A new arrangement of blades in scraped surface heat exchangers for food pastes

The present study analyses the performance of a scraped surface heat exchanger (SSHE) equipped with a new arrangement of blades to achieve higher thermal efficiencies than the conventional SSHE. This new design of exchanger, named here as scraped surface heat exchanger with alternate blades, A-SSHE, may be particularly suited to treat high viscous fluids, like food pastes. Experimental and numerical tests were carried out on an industrial scale A-SSHE used to heat hazelnut paste, an intermediate product widely used in Italian confectionery industry. Experimental tests include physical, chemical and rheological characterization of the hazelnut paste and the evaluation of the overall heat transfer coefficient as a function of rotational speeds and mass flow rates. Three-dimensional axial-symmetric CFD simulations of the A-SSHE were performed by using the software Fluent 6.2. For comparison, the same numerical tests were carried out for an equivalent SSHE with a conventional blades design (C-SSHE). Our studies show that the A-SSHE gives heat transfer coefficient values almost twice that of an equivalent C-SSHE, and that the numerical results are consistent with the experimental observations. The analysis of the fluid dynamics and of the thermal profiles suggests that the higher heat transfer efficiency of A-SSHE may be attributed to the occurrence of backmixing phenomena.     

Diurnal and Nocturnal Measurements of Aerosol Optical Depth at a Desert Site in Namibia

The Namibian desert is a candidate site for astrophysical observations with ground-based instrumentation, such as the High Energy Stereoscopic System experiment. For this kind of application, the characterization of the atmospheric transmittance is mandatory. In this context, a first campaign of both solar and lunar direct irradiance measurements has been performed from 7 July 1998 to 10 July 1998 on a desert plateau in Namibia. The aerosol optical depth in the visible range (330-700 nm) has been measured; we found daily values (at 483 nm) ranging from 0.10 to 0.26, while the nightly ones range from 2.5 2 10 m 3 up to 0.86. By means of a least square fitting procedure, the Ångström turbidity parameters have been estimated. ( f daily values 0.92 1 3.64, f nightly values 0.008 1 4.2; g daily values 0.06 1 0.56, g nightly values 0.001 1 0.68). Furthermore, a relationship between Ångström parameters and meteorological variables such as relative humidity and wind speed has been investigated. The results do not highlight any correlation, except for two diurnal data sets that show a negative correlation between the optical thickness and the wind speed. Although preliminary, our measurements allow us to have a first insight into characterizing the aerosol optical properties of the Namibian background aerosol. On the other hand, an extended campaign of measurements is needed for a full characterization of the site.     

Osteogenic differentiation and mineralization in fibre-reinforced tubular scaffolds: theoretical study and experimental evidences

The development of composite scaffolds with well-organized architecture and multi-scale properties (i.e. porosity, degradation) represents a valid approach for achieving a tissue-engineered construct capable of reproducing the medium- and long-term in vitro behaviour of hierarchically complex tissues such as spongy bone. To date, the implementation of scaffold design strategies able to summarize optimal scaffold architecture as well as intrinsic mechanical, chemical and fluid transport properties still remains a challenging issue. In this study, poly ɛ-caprolactone/polylactid acid (PCL/PLA) tubular devices (fibres of PLA in a PCL matrix) obtained by phase inversion/salt leaching and filament winding techniques were proposed as cell instructive scaffold for bone osteogenesis. Continuous fibres embedded in the polymeric matrix drastically improved the mechanical response as confirmed by compression elastic moduli, which vary from 0.214 ± 0.065 to 1.174 ± 0.143 MPa depending on the relative fibre/matrix and polymer/solvent ratios. Moreover, computational fluid dynamic simulations demonstrated the ability of composite structure to transfer hydrodynamic forces during in vitro culture, thus indicating the optimal flow rate conditions that, case by case, enables specific cellular events—i.e. osteoblast differentiation from human mesenchymal stem cells (hMSCs), mineralization, etc. Hence, we demonstrate that the hMSC differentiation preferentially occurs in the case of higher perfusion rates—over 0.05 ml min^–1—as confirmed by the expression of alkaline phosphate and osteocalcin markers. In particular, the highest osteopontin values and a massive mineral phase precipitation of bone-like phases detected in the case of intermediate flow rates (i.e. 0.05 ml min^–1) allows us to identify the best condition to stimulate the bone extracellular matrix in-growth, in agreement with the hydrodynamic model prediction. All these results concur to prove the succesful use of tubular composite as temporary device for long bone treatment.     

Spectroscopic characterization of red perylimide/surfactant nanocomposites

Novel photoluminescent materials formed by some selected surfactants, metal derivatives of bis(2-ethylhexyl) sulfosuccinate (M(AOT) _n ; M = Na⁺, Co²⁺, Er³⁺ and Yb³⁺), bis(2-ethylhexyl) amine (BEEA), bis(2-ethylhexy1) phosphoric acid (HDEHP) and a 1:1 BEEA/HDEHP mixture, doped with the red perylimide (ROT-300) have been prepared, and their optical properties have been tested by absorption spectroscopy and steady state and time-resolved fluorescence. Experimental results show spectral shifts of the typical ROT-300 absorption and fluorescence bands with respect to that in apolar solvent medium. Data analysis leads consistently to attribute this feature mainly to the freezing of the diffusive movement of the dye molecules confined in the nanodomains of the surfactant liquid crystals, whilst minor effects can be due to interaction with the surfactant polar groups. Potentialities of these novel luminescent nanostructured composites as dye lasers, optical amplifiers and solar concentrators have been highlighted. In particular, under optical pumping using a pulse laser, amplified spontaneous fluorescence emission of the ROT-300/HDEHP system above an excitation energy threshold value of about 725 mJ cm⁻² was observed.     

Graphical method to select vegetable oils as potential feedstock for biodiesel production

Chemical compositions of 80 vegetable oils were collected from literature and the properties of the obtainable biodiesel (methyl esters) have been predicted by empirical relationships. The purpose has been to check the viability of predicting if a biodiesel could meet the EN 14214 standards knowing only the fatty acid profile (FAP) of the parent oil. Two parameters were used in this investigation: (i) average number of carbon atoms in the fatty acid chains, (ii) average number of double bonds (C?C) per molecule. Two new empirical relationships have been proposed to predict the viscosity and the cetane number of biodiesel from the two parameters. The range of values of the two parameters leading to biodiesel meeting the EN 14214 standard for viscosity, cetane number, iodine value, and cold filter plugging point have been graphically obtained by overlapping the corresponding level surfaces. Practical applications: This work provides biodiesel producers with indications of the quality of biodiesel without the need for analytical testing of the product (indeed, of the product itself). Only the fatty acid profile of the starting vegetable oil is required. The quality of biodiesel can be estimated by using a chart developed in this work, allowing to estimate, e.g. if the biodiesel meets the European standards. The work can be useful to rapidly screen oil seed crops in studies of genetic engineering that require high throughput.     

Polyamide 6 nanofibrous nonwovens via electrospinning

Electrospinning of Polyamide 6 (PA 6) in 2,2,2‐trifluoroethanol (TFE) was investigated for the fabrication of nanofibrous nonwoven membranes useful for separation systems. The effects of solution characteristics such as concentration and conductivity as well as the effects of processing conditions such as relative humidity and applied potential on the resultant nonwoven fibers were studied. By changing the relative humidity of the electrospinning chamber and the conductivity of the solvent, it is possible to modulate the fiber's size and consequently the porosity of the mats. The morphology of the electrospun PA 6 nanofibers was observed by scanning electron microscopy. The mechanical properties of the nanofibers were also studied. The results showed that PA 6 nanofibers having a diameter ranging from 100 to 600 nm, has been successfully prepared. The electrospun PA 6 nanofiber mats show good mechanical properties, such as a high‐tensile strength (12 ± 0.2 MPa) and elongation (300% ± 50%). The strength of the web was high enough to use as filter without the need of any supporting matrix and could be applicable in the field of self‐supporting membranes. The X‐ray and DSC analyses of the PA 6 electrospun fibers show the presence of the γ‐form of PA 6 crystallite that is usually obtained in the condition where a high stress of the fibers is applied. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010