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Lorenzo Spinelli Giovanna Tissoni Luigi A. Lugiato Massimo Brambilla 《Journal of Modern Optics》2013,60(14-15):2413-2422
We introduce here a model which includes the thermal dynamics in the time evolution of a semiconductor multiple quantum well microresonator, driven by a coherent holding beam. The active layer is electrically pumped, in order to obtain population inversion, but it is maintained below the lasing threshold. We show that the inclusion of thermal effects introduces a Hopf instability which may dominate the dynamical behaviour of the system in some operational regimes. In those cases our numerical simulations show that both spatial patterns and cavity solitons perform a drift motion in the transverse direction. This motion develops over the slow time scale which characterizes thermal effects. 相似文献
34.
Modeling and performance analysis of an absorption chiller with a microchannel membrane‐based absorber using LiBr‐H2O,LiCl‐H2O,and LiNO3‐NH3
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In order to develop compact absorption refrigeration cycles driven by low heat sources, the simulated performance of a microchannel absorber of 5‐cm length and 9.5 cm3 in volume provided with a porous membrane is presented for 3 different solution‐refrigerant pairs: LiBr‐H2O, LiCl‐H2O, and LiNO3‐NH3. The high absorption rates calculated for the 3 solutions lead to large cooling effect to absorber volume ratios: 625 kW/m3 for the LiNO3‐NH3, 552 kW/m3 for the LiBr‐H2O, and 318 kW/m3 for the LiCl‐H2O solutions given the studied geometry. The performance of a complete absorption system is also analyzed varying the solution concentration, condensation temperature, and desorption temperature. The LiNO3‐NH3 and the LiBr‐H2O solutions provide the largest cooling effects. The LiNO3‐NH3 can work at a lower temperature of the heating source, in comparison with the one needed in a LiBr‐H2O system. The lowest cooling effect and coefficient of performance are found for the LiCl‐H2O solution, but this mixture allows the use of lower temperature heating sources (below 70°C). These results can be used for the selection of the most suitable solution for a given cooling duty, depending on the available heat source and condensation temperature. 相似文献
35.
Exploring laccase and mediators behavior during saccharification and fermentation of steam‐exploded wheat straw for bioethanol production
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36.
Rodolfo Daniel Velasco-Barraza Ricardo Vera-Graziano Eduardo Alberto López-Maldonado Mercedes Teresita Oropeza-Guzmán Syed G. Dastager Adriana Álvarez-Andrade 《国际聚合物材料杂志》2018,67(13):800-807
In recent times, electrospun nanofibers have been widely studied from several biotechnological approaches; in this work, poly(acrylic acid) (PAA) solutions mixed with chitosan and alginate were electrospun and characterized to determine the behavior of these fibers when used in combination with bacteria, different samples were incubated with the bacterial strains: Streptomyces spp., Micromonospora spp., and Escherichia coli and a OD600 test was performed. The formation of nanofibers via electrospinning and the physicochemical properties of the obtained fibers were evaluated. Results showed that the presence of chitosan enhanced the thermal stability of PAA, since PAA/alginate fibers lost 5% of their mass at 41°C, whereas PAA/chitosan lost this amount at around 125°C. The fibers demonstrated suitable characteristics to be used as a bacteria bioreactor. 相似文献
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Ester Rojo M. Virginia Alonso Beln Del Saz‐Orozco Mercedes Oliet Francisco Rodriguez 《应用聚合物科学杂志》2015,132(26)
Viscose cellulosic fibers from eucalyptus wood were treated with organosilanes to introduce specific functionalities on the fibers and enhance their wettability and adhesion with phenolic matrices in composites. Modeling procedures were employed to optimize the conditions of the treatments of the fibers with the silanes (3‐aminopropyl) trimethoxysilane (APS) and 3‐(2‐aminoethylamino) propyltrimethoxysilane (AAPS). The analyzed responses were relative intensities of the bands 1565/897 and 1120/897 cm−1, measured by Fourier transform infrared spectroscopy, and the silicon amount incorporated into the cellulosic fibers, which was determined by energy dispersive X‐ray analysis. In addition, surface morphology of the silane treated fibers was observed using scanning electron microscopy. The treatments of the cellulosic fibers with 2.2% APS for 120 min and 1.5% AAPS for 100 min were selected as optimums. According to contact angle measurements, both treatments enhanced the wettability between the fibers and a resol‐type phenolic resin, revealing the possible use of the silane treated fibers as reinforcement in phenolic composites. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42157. 相似文献
39.
Xuesong Lu Xiaojiao Luo Warren A. Thompson Jeannie Z.Y. Tan M. Mercedes Maroto-Valer 《Frontiers of Chemical Science and Engineering》2022,16(7):1149
The production of solar fuels via the photoreduction of carbon dioxide to methane by titanium oxide is a promising process to control greenhouse gas emissions and provide alternative renewable fuels. Although several reaction mechanisms have been proposed, the detailed steps are still ambiguous, and the limiting factors are not well defined. To improve our understanding of the mechanisms of carbon dioxide photoreduction, a multiphysics model was developed using COMSOL. The novelty of this work is the computational fluid dynamic model combined with the novel carbon dioxide photoreduction intrinsic reaction kinetic model, which was built based on three-steps, namely gas adsorption, surface reactions and desorption, while the ultraviolet light intensity distribution was simulated by the Gaussian distribution model and Beer-Lambert model. The carbon dioxide photoreduction process conducted in a laboratory-scale reactor under different carbon dioxide and water moisture partial pressures was then modeled based on the intrinsic kinetic model. It was found that the simulation results for methane, carbon monoxide and hydrogen yield match the experiments in the concentration range of 10−4 mol·m–3 at the low carbon dioxide and water moisture partial pressure. Finally, the factors of adsorption site concentration, adsorption equilibrium constant, ultraviolet light intensity and temperature were evaluated. 相似文献
40.
Arturo Lopez Quintela Mercedes Pazos Pellin Senen Paz Abuin 《Polymer Engineering and Science》1996,36(4):568-573
The kinetics of the reaction between trimethylolpropane (TMP) and epichlorohydrin (ECH) were studied. A mechanism is proposed which involves the synthesis of chlorohydrins, a previous stage which then leads to epoxy resin formation. From this mechanism a set of three coupled non-linear differential equations, (each equation corresponds to each chlorohydrin) was derived and numerical solutions were obtained using a Monte-Carlo method. The concentrations of chlorohydrins determined by this method (41.7, 35.7, and 22.5%) compare well with the experimental GPC results (42.7, 34.7, and 22.6%). The corresponding rate constants for the formation of the chlorohydrins were obtained. 相似文献