Layer‐by‐Layer All‐Inorganic Quantum‐Dot‐Based LEDs: A Simple Procedure with Robust Performance

A novel all‐inorganic electroluminescent device is demonstrated based on highly luminescent CdTe nanocrystals intercalated within a laminar hydrotalcite‐like structure. The laminar scaffold acts to both support and distribute the CdTe nanocrystals. The device is synthesized using simple wet chemical processes at room temperature in ambient conditions. It has high thermal stability, operating continuously up to 90 °C, and a maximum efficiency at J = 0.12 A cm^?2. The device is targeted at the automotive industry.     

Towards high efficiency video coding: Subjective evaluation of potential coding technologies

This paper describes the details and the results of the subjective quality evaluation performed at EPFL, as a contribution to the effort of the joint collaborative team on video coding (JCT-VC) for the definition of the high efficiency video coding (HEVC) standard. The performance of twenty-seven coding technologies has been evaluated with respect to two H.264/MPEG-4 AVC anchors, for high definition (HD) test material. The test campaign involved a total of 494 naive observers and took place over a period of four weeks. While similar tests have been conducted as part of the standardization process of previous video coding technologies, the test campaign described in this paper is by far the most extensive in the history of video coding standardization. A detailed statistical analysis of the subjective results is provided. The results show high consistency and support an accurate comparison of the performance of the different coding technologies.     

Facile Fabrication of Ordered Crystalline‐Semiconductor Microstructures on Compliant Substrates

Buckling and wrinkling of thin films on a compliant material has proved to be a resource in several applications, such as flexible electronics, thin‐film metrology and fabrication of tunable optical components. A versatile approach for the fabrication of two‐dimensional and linear arrays of buckled structures is demonstrated here using a stiff material, in the form of a nanomembrane, on a compliant substrate. The novelty of the fabrication process is that the substrates are strained by isotropic volume expansion in solvents. This work illustrates in detail the potential of our technology to fabricate ordered arrays of 3D structures on large‐area compliant substrates, with important implications for a large number of fields. Furthermore, this paper discusses the interesting interface chemistry and mechanics leading to controllable and reproducible fabrication of our 3D structures.     

Carrier trapping in thin N2O-grown oxynitride/oxide di-layer for PowerMOSFET devices

A detailed study of the carrier trapping properties shown by the silicon/oxynitride/oxide gate layers in PowerVDMOS technologies is reported. A quantitative analysis of hole and electron trap densities versus the specific N₂O based nitridation process, extracted from Fowler–Nordheim constant current stress kinetics, allows a deep understanding of the role played by those defects in the susceptibility of every nitrided layer.     

Cross-layer network formation for energy-efficient IEEE 802.15.4/ZigBee Wireless Sensor Networks

In IEEE 802.15.4/ZigBee Wireless Sensor Networks (WSNs) a specific node (called the PAN coordinator or sink) controls the whole network. When the network operates in a multi-hop fashion, the position of the PAN coordinator has a significant impact on the performance: it strongly affects network energy consumption for both topology formation and data routing. The development of efficient self-managing, self-configuring and self-regulating protocols for the election of the node that coordinates and manages the IEEE 802.15.4/ZigBee WSN is still an open research issue. In this paper we present a cross-layer approach to address the problem of PAN coordinator election on topologies formed in accordance with the IEEE 802.15.4. Our solution combines the network formation procedure defined at the MAC layer by the IEEE 802.15.4 standard with a topology reconfiguration algorithm operating at the network layer. We propose a standard-compliant procedure (named PAN coordinator ELection – PANEL) to self-configure a IEEE 802.15.4/ZigBee WSN by electing, in a distributed way, a suitable PAN coordinator. A protocol implementing this solution in IEEE 802.15.4 is also provided. Performance results show that our cross-layer approach minimizes the average number of hops between the nodes of the network and the PAN coordinator allowing to reduce the data transfer delay and determining significant energy savings compared with the performance of the IEEE 802.15.4 standard.     

Upconversion in Er-doped Gd2O3 nanocrystals prepared by propellant synthesis and flame spray pyrolysis

In this study, monoclinic luminescent Gd₂O₃ nanocrystals doped with different concentrations of Er³⁺ (0.1, 1, and 10 mol%) were produced by propellant synthesis and flame spray pyrolysis (FSP). A comparison of their optical and morphological properties is reported. Following 980 nm excitation, an increase of the emission intensity from the ²H_11/2, ⁴S_3/2 → ⁴I_15/2 and ⁴F_9/2 → ⁴I_15/2 transitions was observed with increasing Er³⁺ concentration in the Gd₂O₃ nanocrystalline samples prepared via both techniques. However, the overall upconversion emission intensity was greater for the samples obtained by FSP. Furthermore, as the Er³⁺ concentration was increased, the intensity of the red (⁴F_9/2 → ⁴I_15/2) emission was observed to increase more rapidly in comparison to the green (²H_11/2, ⁴S_3/2 → ⁴I_15/2) emission resulting in an overall enhancement of the red component in the upconversion emission. Although both synthetic routes yield average crystallite sizes in the nanoscale, the TEM and SEM images confirm a more homogeneous morphology and lower particle aggregation for the nanocrystals produced by FSP.     

Evaluation of a child passenger safety class in increasing parental knowledge

Background

Child passenger restraint systems have been found to greatly reduce the risk of injury and death among child passengers. However, nearly half of the children who died in 2009 as a result of motor vehicle crashes were completely unrestrained. Our global hypothesis is that parents and other caregivers failed to restrain children due to a lack of child passenger seat education and practice. In this report, we postulate that a car seat class will improve the basic understanding of child passenger safety. The objective of the study was to evaluate the effectiveness of a car seat class in increasing parental knowledge about child passenger safety.

Methods

Car seat classes were held at a Level 1 pediatric trauma center every other Tuesday for ten months. The curriculum consisted of: child passenger safety laws discussion, a 21-min video on the use of child safety seats followed by a 15-min discussion about the video, 15 min of discussing the different types of car seats, and hands-on training on how to properly install and use child restraints. Free car seats were provided to eligible parents. The pre-test was administered at the beginning of class and the post-test at the end of the class. McNemar's test and a paired t-test were used to compare pre- and post-test scores. Test scores were also stratified by language spoken.

Results

Forty-four classes were held and a total of 491 parents/caregivers attended the classes. An increase in knowledge was found for all survey questions. Mean knowledge score for the post-test was 3.10 points higher compared to the mean knowledge score from the pre-test. Mean difference in knowledge scores for English-speaking participants were higher than Spanish-speaking participants.

Conclusion

Lack of knowledge and low risk perception have frequently been cited as barriers for the use of child passenger restraints. Our intervention attempted to eliminate these barriers. We found that this intervention was effective at increasing parental knowledge about child passenger safety. The results of this study may be used to design and implement future interventions in multicultural settings.     

PCBs and selected organochlorine compounds in Italian mountain air: the influence of altitude and forest ecosystem type

Passive air samplers (polyurethane foam disks) were deployed on an altitudinal transect in the rural Italian Alps to investigate the potential influence of forest cover on air concentrations. Samplers were exposed overtwo periods, each of several weeks, either in clearings or in forests. In the first period, there was high leaf coverage (high leaf area index, LAI); in the second, the LAI was low after the autumnal leaf fall. PCBs sequestered in the PUF generally declined with altitude, for example, in the clearings PCBs-28, 52, 90/101, 118, and 138, all showed statistically significant declines (p < 0.05). The mass of HCB sequestered increased with altitude, evidence of cold condensation. Ratios of the forest:clearing concentrations were calculated; this ratio expresses the filtering ability of forests to deplete air concentrations compared to the adjacent clearings. During the high LAI sampling period, these depletion factors ranged between 0.93 and 0.54 and were inversely correlated with temperature-corrected log K0A. This relationship was notobserved during the low LAI sampling period. The depletion factors were normalized using the LAI to give a density independent depletion factor (DIDF). The slopes of the correlations with K0A were comparable for broadleaf or coniferous forests at different altitudes, suggesting that leaf surfaces determine the exchanges with air. Broadleaf forests at 1000 and 1400 m showed similar behavior, while a conifer forest at 1800 m gave depletion factors which were higher by about a factor of 2. It is suggested that DIDF can be used in regional environmental fate models to estimate the contribution of forests to contaminant fate.     

Effects of nutrient supplementation on fermentation kinetics, H2S evolution, and aroma profile in Verdicchio DOC wine production

Different yeast nutrient additions were studied for the 2008 and 2009 vintages of Verdicchio grape juice fermentation. Addition of yeast derivatives at the beginning of fermentation and/or different amounts of diammonium phosphate at various times within the first half of fermentation were examined, with initial yeast assimilable nitrogen concentrations set at 200 and 250 mg l^?1. Supplementation with glutathione in combination with this nitrogen addition was also evaluated. Fermentation rates were monitored throughout these fermentations carried out under different nutrient conditions. H₂S production during fermentation and synthesis of volatile compounds in the finished wines were quantified; the wines also underwent sensory evaluation. The fermentation kinetics were almost exclusively influenced by the inorganic nitrogen supplementation with diammonium phosphate. H₂S evolution was more affected by assimilable nitrogen than glutathione. Diammonium phosphate significantly reduced H₂S production, with a further reduction in the presence of yeast derivative. This nitrogen supplementation yielded higher concentrations of acetate esters, and in particular of isoamyl acetate (fruity aromas), which positively influences the analytical and aroma profile of wines and results in a general reduction in 2-phenylethanol production (floral aromas). Overall results (two harvesting times and vintages) indicate that the management with diammonium phosphate and yeast derivative supplementation improves the kinetics of fermentation and provides a good tool to reduce H₂S formation and increase the analytical and sensory quality of Verdicchio wine.