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A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron 总被引:1,自引:0,他引:1
A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the
zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction.
Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated
as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the
reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated
by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI,
both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the
combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when
sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher
than that with ZVI only. 相似文献
44.
宋世光 《哈尔滨工业大学学报》1986,(2)
本文在增量调制的原理基础上,对“△”脉宽调制的原理及实质进行了实验分析与研究。从理论上论证了“△”调制方案的合理性。通过实验对“△”调制所提供的满足变频调速要求的控制特性及设计思想的可行性进行了验证。着重对参数选择进行了实验分析,指出了参数选择的观点及其依据。按本文的观点选择参数,在工程应用中是切实可行的。 相似文献
45.
This letter presents some further results on the local stability in equilibrium for Internet congestion control algorithm proposed by Low et al., (IEEE/ACM Transactions on Networking, 1999). The propagation delay d(t) is assumed to be time-varying and have maximum and minimum delay bounds (i.e., d/sub m//spl les/d(t)/spl les/d/sub M/), which is more general than the assumption (0相似文献
46.
Effects of surfactant/silica and silica/cerium ratios on the characteristics of mesoporous Ce-MCM-41
Se Ho Park Bo Yune Song Tai Gyu Lee 《Journal of Industrial and Engineering Chemistry》2008,14(2):261-264
Using the surfactant CTMABr (cetyltrimethyl ammonium bromide) and cerium(IV) sulfate, mesoporous Ce-MCM-41 molecular sieves were produced under a hydrothermal condition with various surfactant/silica (surfactant/Si) and silica/cerium (Si/Ce) ratios. Changes to the structural traits caused by changing the molar ratios of both surfactant/Si and Si/Ce were investigated. XRD (X-ray diffraction), FT-IR (fourier transform infrared spectroscopy), and SEM (scanning electro microscopy) were used for the characterization of prepared mesoporous samples. Among the tested molar ratios, surfactant/Si ratio of 0.5 and 0.2 showed highest values of d1 0 0 and intensity, respectively, for the Si-MCM-41. XRD analysis also identified a quintessential hexagonal structure of Ce-MCM-41 for the Si/Ce molar ratio higher than 40 (maintaining the surfactant/Si ratio at 0.2). When cerium content was increased to have the Si/Ce molar ratio of 20, the hexagonal structure of Ce-MCM-41 was collapsed due to the structural stress of substituted cerium. FT-IR results confirmed calcination of Ce-MCM-41 and the incorporation of Ce4+ ions of cerium sulfate into the silica surface with proper removal of the surfactant. Rod-like shape with rounded edges of the prepared Ce-MCM-41 samples was identified by SEM. These results suggest surfactant/Si ratio of 0.2 and Si/Ce ratio of 40 for the production of Ce-MCM-41 with the highest level of crystallinity. 相似文献
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本文介绍了HSDPA的发展背景,针对HSDPA的主要技术特点,依据市场发展规划、用户需求等方面对HSDPA部署进行探讨,并对HSDPA的覆盖与容量方面进行规划分析. 相似文献
50.
今年上半年我国石油工业基本保持平稳、健康的发展格局:油气产量和消费需求均持续增长,油气开采业大幅盈利,原油加工业仍然亏损,投资大幅度增长,原油进口依存度加大。下半年需要采取的应对措施是:进一步完善成品油价格形成机制;规范和引导上海石油交易所健康运行;加强天然气管理,作好需求预测;实施石油替代激励政策。预计下半年国际油价继续走高的可能性较大;我国全年石油表观消费可能会突破3亿吨,进口依存度继续在40%以上。 相似文献