Production and properties of micro‐porous glas bubble zinc and aluminium composites

Micro‐porous syntactic foams were produced by means of integration of glass bubbles into aluminium and zinc matrices. Preforms of glass bubbles were pressure infiltrated with the alloys AlSi9Cu9 ans ZnAl4Cu using squeeze casting. The preforms were sintered thermically without the use of bonding agents. Using the combination of different sintering steps syntactic foams with locally different densities could be produced. The mechanical properties of the foams were tested indicating a high compression strength of the foams and a very good compression energy absorption. Furthermore, corrosion behaviour and behaviour at higher temperatures were investigated.     

Fast method to compute the scalar product of gradient and given vector

The paper deals with a special problem in Automatic Differentiation. Letf be a rational function ofn variables, let #(f) denote the number of operations to evaluatef(x), letg denote the gradient off. Many algorithms for minimizingf(x) require the scalar productg(u) ^tv. In the standard method for computingg(u) ^tv the amount of work grows withn·#(f). In this note a new method for computingg(u) ^tv is presented. The new method is considerably faster, its amount of work only grows with #(f).     

The possibility of evolving a theory for predicting the service life of reinforced concrete structures

The development in recent years with increasing air pollution, increasing need of energy saving and last not least the growing number of damage in old structures leads to a raising demand to calculate the durability of structures, too. The paper has been prepared by request of the RILEM Technical Committee 45-LTO to show that, in principle, it is possible to evolve a theory for predicting the service life of r.c. structures and to sketch a way how that could be achieved. A lot of necessary basic data can be found scattered in the literature. To collect these data will be the first step to take.     

Regeneration studies on nickel molybdate catalysts used for the upgrading of coal-derived liquids

Nickel molybdate catalysts used in several different upgrading reactions of coal-derived materials from low-rank Australian coals have been regenerated and their activity assessed using a number of physical and chemical techniques. Regeneration of spent coked catalysts for 20 hours in air at 450°C was sufficient to restore chemical hydrogenation activity to catalyst used for pre-asphaltene, asphaltene and oil upgrading, provided poisoning of the catalyst surface by other impurities, principally chlorine-containing molecules, had not occurred.     

How to avoid logarithms in comparisons with uniform random variables

In many algorithms for sampling from non-uniform distributions the logarithm of a uniform deviate must be compared with some test quantity. It is shown that all these comparisons can be done efficiently without calling a logarithm subprogram: two procedures for this task are presented and compared.     

Preliminary Assessment of Contaminants in Soft Sediments of the Detroit River

Soft sediments from the Detroit River were analyzed for the USEPA priority pollutants to generally characterize contaminant distribution. Forty-three were detected. Highest heavy metal concentrations were found in the Trenton Channel and immediately downstream of Grosse Ile. They ranged from an area mean (N = 2) of 0.19 mg/kg mercury to 338.7 mg/kg zinc (dry weight). Polynuclear aromatic hydrocarbons ranged from 0.1 mg/kg to 38.8 mg/kg (mean, N = 2) with the highest levels near Grosse Ile. PCBs ranged from 0.015 mg/kg to 1.7 mg/kg (mean, N = 2). Organochlorine pesticides were not detected except for a trace of heptachlor in one sample. Sediment contamination in the Detroit River is widespread with higher concentrations on the U.S. side downstream of the Rouge River and in the Trenton Channel. The significance of these in-place pollutants to biota and as a source to Lake Erie is still unknown.     

On plastic potentials for anisotropic metals and their derivation from the texture function

Summary Plastic yielding of anisotropic metals can be either described by a macroscopic constitutive relation or assessed by means of a model which correlates single and polycrystal behaviors. The mathematical identification of the plastic work rate derived from the two approaches, for all strain rate tensors, leads to a fit of the polycrystal yield surface by an analytical function. When a quadratic from is assumed, the macroscopic anisotropy parameters become explicit functions of the texture coefficients. This identification method is applied to calculate yield surfaces andR-values of rolled and annealed steel sheets: theR-values and in general the flow rule, are more significantly modified by the fitting than the yield surface. Thus, it is worth extending the method to more general constitutive relations which may be given by the form of their work function: alternative forms of the work function for plastic materials are explored, especially in the bearing of convexity and homogeneity where quadratic forms have a distinct advantage. Finally, it is shown that the identification of the work function allows to express the phenomenological coefficients as analytical functions of the texture parameters for many forms of the work function; in the other cases, these coefficients may be obtained by linear or non-linear regression.