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11.
P. B. Lovyrev A. I. Lavrov V. A. Babkin A. N. Aminov S. M. Melekhin Yu. P. Kazantsev P. M. Korol’kov 《Metallurgist》2006,50(3-4):152-157
Specifications require that all the welds in 12-m-diam. decomposers with a capacity of 3600 m3 be subjected to high-temperature tempering before going into service in order to alleviate the stresses from the welding
operation. Specialists at the organizations VNIIPTkhimnefteapparatury and VNIImontazhspetsstroi have proposed out-of-furnace
volumetric (complete) of the assembled decomposer with the use of special heaters. The use of this heating method has shortened
assembly operations while providing the welds with a highquality heat treatment and reducing the stresses overall (including
welding stresses, stresses from assembly of the decomposer, etc.) The technology ensures uniform heating of the housing of
the decomposer and provides for close control over the process. The experience gained in heat-treating decomposers can also
be used in the construction of other containers that come into contact with corrosive media.
__________
Translated from Metallurg, No. 3, pp. 61–64, March, 2006. 相似文献
12.
B. Schönfelder G. Gottstein L. S. Shvindlerman 《Metallurgical and Materials Transactions A》2006,37(6):1757-1771
While the motion of twist boundaries can be readily studied by atomistic simulations with molecular dynamics (MD) under the
action of an elastic driving force, the approach fails for tilt boundaries. This is due to the interaction of the elastic
stress with the grain boundary (GB) structure, which causes plastic strain by GB sliding. A novel concept, the orientation
correlated driving force, is introduced to circumvent this problem. It is shown that this concept can be successfully applied
to the study of the migration of tilt boundaries. The migration behavior of several twist and tilt GBs was investigated. The
transition from low-to high-angle boundaries can be captured, and a structural transition of tilt boundaries was found at
high temperatures, which also affected the migration behavior. The results compare well with experimental results of the motion
high-angle boundaries, but for low-angle boundaries, the agreement is poor.
This article is based on a presentation made in the “Hillert Symposium on Thermodynamics & Kinetics of Migrating Interfaces
in Steels and Other Complex Alloys,” December 2–3, 2004, organized by The Royal Institute of Technology in Stockholm, Sweden. 相似文献
13.
Observer-based estimators (OBE) were used for estimation of state variables and kinetic parameters in an anaerobic digestion (AD) process. A simplified first-order model with time-varying kinetic parameters was used to design an OBE for kinetic parameter estimation. This approach was validated on a laboratory-scale anaerobic reactor equipped with a multiwavelength fluorometer for on-line measurements of COD and VFA concentrations in the reactor effluent. The proposed estimators provide continuous adjustment of kinetic parameters and can be used for predictions of state variables between samples acquisition and during sensor failure. 相似文献
14.
Beneficial effects of wettability altering surfactants in oil-wet fractured reservoirs 总被引:3,自引:0,他引:3
Subhash C. Ayirala Chandra S. Vijapurapu Dandina N. Rao 《Journal of Petroleum Science and Engineering》2006,52(1-4):261
In fractured reservoirs, an effective matrix-fracture mass transfer is required for oil recovery. Surfactants have long been considered for oil recovery enhancement, mainly in terms of their ability to reduce oil–water interfacial tension. These surfactants are effective when the fractured formations are water-wet, where capillary imbibition of surfactants from the fracture into the matrix contributes to oil recovery. However, another beneficial aspect of surfactants, namely their ability to alter wettability, remains to be explored and exploited. Surfactants capable of altering wettability can be especially beneficial in oil-wet fractured formations, where the surfactant in the fracture diffuses into the matrix and alters the wettability, enabling imbibition of even more surfactant into the matrix. This sequential process of initial diffusion followed by imbibition continues well into the matrix yielding significant enhancements in oil recovery.In order to test this hypothesis of sequential diffusion–imbibition phenomenon, Dual-Drop Dual-Crystal (DDDC) contact angle experiments have been conducted using fractured Yates dolomite reservoir fluids, two types of surfactants (nonionic and anionic) and dolomite rock substrates. A new experimental procedure was developed in which crude oil equilibrated with reservoir brine has been exposed to surfactant to simulate the matrix-fracture interactions in fractured reservoirs. This procedure enables the measurements of dynamic contact angles and oil–water interfacial tensions, in addition to providing the visual observations of the dynamic behavior of crude oil trapped in the rock matrix as it encounters the diffusing surfactant from the fractures. Both the measurements and visual observations indicate wettability alterations of the matrix surface from oil-wet to less oil-wet or intermediate wet by the surfactants. Thus this study is of practical importance to oil-wet fractured formations where surfactant-induced wettability alterations can result in significant oil recovery enhancements. In addition, this study has also identified the need to include contact angle term in the dimensionless Bond number formulations for better quantitative interpretation of rock–fluids interactions. 相似文献
15.
The effects of α and β phase interactions on the room-temperature tensile and creep deformation behavior of α + β titanium
alloys with Widmanst?tten microstructures were studied using Ti-6.0 wt pct Mn and Ti-8.1 wt pct V as the model two-phase alloy
systems. This article, Part I, deals with tensile deformation. It was found that when the α phase is present as thin (<10-μm)
plates in the α + β alloys, significant twinning occurs. No significant twinning was observed in single-phase alloys with
the same chemistry and similar grain size. Additionally, the β phase of Ti-8.1 V deforms by stress-induced hexagonal martensite
(α′), while only twinning occurs in the single-phase β alloy with the same chemistry. Twinning in the α phase in association
with stress-induced martensite (SIM) in the β phase was observed for the first time in a two-phase titanium alloy. This behavior
is explained in terms of a number of factors including elastic interaction stresses between the α and β phases, coherency
between the α phase and hexagonal martensite, and β phase stability. 相似文献
16.
S H Lee J H Ko J R Kim Y J Kim J J Lee C W Kim T H Lee 《Water science and technology》2006,53(4-5):115-123
The adverse effect of nitrate on the phosphate release rate in the anaerobic phase was observed and was hardly explainable with conventional EBPR process models. Four possible mechanisms were proposed including substrate competition, reduced fermentation, parallel reaction and sequential reaction. Batch experiments were designed and conducted to identify the dominant mechanism. Results showed that the sequential reaction was the only possible mechanism where only denitrification occurred if any nitrate existed in the anaerobic phase. Then the phosphate release following after the nitrate was completely removed. Nitrate inhibition effect was added into the PHA storage rate to incorporate the sequential reaction in the conventional ASM3 plus EAWAG bio-P module (ASM3 + P). Nitrate inhibition coefficient, K(I,NO,PAO) was found to be as low as 0.05 mg/L. This correlated well with experimental observation where no also meant that the anaerobic compartment of a continuous flow reactor could be seriously affected by the residual nitrate contained in the sludge recycle flow. This phenomenon caused overestimation of the phosphate uptake rate and consequently underestimation of PO4(3-) -P concentration. This problem was resolved by incorporation of a nitrate inhibition term in the ASM3 + P for more accurate simulation of the EBPR process. 相似文献
17.
Stormwater quality simulation models are useful tools for the design and management of sewer systems. Modelling results are highly sensitive to experimental data used for calibration. This sensitivity is examined for three modelling approaches of various complexities (site mean concentration approach, event mean concentration approach and build-up, washoff and transport modelling approach) applied to a typical case study (design of a dry detention tank), accounting for the variability of calibration data and their effect on simulation results. Calibrated models with different calibration data sets were used to simulate 3 years of rainfall with different retention tank specific volumes. Annual pollutant load interception efficiencies were determined. Simulations results revealed (i) that there is no advantage in using the EMC model compared to the SMC model and (ii) that the BWT model resulted in higher design ratios than those given by the SMC/hydraulic approach. For both EMC and BWT models, using an increasing number n of events for calibration leads to narrower confidence intervals for the design ratios. It is crucial for design ratios to account for successive storm events in chronological order and to account for the maximum allowable flow to be transferred to the downstream WWTP. 相似文献
18.
It was found that vanadyl porphyrin complexes synthesized from petroleum metal porphyrin concentrates stimulated epoxidation during the olefin oxygenation process. The yields of obtained oxiranes turned out to be 38–75%, depending on the olefin structure. An epoxidation mechanism that suggests the formation of a protonated dioxygen adduct as an intermediate during oxygenation of olefins in the presence of vanadyl porphyrin complexes was proposed. An analogy is drawn between the epoxide formation reaction upon the catalytic oxygenation of olefins and the Prilezhaev reaction. 相似文献
19.
Improved homogenization of Ni in sintered steels through the use of Cr-containing prealloyed powders
The homogenization of Ni in powder metal (PM) steel compacts is usually difficult even after high-temperature sintering at
1250°C. An earlier study by the authors demonstrated that this problem can be alleviated through the addition of 0.5 wt pct
Cr in the form of stainless steel powders. To further improve the microstructure and mechanical properties of Ni-containing
PM steels and to understand the mechanisms, an attempt was made in this study using the Fe-3Cr-0.5Mo prealloyed powder as
the base material. The results showed that the distribution of the Ni additives was significantly improved. As a result, the
tensile strength of the Fe-3Cr-0.5Mo-4Ni-0.5C compact sintered at 1250°C reached 1323 MPa. The elongation was higher than
1 pct. These sinter-hardened properties, which were attained using a slow furnace cooling rate, were comparable to those of
the sinter-hardened alloys reported in the literature using accelerated cooling and were equivalent to those of the best quenched-and-tempered
alloys registered in the Metal Powder Industries Federation (MPIF) standards. These improvements were attributed to the positive
effect of Cr addition on alloy homogenization due to the reduction of the repelling effect between Ni and C, as was demonstrated
through the thermodynamic analysis using the Thermo-Calc program. 相似文献
20.
This study was undertaken to develop a modified atmosphere package to control microbial growth in ready‐to‐eat (RTE) products stored at ambient temperature. Ethanol and/or limonene associated with modified atmosphere (CO2 : O2 : N2 = 30% : 5% : 65%) was used to inhibit the growth of total air‐borne microorganisms and Escherichia coli in RTE products stored at 25°C. The results indicated that 0.05% ethanol vapour in the headspace was effective to inhibit the growth of air‐borne microorganisms and E. coli at 25°C for 72 h in a model study, and the effectiveness was related to ethanol content. Both 73 ppm limonene and 0.05% ethanol vapour enhanced the bacteriostatic effect of modified atmosphere in RTE sushi roll products, and no off‐flavour was detected using this formulated gas; however, no significant inhibitory effect was observed for RTE cold noodle products. This study concludes that combinations of carbon dioxide, ethanol or limonene vapours are effective to inhibit microbial growth in RTE food at ambient temperature, and the outcome may be due to the hurdle effect. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献