全文获取类型
收费全文 | 72110篇 |
免费 | 6062篇 |
国内免费 | 3252篇 |
专业分类
电工技术 | 3713篇 |
技术理论 | 9篇 |
综合类 | 4981篇 |
化学工业 | 12328篇 |
金属工艺 | 3980篇 |
机械仪表 | 4585篇 |
建筑科学 | 5753篇 |
矿业工程 | 1964篇 |
能源动力 | 2173篇 |
轻工业 | 4089篇 |
水利工程 | 1254篇 |
石油天然气 | 4905篇 |
武器工业 | 501篇 |
无线电 | 8181篇 |
一般工业技术 | 8955篇 |
冶金工业 | 3447篇 |
原子能技术 | 927篇 |
自动化技术 | 9679篇 |
出版年
2024年 | 218篇 |
2023年 | 1073篇 |
2022年 | 1765篇 |
2021年 | 2641篇 |
2020年 | 1982篇 |
2019年 | 1735篇 |
2018年 | 1928篇 |
2017年 | 2182篇 |
2016年 | 2049篇 |
2015年 | 2517篇 |
2014年 | 3351篇 |
2013年 | 4049篇 |
2012年 | 4149篇 |
2011年 | 4700篇 |
2010年 | 4135篇 |
2009年 | 3952篇 |
2008年 | 3909篇 |
2007年 | 3636篇 |
2006年 | 3778篇 |
2005年 | 3253篇 |
2004年 | 2414篇 |
2003年 | 2624篇 |
2002年 | 2950篇 |
2001年 | 2658篇 |
2000年 | 2099篇 |
1999年 | 2236篇 |
1998年 | 1712篇 |
1997年 | 1421篇 |
1996年 | 1368篇 |
1995年 | 1082篇 |
1994年 | 932篇 |
1993年 | 702篇 |
1992年 | 505篇 |
1991年 | 375篇 |
1990年 | 291篇 |
1989年 | 257篇 |
1988年 | 225篇 |
1987年 | 140篇 |
1986年 | 105篇 |
1985年 | 55篇 |
1984年 | 52篇 |
1983年 | 40篇 |
1982年 | 42篇 |
1981年 | 33篇 |
1980年 | 19篇 |
1979年 | 22篇 |
1978年 | 5篇 |
1976年 | 14篇 |
1970年 | 6篇 |
1966年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
Huizhu Cai Bingbing Chen Xiao Zhang Yuchen Deng Dequan Xiao Ding Ma Chuan Shi 《Nano Research》2021,14(1):122-130
Over recent years,catalytic materials of Fe-N-C species have been recognized being active for oxygen reduction reaction(ORR).However,the identification of active site remains challenging as it generally involves a pyrolysis process and mixed components being obtained.Herein Fe3C/C and Fe2N/C samples were synthesized by temperature programmed reduction of Fe precursors in 15%CH4/H2and pure NH3,respectively.By acid leaching of Fe2N/C sample,only single sites of FeN4species were presented,providing an ideal model for identification of catalytic functions of the single sites of FeN4in ORR.A correlation was conducted between the concentration of FeⅡN4in low spin state by Mossbauer spectra and the kinetic current density at 0.8 V in alkaline media,and such a structure-performance correlation assures the catalytic roles of low spin FeⅡN4 species as highly active sites for the ORR. 相似文献
32.
Qiaozhi Zhang Yanbo Wang Linglin Fu 《Comprehensive Reviews in Food Science and Food Safety》2020,19(5):2559-2587
Dietary advanced glycation end products (dAGEs) are complex and heterogeneous compounds derived from nonenzymatic glycation reactions during industrial processing and home cooking. There is mounting evidence showing that dAGEs are closely associated with various chronic diseases, where the absorbed dAGEs fuel the biological AGEs pool to exhibit noxious effects on human health. Currently, due to the uncertain bioavailability and rapid renal clearance of dAGEs, the relationship between dAGEs and biological AGEs remains debatable. In this review, we provide the most updated information on dAGEs including their generation in processed foods, analytical and characterization techniques, metabolic fates, interaction with AGE receptors, implications on human health and reducing strategies. Available evidence demonstrating a relevance between dAGEs and food allergy is also included. AGEs are ubiquitous in foods and their contents largely depend on the reactivity of carbonyl and amino groups, along with surrounding condition mainly pH and heating procedures. Once being digested and absorbed into the circulation, two separate pathways can be involved in the deleterious effects of dAGEs: an AGE receptor‐dependent way to stimulate cell signals, and an AGE receptor‐independent way to dysregulate proteins via forming complexes. Inhibition of AGEs formation during food processing and reduction in the diet are two potent approaches to restrict health‐hazardous dAGEs. To elucidate the biological role of dAGEs toward human health, the following significant perspectives are raised: molecular size and complexity of dAGEs; interactions between unabsorbed dAGEs and gut microbiota; and roles played by concomitant compounds in the heat‐processed foods. 相似文献
33.
与传统比例-积分-微分(PID)控制方法相比,滑模控制(SMC)方法可以比较容易地将不确定性纳入控制器设计中,从而增强系统的鲁棒性。探索了SMC技术在运载器主动段姿态控制中的工程应用,首先通过分析基于趋近律的SMC系统,提出了降低不连续切换项系数的需求,然后研究了基于干扰上界的SMC方法。三通道小偏差仿真结果验证了两种方法的控制效果,表明第2种控制器的鲁棒性更好,稳态误差小,同时发动机喷管摆角需求较小。 相似文献
34.
Yong Xu Yun Li Songlin Li Francis Balestra Gerard Ghibaudo Wenwu Li Yen‐Fu Lin Huabin Sun Jing Wan Xinran Wang Yufeng Guo Yi Shi Yong‐Young Noh 《Advanced functional materials》2020,30(20)
Unreliable mobility values, and particularly greatly overestimated values and severely distorted temperature dependences, have recently hampered the development of the organic transistor field. Given that organic field‐effect transistors (OFETs) have been routinely used to evaluate mobility, precise parameter extraction using the electrical properties of OFETs is thus of primary importance. This review examines the origins of the various mobilities that must be determined for OFET applications, the relevant extraction methods, and the data selection limitations, which help in avoiding conceptual errors during mobility extraction. For increased precision, the review also discusses device fabrication considerations, calibration of both the specific gate‐dielectric capacitance and the threshold voltage, the contact effects, and the bias and temperature dependences, which must actually be handled with great care but have mostly been overlooked to date. This review serves as a systematic overview of the OFET mobility extraction process to ensure high precision and will also aid in improving future research. 相似文献
36.
37.
38.
Baofeng Hou Hong He Ruixiu Jia Meilong Fu Yanbin Cao Shaoqun He Liwen Luo Youqing Huang 《应用聚合物科学杂志》2019,136(10):47161
The synthesis and performance of a novel temperature-tolerant foamed resin for enhanced oil recovery were investigated using various methods, including infrared, NMR, scanning electron microscopy (SEM), and displacement experiments. Polycondensation of furfuryl alcohol prepolymers was confirmed by the infrared and NMR results. The poor temperature tolerance of furfuryl alcohol prepolymers after gelation at high temperatures is mainly due to the fracture of furan rings. The addition of ester additives is an effective method of increasing the temperature tolerance of the prepared foamed resins and can effectively reduce the weight-loss rate of the polycondensation products. The SEM results show that the skeleton structure of the foamed resin remains intact after high-temperature treatment. Thus, the novel plugging agent system has excellent thermal stability and still has a high strength (>0.8 MPa) after high-temperature aging treatment for 40 days, giving the prepared foamed resin a good plugging performance (plugging rate > 91%) at 250 °C. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47161. 相似文献
39.
Dr. Jiayao Y. Wang Dr. Jiaqi Q. Li Prof. Dr. Yumei M. Xiao Prof. Dr. Bin Fu Prof. Dr. Zhaohai H. Qin 《ChemMedChem》2020,15(5):404-410
Mitochondrial oxidative damage and dysfunction contribute to a wide range of human diseases. Considering the limitation of conventional antioxidants and that mitochondria are the main source of reactive oxygen species (ROS) which induce oxidative damage, mitochondria-targeted antioxidants which can selectively block mitochondrial oxidative damage and prevent various types of cell death have been widely developed. As a lipophilic cation, triphenylphosphonium (TPP) has been commonly used in designing mitochondria-targeted antioxidants. Conjugated with the TPP moiety, antioxidants can achieve more than 1000-fold higher mitochondrial concentration depending on cell membrane potentials and mitochondrial membrane potentials. Herein we discuss the deficiencies of conventional antioxidants and the advantages of mitochondrial targeting, and review various types of TPP-based mitochondria-targeted antioxidants. These provide theoretical and background support for the design of new anti-oxidant. 相似文献
40.
In this study, the crystal structure, thermal, oxygen transport, electrical conductivity and electrochemical properties of the perovskite NdBa0.5Sr0.5Co2O5+δ (NBSC55) are investigated. In the temperature range of 250 °C–350 °C, the weight loss upon heating was due to a partial loss of lattice oxygen and along with a reduction of Co4+ to Co3+. The tend of weight-loss slows down as temperature increased above 350 °C indicating a reduction of Co3+ to Co2+ during this stage. The oxygen migration is dominated by surface exchange process at high temperature range (650-800 °C); however, the bulk diffusion process prevails at low temperature range (500–600 °C). For long-term testing, the polarization resistance of NBSC55 increases gradually form 3.13 Ω cm2 for 2 h to 3.34 Ω cm2 for 96 h at 600 °C and an increasing-rate for polarization resistance is around 0.22% h?1. The power density of the single cell with NBSC55 cathode reached 341 mW cm?2 at 800 °C. 相似文献