Effect of pH and zeta potential of Pickering stabilizing magnetite nanoparticles on the features of magnetized polystyrene microspheres

Styrene as a monomer was emulsified in water using several magnetite nanoparticles concentration and pH values. Emulsified styrene drops were used as templates for polymerization, in presence of water soluble free radical initiator, and formation of composite particles. Styrene template drops stabilization was verified by light as well as scanning electron microscopy imaging, which ensured the participation of the particles in building up a mechanical barrier to stop oil drops coalescence. Furthermore, the produced polystyrene composites were strongly attracted to an external magnet. The difference in particles size as a function of pH was elucidated using zeta potential measurements, which indicated dominance of pH on the hydrophilicity of the particles and consequently the extent of emulsification, which in turn affected the size of the obtained microspheres. Under some circumstances, capsules were formed instead of particles. Thereby, it can be concluded that the magnetic microspheres are optimally formed at pH 2.3 independently of the magnetite content used.     

Effect of bioactive dental adhesive on periodontal and endodontic pathogens

The objectives of this study were to: (1) develop a new bioactive dental bonding agent with nanoparticles of amorphous calcium phosphate and dimethylaminohexadecyl methacrylate for tooth root caries restorations and endodontic applications, and (2) investigate biofilm inhibition by the bioactive bonding agent against eight species of periodontal and endodontic pathogens for the first time. Bonding agent was formulated with 5?% of dimethylaminohexadecyl methacrylate. Nanoparticles of amorphous calcium phosphate at 30?wt% was mixed into adhesive. Eight species of biofilms were grown on resins: Porphyromonas gingivalis, Prevotella intermedia, Prevotella nigrescens, Aggregatibacter actinomycetemcomitans, Fusobacterium nucleatum, Parvimonas micra, Enterococcus faecalis, Enterococcus faecium. Colony-forming units, live/dead assay, biomass, metabolic activity and polysaccharide of biofilms were determined. The results showed that adding dimethylaminohexadecyl methacrylate and nanoparticles of amorphous calcium phosphate into bonding agent did not decrease dentin bond strength (P?>?0.1). Adding dimethylaminohexadecyl methacrylate reduced the colony-forming units of all eight species of biofilms by nearly three orders of magnitude. The killing efficacy of dimethylaminohexadecyl methacrylate resin was: P. gingivalis?>?A. actinomycetemcomitans?>?P. intermedia?>?P. nigrescens?>?F. nucleatum?>?P. micra?>?E. faecalis?>?E. faecium. Dimethylaminohexadecyl methacrylate resin had much less biomass, metabolic activity and polysaccharide of biofilms than those without dimethylaminohexadecyl methacrylate (P?<?0.05). In conclusion, a novel dental adhesive was developed for root caries and endodontic applications, showing potent inhibition of biofilms of eight species of periodontal and endodontic pathogens, and reducing colony-forming units by three orders of magnitude. The bioactive adhesive is promising for tooth root restorations to provide subgingival margins with anti-periodontal pathogen capabilities, and for endodontic sealer applications to combat endodontic biofilms.     

Embedding requirements within Model-Driven Architecture

Model-Driven Architecture (MDA) brings benefits to software development, among them the potential for connecting software models with the business domain. This paper focuses on the upstream or Computation-Independent Model (CIM) phase of MDA. Our contention is that, whilst there are many models and notations available within the CIM phase, those that are currently popular and supported by the Object Management Group (OMG) may not be the most useful notations for business analysts nor sufficient to fully support software requirements and specification. Therefore, with specific emphasis on the value of the Business Process Modelling Notation (BPMN) for business analysts, this paper provides an example of a typical CIM approach before describing an approach that incorporates specific requirements techniques. A framework extension to MDA is then introduced, which embeds requirements and specification within the CIM, thus further enhancing the utility of MDA by providing a more complete method for business analysis.     

An adaptive learning approach for 3-D surface reconstruction from point clouds.

In this paper, we propose a multiresolution approach for surface reconstruction from clouds of unorganized points representing an object surface in 3-D space. The proposed method uses a set of mesh operators and simple rules for selective mesh refinement, with a strategy based on Kohonen's self-organizing map (SOM). Basically, a self-adaptive scheme is used for iteratively moving vertices of an initial simple mesh in the direction of the set of points, ideally the object boundary. Successive refinement and motion of vertices are applied leading to a more detailed surface, in a multiresolution, iterative scheme. Reconstruction was experimented on with several point sets, including different shapes and sizes. Results show generated meshes very close to object final shapes. We include measures of performance and discuss robustness.     

Power system transient stability analysis: Formulation as nearly Hamiltonian systems

In this paper we formulate power systems as nonlinear nearly Hamiltonian systems. Using the invariance principle for ordinary differential equations, necessary and sufficient conditions for asymptotic stability are established and a new method of estimating the domain of attraction of the stable equilibrium point is developed. The present results constitute a novel approach to stability analysis and involve the following three steps:

1. Given a system with dissipation, the stability of its equilibrium is ascertained by determining the stability of the associated conservative system.
2. Attractivity of the stable equilibrium of the entire system (with dissipation) is determined from the system topology.
3. An estimate of the domain of attraction of the asymptotically stable equilibrium is obtained by making use of results obtained in (a) and (b).

The stability criterion developed in this paper sheds new light on the mechanism of instability in power systems and it provides analytical verification to the concept of the potential-energy boundary surface (PEBS). The PEBS is a hypersurface which makes up a part of the boundary of the domain of attraction of the stable equilibrium in a power system. The existence and properties of the PEBS have thus far been deduced primarily via simulations and heuristic methods.     

Optical parameter studies of thermally evaporated As-Se-Sn glassy system

The optical properties of As₃₀Se_70-xSn_x with (x = 0, 1, 2 and 3 at Sn %) thin films have been investigated. The films used in these studies were thermally evaporated. The structural characterization revealed that the as-deposited films were amorphous in nature. The spectral and optical parameters have been investigated using spectrophotometric measurements of transmittance in the wavelength range (200–1100 nm). The optical constants were determined from the interference maxima and minima using the Swanepole method. The dispersion of the refractive index is discussed in terms of the single-oscillator Wemple-Didomenico model. The optical-absorption edge and the optical band gap are calculated from the absorption coefficient values using the non direct transition model proposed by Tauc’s extrapolation procedure. The relation between the optical gap and chemical composition in As-Se-Sn glassy system is discussed in terms of the average heat of atomization H_s and the average coordination number N_c.     

Sludge Production and Settleability in Biofilm-Activated Sludge Process

The sludge production and settleability have been estimated experimentally in a completely mixed biofilm-activated sludge reactor (hybrid reactor). A steady-state hybrid reactor was run at different stages of suspended biomass concentration (X) under constant values of influent substrate concentration (So) and hydraulic retention time (HRT). The values of X were gradually decreased in these stages until the system completely washed out of the suspended biomass and converted to pure biofilm reactor. As a result, the role of biofilm in the treatment gradually increased with an increase in the effluent substrate concentration (S). The experiment was supported by a mathematical expression for describing the sludge yield in the system under the previous conditions. The experimental and theoretical studies in the present work reveal that there is a critical phase of the hybrid system at which the system produces a high rate of excess sludge. That critical phase is found at a specific ratio between the suspended and the attached growth. Avoiding that critical phase enables the sludge production in the hybrid reactor to be reduced and optimized. Further, the minimum sludge production was found when the biofilm is theoretically inactive for chemical oxygen demand (COD) removal (S相似文献   

Hierarchical Reliable Multicast: Performance Analysis and Optimal Placement of Proxies

This paper studies the use of multicast together with proxy nodes for reliably disseminating data from a single source to a large number of receivers. In order to achieve reliability, data must be retransmitted in case of loss either by the source or by special network nodes, called proxies. Each proxy is responsible for reliably delivering the data to a subgroup it is assigned. The multicast tree is partitioned into subgroups that form a hierarchy rooted at the source, hence the term hierarchical reliable multicast. The performance of this approach strongly depends on the topology and the loss characteristics of the underlying tree and the location of proxies. In the first part of the paper, we study the processing and bandwidth performance of such a reliable multicast dissemination given the tree and the placement of proxies. In the second part of the paper, we develop dynamic programming algorithms that give a placement of a fixed number of proxies on an arbitrary tree that minimizes the bandwidth used for reliable transfer. The first algorithm provides an optimal solution to the multicast proxies location problem in polynomial time, in the number of nodes and proxies. The second is an approximation algorithm that gives a solution with cost within a chosen precision from the optimal, in an improved running time. An optimal and an approximate solution are also provided for the proxies location problem if unicast is used for transmissions. Applications of this dynamic programming approach to related problems are discussed.