Doped silicon and NIS junctions for bolometer applications

We discuss the performance, of a normal metal hot electron bolometer (NHEB) that we have measured at 0.3 K. We found that the noise equivalent power was limited by the amplifier noise. To improve the NHEB power response and to make it more robust and reliable we propose to substitute the normal metal with heavily doped silicon. The heavily doped silicon behaves like a metal with lower carrier concentration and has a smaller electron–phonon thermal coupling. We have fabricated superconductor-doped silicon-superconductor contacts (S-Sm-S) and we have used them as thermometers and coolers.     

Inorganic–organic hybrid materials with zirconium oxoclusters as protective coatings on aluminium alloys

Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr₄O₄(OMc)₁₂, where OMcCH₂C(CH₃)C(O)O, can be deposited as UV-cured films on aluminium alloys.

In particular, the molar ratios between the oxocluster and the monomer, the polymerisation time, the amount of photo-initiator and the deposition conditions, by using an home-made spray-coating equipment, were optimised in order to obtain the best performing layers in terms of transparency and hardness to coat aluminium alloy (AA1050, AA6060 and AA2024) sheets. Furthermore, it was also evaluated whether the hybrid coatings behave as barrier to corrosion.

Several coated samples were prepared and characterised. Environmental scanning electronic microscopy (ESEM) and scratch test were used to investigate the morphology of the films and to evaluate their scratch resistance, respectively. Electrochemical impedance spectroscopy (EIS) was performed in order to evaluate if the coatings actually protect the metallic substrate from corrosion.

In order to measure shear storage modulus (G′) and loss modulus (G″) of the materials used for coatings, bulk samples were also obtained by UV-curing of the precursors solution. Dynamical mechanical thermal analysis (DMTA) was performed in shear mode on cured disks of both the hybrid materials and pristine polymer for comparison. The values of T_g were read off as the temperatures of peak of loss modulus. The length and mass of all the samples were measured before and after the DMTA analysis, so that the shrinkage of the materials in that temperature range was exactly evaluated.     

Combined time and wavelength multiplexing technique of optical fiber grating sensor arrays using commercial OTDR equipment

The use of a commercial optical time domain reflectometry device for simultaneous wavelength and time domain multiplexing of fiber-optic Bragg grating sensors is proposed and demonstrated. The realization of such systems provides an inexpensive way of interrogating several hundreds of sensors in a single fiber. Strain resolution of 30 /spl mu/m/m over a strain measuring range of 0.5% was obtained.     

Lateral Walking-Induced Forces on Footbridges

In the last several years many cases of large amplitude horizontal vibrations of footbridges have been observed, due to dynamic interaction between the walkers and the footbridge, which may occur when some conditions on the bridge mass, frequency and damping, as well as on the crowd density are met. Such interaction is an intriguing phenomenon, as it is associated with the dynamics of a complex system made of a structure and a number of walkers, the dynamics of the latter being governed by physiology and psychology. Provided this complexity, in this paper a preliminary step is made toward the modeling of the interaction forces exerted by a crowd to a footbridge. The results of an experimental investigation of the lateral forces exerted by one walker to a fixed floor are presented, and used to calibrate a deterministic and stochastic lateral loading models of footbridges, to be used in the case in which no interaction takes place. The results presented are also the background data for more sophisticated dynamic models allowing for bridge-crowd interaction.     

Tensile and flexural creep rupture tests on partially-damaged concrete specimens

Three series of novel tensile and flexural creep tests on partially-damaged concrete specimens were carried out in order to gain some insight into creep crack growth and failure of strain-softening materials. In the tests, each specimen was initially loaded to a given point in the descending branch and thus had a lower load-carrying capacity than that at the peak-point. Then, the specimen was unloaded and reloaded to sustain a load which was from 70% to 95% of its current load-carrying capacity. Experimental creep curves display a three-stage process, consisting of primary, secondary and tertiary stages, with a decreasing, constant and increasing creep rate, respectively. The secondary stage dominates the whole failure lifetime, whereas both the secondary and tertiary stages are important in terms of creep deformation. Failure life-time seems to be more sensitive to the change of load level in flexural tests rather than in tensile tests. The decrease in load-carrying capacity due to damage tends to result in a shorter failure lifetime and a lower critical load level for creep rupture. The descending branch of the static load-deflection or load-CMOD curve may be used as an envelope criterion for creep fracture.     

Vibrational analysis of functionalized polyolefins/poly(vinylchloride) blends

Polyolefins functionalized with diethylmaleate were mixed with poly(vinylchloride) (PVC) in different compositions. Intermolecular interactions involving the carbonyl groups of the side chains of the functionalized polyolefins and methine hydrogens of PVC were investigated by means of infrared spectroscopy. The major flexibility of the ester groups attached to the backbone chains, with respect to polyesters, seems to increase the capability of such groups to interact with groups of more polar polymers, thus allowing prediction of easier miscibility, which however also depends on the starting polyolefin structure and function-alization degree.     

Layered Video and Differentiated Coding for Adaptive QoS in Mixed Wired-Satellite Networks

Mobile networks are becoming nothing but a way to allow ubiquitous access to multimedia services. To allow efficient use of resources, new systems provide flexible bandwidth and different error protection techniques to match channel behavior. As the backbone network is increasingly becoming based on packet techniques and in particular on IP and related transport protocols, end to end service quality must be analyzed considering both the fixed and the mobile part. Source scalability may help in coping with a mixed and heterogeneous environment. In this work we present some results of a transmission chain comprising a scalable MPEG-2 coder, an IP network and a radio access exploiting the availability of satellites. It is shown that for a given target rate, differentiated coding can be exploited to achieve decodability and good quality at a channel SNR much lower that single layer streams. This revised version was published online in July 2006 with corrections to the Cover Date.     

A low cost calibration conditioner for dynamic strain gauge measurements

A conditioner for dynamic strain measurements that allows for a series of calibration signals with periodic and predefined time occurrence, during the whole period in which the measurements have to be carried out, is presented in this work. The calibration signals, having suitable size ratios between them, allow one to evaluate the linearity of the entire measurement chain.     

Vacuum-u.v. circular dichroism of optically active isotactic poly-α-olefins

Summary Circular dichroism of isotactic samples of poly-(S)-4-methyl-1-hexene and poly-(R)-3,7-dimethyl-1-octene, have been measured in the vacuum ultraviolet spectral region (200-140 nm). The c.d. band at about 160. nm accounts for the optical activity in the visible region and reflects the presence of one screw sense helical conformation of the sample examined.The authors thank Prof. W.C. Johnson, Jr., Department of Biochemistry and Biophysics, Oregon State University, for allowing them to use the vacuum u.v. spectrometer. This work has been partially supported by a N.A.T.O. grant, and by Ministero Pubblica Istruzione (MPI), Roma — Italy.     

Electrical and magnetic properties of Polystyrene doped with Iron nanoparticles

Summary Polymer composites have recently received a considerable amount of scientific and technological interest, because their properties can be properly controlled, choosing the adequate doped particles, their size and concentrations, and the synthesis conditions. In this work we report the synthesis and characterization of a polystyrene (PS) matrix doped with different concentrations of iron nanoparticles. X-ray diffraction and transmission electron microscopy were used to characterize the structure of the samples. The behaviour of the d.c. electrical conductivity (σ_dc) and the complex permittivity (ε*=ε^′-iε^′′) as a function of frequency (100 Hz–10 MHz) reflects the important effect of the iron nanoparticles concentration in the sample properties. A percolation threshold in the conductivity was observed at a critical concentration of iron nanoparticles. A noticeable increase in the saturation magnetization and coercivity is observed with the rise of the iron nanoparticles concentration, being thisbehaviour also noticed in the remanent magnetization. A rise of the initial a.c. susceptibility with the iron concentration is also observed.