR spectroscopy. This phase is observed in the TeVMo or TeVNbMo mixed oxide but not in the TeNbMo mixed oxide. The new crystalline phase shows an XRD pattern similar to Sb4Mo10O31 and probably corresponds to the M1 phase recently proposed by Aouine et al. (Chem. Commun. 1180, 2001) to be present in the active and selective MoVTeNbO catalysts. Although these catalysts present a very low activity in the propane oxidation, they are active and selective in the oxidation of propene to acrolein and/or acrylic acid. However, the product distribution depends on the catalyst composition. Acrolein or acrylic acid can be selectively obtained from propene on Nb-free or Nb-containing TeVMo catalysts, respectively. The presence of both V and Nb, in addition to Mo and Te, appears to be important in the formation of acrylic acid from propene. 相似文献
4.
C Nieto 《Archivos latinoamericanos de nutrición》1991,41(2):213-221
An analysis of tuber roots yield and nutritional characteristics for 10 lines of jícama (Polymnia sonchifolia Poepp et Endl.) was carried out under the environmental conditions of Santa Catalina Experimental Station (12 degrees C of temperature and 3,100 m above sea level). The following average mean values were obtained: A fresh tuber root's yield from 29,755 to 73,558 kg/ha with 41,547 kg/ha of average, while the yield of the useful part (roots without skin) was from 24,309 to 60,097 kg/ha with 33,944 kg/ha of average. On the other hand, average mean values of 3.7% of protein, 3.5% ashes, 1.5% fat, 3.4% fiber, 2.2% potassium, 0.12% phosphorus, 96 micrograms/100 g iron, and 390 micrograms/100 g zinc, were obtained from the edible root samples. Besides, we obtained average values of 2.47, 2.12, 1.63 and 2.51 g/100 g of fructose, alfa glucose, beta glucose and saccharose, respectively, on edible root samples with skin, for the 10 lines studied. All these analyses were reported on a dry basis. 相似文献
5.
A. T. Sousa P. S. Fialho C. A. Nieto de Castro R. Tufeu B. Le Neindre 《International Journal of Thermophysics》1996,17(3):551-560
The density of HCFC 141b has been measured at several temperatures between 260 and 320 K, Mid pressures up to 20 MPa, with a mechanical oscillator densimeter. The densimeter was calibrated with 2,2,4-trimethylpentane, whose density was obtained from a correlating cyuation with 0.3% uncertainty. The density data obtained for HCFC 14H) hits a reproducibility of 0.05% and an uncertainty of 0.3%. The data obtained were fitted to a Tait-type equation. which reproduced the experimental densities within 0.11 % and were compared with the data obtained in other works.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A. 相似文献
6.
Athanasios Eftaxias Josep Font Agusti Fortuny Azael Fabregat Frank Stüber 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(6):677-687
The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry 相似文献
7.
8.
J. C. G. Calado J. M. N. A. Fareleira U. V. Mardolcar C. A. Nieto de Castro 《International Journal of Thermophysics》1988,9(3):351-363
The thermal conductivity of liquids has been shown in the past to be difficult to predict with a reasonable accuracy, due to the lack of accurate experimental data and reliable prediction schemes. However, data of a high accuracy, and covering wide density ranges, obtained recently in laboratories in Boulder, Lisbon, and London with the transient hot-wire technique, can be used to revise an existing correlation scheme and to develop a new universal predictive technique for the thermal conductivity of liquid normal alkanes. The proposed correlation scheme is constructed on a theoretically based treatment of the van der Waals model of a liquid, which permits the prediction of the density dependence and the thermal conductivity of liquid n-alkanes, methane to tridecane, for temperatures between 110 and 370 K and pressures up to 0.6 MPa, i.e., for 0.3T/T
c0.7 and 2.4P/P
c3.7, with an accuracy of ±1%, given a known value of the thermal conductivity of the fluid at the desired temperature. A generalization of the hard-core volumes obtained, as a function of the number of carbon atoms, showed that it was possible to predict the thermal conductivity of pentane to tetradecane±2%, without the necessity of available experimental measurements. 相似文献
9.
Helmut Alt Esther M. Arkin Alon Efrat George Hart Ferran Hurtado Irina Kostitsyna Alexander Kröller Joseph S. B. Mitchell Valentin Polishchuk 《Theory of Computing Systems》2014,54(4):689-714
We show how to compute the smallest rectangle that can enclose any polygon, from a given set of polygons, in nearly linear time; we also present a PTAS for the problem, as well as a linear-time algorithm for the case when the polygons are rectangles themselves. We prove that finding a smallest convex polygon that encloses any of the given polygons is NP-hard, and give a PTAS for minimizing the perimeter of the convex enclosure. We also give efficient algorithms to find the smallest rectangle simultaneously enclosing a given pair of convex polygons. 相似文献
10.
Carbon materials and catalytic wet air oxidation of organic pollutants in wastewater 总被引:1,自引:0,他引:1
F. Stüber J. Font A. Fortuny C. Bengoa A. Eftaxias A. Fabregat 《Topics in Catalysis》2005,33(1-4):3-50
The use of carbon materials as catalytic support or direct catalyst in catalytic wet air oxidation (WAO) of organic pollutants is reviewed. The discussion covers important engineering aspects including the characterisation, activity and stability of carbon catalysts, process performance, reaction kinetics and reactor modelling. Recommendations for further research in catalytic WAO are outlined. 相似文献