Effect of Moisture on the High-Temperature Stability of Unidirectionally Solidified Al2O3/YAG Eutectic Composites

The corrosion resistance of a unidirectionally solidified alumina/yttrium aluminum garnet (Al₂O₃/YAG) eutectic mixture was investigated at high temperature. Samples were exposed to high temperature (1200°–1800°C) in different atmospheres, which included argon, argon/water vapor, air, and air/water vapor. The most important microstructural changes occurred at the interface between the YAG and the Al₂O₃. Those changes consisted of localized thermal grooving, especially when the corrosive atmosphere contained water vapor. The samples exhibited significant weight loss at high temperature (1800°C) after 20 h of exposure. The calculated volume gain that was induced by the increased surface relief was low and limited, except when the corrosive atmosphere contained air, which indicated that the presence of air (particularly oxygen) induced a more-active corrosion process. On the other hand, no change in the flexural strength was observed, even after 100 h at 1800°C in a humid atmosphere, because of the cross-linked structure of the composite, which limited propagation of the groove.     

New Sol–Gel Route for the Preparation of Pure α-Alumina at 950°C

An anhydrous alumina (Al₂O₃) sol was prepared from aluminum isopropoxide and an organic solvent, using an acetic acid stabilizer. The complete conversion of the dried sol to α-Al₂O₃ was accomplished at a temperature of 950°C by a single transition via γ-Al₂O₃. Al₂O₃ that was deposited via dip coating resulted in amorphous films, even after annealing at 1100°C, because of the silicon diffusion from the substrate. This phenomenon was avoided using a rapid thermal treatment in a flame after dip coating, which resulted in uniform thin films that are converted to α-Al₂O₃ via heat treatment.     

A channel-erasing 1.8-V-only 32-Mb NOR flash EEPROM with a bitlinedirect sensing scheme

A 1.8-V-only 32-Mb NOR flash EEPROM has been developed based on the 0.25-μm triple-well double-metal CMOS process. A channel-erasing scheme has been implemented to realize a cell size of 0.49 μm² , the smallest yet reported for 0.25-μm CMOS technology. A block decoder circuit with a novel erase-reset sequence has been designed for the channel-erasing operation. A bitline direct sensing scheme and a wordline boosted voltage pooling method have been developed to obtain high-speed reading operation at low voltage. An access time of 90 ns at 1.8 V has been realized     

A mechanical sensorless control system for salient-pole brushlessDC motor with autocalibration of estimated position angles

In this paper, a mechanical sensorless control system is reported for salient-pole brushless DC motor drives. Here, two new methods are proposed for obtaining the position angle, the accuracy of which affects the operation of the switching devices of the inverter that drives the motor. First, the method for estimating the position angle is proposed. Secondly, the correcting method for reducing the errors involved in the estimation of position angle is given. The experimental results show that the estimated position angles are calibrated automatically, and then the proposed sensorless control system can control the speed and the position angles of the motor precisely     

Transmission performance of chirp-controlled signal by usingsemiconductor optical amplifier

We examine the fiber transmission performance of the optical signal whose chirp is controlled by utilizing phase modulation in semiconductor optical amplifier (SOA) with both simulations and experiments. This chirp control technique converts a positive chirp created by electroabsorption (EA) modulator into negative chirp, which reduces the waveform degradation due to the chromatic dispersion in transmission over standard single-mode fiber (SMF). It also provides an optical gain that is sufficient to compensate the insertion loss of the EA modulator. We investigate how the chirp control is affected by the input power to the SOA and the carrier lifetime of the SOA. As the SOA input power increases, the negative chirp becomes large, while the waveform is largely distorted due to gain saturation. However, the waveform distortion at high SOA input powers can be shaped by using a frequency discriminator. The acceleration of the carrier lifetime also reduces the waveform distortion due to gain saturation. We demonstrate that the chirp control technique is effective even for a high bit rate optical signal up to 10 Gb/s, when the carrier lifetime is expedited by optical pumping     

Alternate drop coating for forming dual biointerfaces composed of polyelectrolyte multilayers

Two types of polyelectrolyte multilayers were formed on both sides of a quartz crystal microbalance (QCM) substrate by a novel alternate drop coating process. In this study, poly(diallyldimethylammonium chloride) (PDDA) and poly(sodium 4-styrene sulfonate) (PSS) were used as strong-strong polyelectrolytes. On the other hand, PDDA and poly(acrylic acid) (PAA) were used as strong-weak polyelectrolytes. The novel alternate drop coating process can separately fabricate each polyelectrolyte multilayer on both sides of the substrate. The substrate provides dual biointerfaces, both sides of which comprise different multilayers, by employing a combination of polymers. The formation of the multilayer by alternate drop coating was evaluated in terms of changes in the frequency of the QCM and model protein adsorption for proteins such as bovine serum albumin, and their characteristics were investigated with those of the conventional alternate adsorption process by performing dip coating. There was no significant difference between the surface properties resulting from the two formation conditions. This result strongly supported the fact that the multilayers fabricated by alternate drop coating were similar in quality to those fabricated by conventional dip coating. The resulting dual biointerfaces with polyelectrolyte multilayers provide alternative biofunctions in terms of individual protein loading. In summary, the novel alternate drop coating process for substrates is a good candidate for the preparation of dual biointerfaces in the biomedical field.     

DCB test simulation of stitched CFRP laminates using interlaminar tension test results

A simulation model for the delamination extension of stitched CFRP laminates and 3-D orthogonal interlocked fabric composites (3-D OIFC) has been developed using a 2-D finite element method incorporating interlaminar tension test results to simulate the experimental results of their DCB tests. The mechanical properties of through-the-thickness fiber were determined from the results of interlaminar tension tests in which the specimen included only one through-the-thickness yarn. The fracture phenomena around the through-the-thickness thread, such as debonding from the in-plane layer, slack absorption, fiber bridging, and the pull-out of broken threads from the in-plane layers, are also introduced into the FEM model. The present FEM simulation results were compared to DCB test results for certain stitched laminates and a 3-D OIFC, and the simulation results showed good agreement with the experimental results of DCB tests, including the load–displacement curve and Mode I strain energy release rate (GI). While it was difficult to estimate GI accurately when the DCB test specimen included different types of z-fiber fracture modes, the present model of FEM analysis can simulate the experimental results of DCB tests of stitched laminates and 3-D OIFC. It is suggested that the GI of CFRP with arbitrary z-fiber densities can be predicted by using this FEM analysis model together with interlaminar tension test results.     

Modified tensile adhesion test for evaluation of interfacial toughness of HVOF sprayed coatings

Tensile adhesion test is widely used to evaluate the adhesion strength of coatings sprayed by High Velocity Oxy-Fuel (HVOF) technique. But there are two issues to be improved. Firstly, when the coatings have high adhesion strength, failure occurs in an adhesive layer, and secondary, the edge of a substrate is heavily deformed and rounded due to the high impact energy of sprayed particles. This deformation causes large scatter of adhesion test results. In this paper, a new technique to evaluate the interfacial fracture toughness has been proposed by introducing pre-crack at the interface of a conventional tensile adhesion test specimen. The asymptotic analytical formula was derived for interfacial toughness evaluation. Numerical analysis was also carried out for comparison. The difference between the numerical and the theoretical data was less than 5%. The developed procedure was applied for the SUS316 L steel coatings and the significant effects of the surface roughness and preheating temperature on adhesion strength were reconfirmed quantitatively.     

X-ray diffraction measurements in high magnetic fields and at high temperatures

A system was developed measuring x-ray powder diffraction in high magnetic fields up to 5 T and at temperatures from 283 to 473 K. The stability of the temperature is within 1 K over 6 h. In order to examine the ability of the system, the high-field x-ray diffraction measurements were carried out for Si and a Ni-based ferromagnetic shape-memory alloy. The results show that the x-ray powder diffraction measurements in high magnetic fields and at high temperatures are useful for materials research.     

Cavitation resistance of powder metallurgy aluminum matrix composite with AlN dispersoids

The cavitation erosion resistance of P/M aluminum alloy sintered composite with AlN dispersoids, prepared via the in situ synthesis and the conventional premixing process, was evaluated by using a magnetostrictive-vibration type equipment. In situ synthesized AlN particles were effective for the improvement of the erosion resistance of the composite because of their good bonding with the aluminum matrix. The additive AlN by the premixing process were easily detached from the specimen surface due to the insufficient coherence with the matrix, and caused the poor resistance. The cavitation resistance also depended on the porosity of the sintered composite. The continuously opened pores accelerated the wear phenomena by the cavitation due to the high pressure attack on the primary particle boundaries of sintered materials in the collapse of the bubbles.