Comparison of ultraviolet femtosecond and nanosecond laser ablation inductively coupled plasma mass spectrometry analysis in glass, monazite, and zircon

We compared the analytical performance of ultraviolet femtosecond and nanosecond laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The benefit of ultrafast lasers was evaluated regarding thermal-induced chemical fractionation, that is otherwise well known to limit LA-ICPMS. Both lasers had a Gaussian beam energy profile and were tested using the same ablation system and ICPMS analyzer. Resulting crater morphologies and analytical signals showed more straightforward femtosecond laser ablation processes, with minimal thermal effects. Despite a less stable energy output, the ultrafast laser yielded elemental (Pb/U, Pb/Th) and Pb isotopic ratios that were more precise, repeatable, and accurate, even when compared to the best analytical conditions for the nanosecond laser. Measurements on NIST glasses, monazites, and zircon also showed that femtosecond LA-ICPMS calibration was less matrix-matched dependent and therefore more versatile.     

Towards efficient data distribution on computational desktop grids with BitTorrent

Datacentric applications are still a challenging issue for large-scale distributed computing systems. The emergence of new protocols and software for collaborative content distribution over the Internet offers a new opportunity for efficient and fast delivery of a high volume of data. This paper presents an evaluation of the BitTorrent protocol for computational desktop grids. We first present a prototype of a generic subsystem dedicated to data management and designed to serve as a building block for any desktop grid system. Based on this prototype we conduct experiments to evaluate the potential of BitTorrent compared to a classical approach based on FTP data server. The preliminary results obtained with a 65-node cluster measure the basic characteristics of BitTorrent in terms of latency and bandwidth and evaluate the scalability of BitTorrent for the delivery of large input files. Moreover, we show that BitTorrent has a considerable latency overhead compared to FTP but clearly outperforms FTP when distributing large files or files to a high number of nodes. Tests on a synthetic application show that BitTorrent significantly increases the communication/computation ratio of the applications eligible to run on a desktop grid system.     

A feasibility study on the use of anthropometric variables to make muscle–computer interface more practical

High classification accuracy has been achieved for muscle–computer interfaces (MCIs) based on surface electromyography (EMG) recognition in many recent works with an increasing number of discriminated movements. However, there are many limitations to use these interfaces in the real-world contexts. One of the major problems is compatibility. Designing and training the classification EMG system for a particular individual user is needed in order to reach high accuracy. If the system can calibrate itself automatically/semi-automatically, the development of standard interfaces that are compatible with almost any user could be possible. Twelve anthropometric variables, a measurement of body dimensions, have been proposed and used to calibrate the system in two different ways: a weighting factor for a classifier and a normalizing value for EMG features. The experimental results showed that a number of relationships between anthropometric variables and EMG time-domain features from upper-limb muscles and movements are statistically strong (average r=0.71?0.80) and significant (p<0.05). In this paper, the feasibility to use anthropometric variables to calibrate the EMG classification system is shown obviously and the proposed calibration technique is suggested to further improve the robustness and practical use of MCIs based on EMG pattern recognition.     

Pneumatic actuator control: Solution based on adaptive twisting and experimentation

An adaptive version of the twisting algorithm is proposed, which actually presents a new second-order sliding-mode algorithm. Due to the dynamic adaptation of the gains the controller design does not require complete information on the bounds of uncertainties and perturbations. It automatically decreases the gains and respectively also the dangerous oscillations due to a too large discontinuous-control magnitude. Thus, both the performance and the accuracy of the closed-loop system are improved. In order to show the feasibility of the approach, the methodology is successfully applied to control the position of a pneumatic actuator in an experimental setup.     

Failure mechanisms in granular media: a discrete element analysis

This paper attempts to numerically validate the concept of diffuse failure using a discrete element method. First, the theoretical background is reviewed, and it is shown how the kinetic energy of a system, initially at rest after a loading history, is likely to abruptly increase under the effect of disturbances. The vanishing of the second-order work thus constitutes a basic ingredient, related to both the pioneering work of Hill (J Mech Phys Solids (6):236–249, 1958) and the notion of bifurcation applied to geomechanics (Vardoulakis and Sulem in Bifurcation analysis in geomechanics, Chapman & Hall Publisher, London, 1995). Discrete numerical simulations were performed on homogeneous three-dimensional specimens, and the three basic conditions that must be satisfied in order to observe a failure mechanism are numerically checked. Finally, this work illustrates the phenomena that are likely to affect in situ slopes, for instance, when the loading (due to weather conditions or human activities) meets the three basic conditions for a failure mechanism to develop.     

Defect analysis and excitons diffusion in undoped homoepitaxial diamond films after polishing and oxygen plasma etching

Several 65 μm thick epitaxial diamond films prepared on (100) Ib substrates by high power pulsed microwave plasma assisted chemical vapour deposition (HP-MPCVD) are studied as a function of surface treatments by cathodoluminescence (CL) and photoluminescence (PL) spectroscopies. They are either asgrown, or polished, or etched by a microwave oxygen plasma, or after applying subsequently the two last processes. In CL spectra, bands due to defects occur at 2.3 eV, 3.07 eV, 3.7 eV and 4.7 eV, the last one being specific of polished surfaces, with nearly no contrast in the luminescence image. A fundamental result consists in demonstrating that the defects induced by polishing can be removed by oxygen plasma etching. Additionally, in order to assess how luminescence spectra originate from a peculiar depth or not, a bevelled sample is studied. PL spectra are acquired on the sample side while CL spectra are measured at several points on the bevel top side till to the Ib substrate. Comparison of the two sets of result show that the H3 signal originates from the Ib substrate even if it is present in the CL spectra of the film. An analysis of the change in the intensity of the TO free exciton line, defect bands and H3 signal, along decreasing photon energies, as a function of the thickness of the remaining HP-PMPCVD film, is performed with the help of a model taking the diffusion of the unrecombined excitonic pairs and the re-excited photoluminescence into account. CL images recorded at specific wavelengths, which do not show inverted contrast, are also assessed. From these data, the exciton diffusion length is evaluated to 11 μm in the major part of the epitaxial layer except for the first 20 μm close to the Ib substrate where it decreases down to 2 μm. This study sheds light on the interpretation of luminescence spectra excited by an electron beam in undoped diamond layers. Defects bands due to damages induced by polishing and etching processes are also documented.     

具有国际化魅力的法国美食

去年十二月份,厨师Franck Page先生加入北京佛雄食品店时正值北方大雪纷飞的日子.但按照Franck家乡的习俗,遇见()雪天意味着好兆头.在黎巴嫩著名的五星级饭店Vendome Intercontinental积累了丰富经验之后.Franck决定对自己的职业生涯做一次转折,于是他加入了享誉全球的著名法国集团佛雄,该集团刚刚在北京开办了第一家分部.Franck就这样来到了北京佛雄食品店.     

A first order method for the Cauchy problem for the Laplace equation using BEM

The purpose is to propose an improved method for inverse boundary value problems. This method is presented on a model problem. It introduces a higher order problem. BEM numerical simulations highlight the efficiency, the improved accuracy, the robustness to noisy data of this new approach, as well as its ability to deblur noisy data.     

Study of the R-(Zr,W)-(O,N) (R = Y, Nd, Sm, Gd, Yb) oxynitride system

The replacement of tantalum by the couple Zr/W within the RTa-O-N systems (R = Y, Nd, Sm, Gd, Yb), enables the preparation of novel oxide and oxynitride phases in the R-Zr-W-O-N system. R₂Zr_2−xW_xO_7+x oxides exhibit the fluorite-type (x < 0.9) and scheelite (x ∼ 1) structures. Corresponding oxynitride compositions are of the fluorite-type and show different colors, for example in the case of ytterbium: pale yellow (x = 0.2 or 0.25), green (x = 0.5-0.8) and brown for the tungsten-rich samples (x = 0.9, 1). Photocatalytic activity measurements have been performed to investigate the overall water splitting behavior of these colored phases.