Preparation of CdS-doped Glasses from Gels Containing Diethyldithiocarbamatocadmium

CdS-doped SiO₂ glasses were prepared via silica gels containing diethyldithiocarbamatocadmium Cd(S₂CN(C₂H₅)₂)₂. Heat treatment of the gels gave transparent yellow SiO₂glasses doped with hexagonal CdS crystals. In optical absorption and fluorescence spectra, the optical absorption edge and the emission peak clearly exhibited a blue shift, which was attributed to the quantum size effect of the carrier confinement, as the CdS content was decreased. In the fluorescence spectra of the CdS-doped silica glasses, the emission peak was observed only near 500 nm and not observed at longer wavelengths which were known to be present if there were sulfur vacancies.     

Anodic Dissolution of Uranium Mononitride in Lithium Chloride-Potassium Chloride Eutectic Melt

Uranium-plutonium nitride is a candidate fuel for fast reactors, but its major drawback is ¹⁴C formation from natural nitrogen. One would probably have to use highly ¹⁵N-enriched nitrogen. A pyrochemical process with molten-salt electroreflning has been proposed as a means to increase the nuclear proliferation resistance of the fuel cycle. Molten-salt electroreflning could also be applied to nitride fuels to make possible the recycling of ¹⁵N. The anodic dissolution behavior of UN in LiCI-KCI melt was studied to provide the basis for a feasibility study of electroreflning of irradiated nitride fuels.     

Synthesis and hydrophilic property of polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA))

Polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA)), which is a hydrophobic-hydrophilic graft copolymer, was synthesized by a combination of an atom transfer radical polymerization (ATRP) of PEGMA with brominated polypropylene (PP-Br), which was synthesized from PP-OH prepared by metallocene-catalyzed copolymerization. Its structure was confirmed by ¹H NMR and GPC analyses. Transmission electron microscope (TEM) micrographs of PP-g-P(PEGMA) revealed the nanometer level microphase-separation morphology between the PP segment and the P(PEGMA) segment. The obtained PP-g-P(PEGMA) showed water-absorbing property as well as thermostability.     

On-Site Fabrication of Crystalline Cerium Oxide Films and Patterns by Ink-Jet Deposition Method at Moderate Temperatures

Crystalline CeO₂ films and patterns have been successfully fabricated in a single-step process at moderate temperature. In this process, the combination of the ink-jet technique and depositing the precursor on a hot substrate (≤300°C) gave crystalline CeO₂ without further heat treatment. X-ray diffraction analysis revealed that the phase formed was crystallized ceria with nanosized (<10 nm) crystallites. The film thickness was several hundred nanometers and the pattern width was about 150 μm. Scanning electron microscopy analysis showed that the films and patterns were free of cracks and adhered to the substrate. This is the first report about the direct patterning of crystalline CeO₂ without postfiring or posttreatments like masking, etching, etc.     

Effects of the Hydroxylation Patterns and Degrees of Polymerization of Condensed Tannins on their Metal-Chelating Capacity

Abstract

We studied the effects of the hydroxylation patterns and the degrees of polymerization of condensed tannins on their metal-chelating capacity. These effects were evaluated by the relative stability of aluminium complexes with proanthocyanidin. The relative stability of aluminium complexes was determined qualitatively in methanol solution by the competition with the metallochromic reagent (chrome azurol S). A comparison of these capacities indicates the following results: 1) phenolic hydroxy groups in tannins are essential sites for the chelation with metal. 2) the sites of tannins interacting with metal ions are mainly o-dihydroxyphenyl groups in B-ring. 3) increasing degrees of polymerization of tannins tends to increase the relative stability of condensed tannin-aluminium chelate.     

Robot vision robust to changes of lighting conditions using a wide-dynamic-range visual sensor

We have developed a robust vision system for 2D positioning of industrial parts stable to changes of lighting conditions. A wide dynamic range vision sensor that we had developed previously was used to avoid the saturation of object images. Additionally, a gray scale pattern matching technique was employed for robust image processing. Performance of the system with a wide dynamic range vision sensor was investigated experimentally in comparison with that of a system with a conventional video camera. The probability of correct positioning of an object under changing lighting conditions, simulating those in a factory, was 100% for the wide dynamic range vision sensor and 83% for the conventional video camera. The experimental results confirm the effectiveness of the developed system, revealing that dynamic range expansion of the video cameras is very effective for realizing robust robot vision systems. © 1997 Scripta Technica, Inc. Electr Eng Jpn, 120(2): 34–40, 1997     

Age differences in dynamical emotion-cognition linkages.

The ability to maintain the separation between positive emotion and negative emotion in times of stress has been construed as a resilience mechanism. Emotional resiliency is particularly relevant in old age given concomitant declines in cognitive performance. In the present study, the authors examined the dynamical linkages among positive emotion, negative emotion, and cognition as individuals performed a complex cognitive task. Comparisons were made between younger (n = 63) and older (n = 52) age groups. Older adults manifested significant unidirectional coupling from negative emotion to cognitive performance; younger adults manifested significant unidirectional coupling from negative emotion to positive emotion and from cognitive performance to both positive and negative emotions. Implications for age differences in emotion regulatory strategies are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)