Patterning of soft polydimethylsiloxane elastomers using plasma etching

Soft polydimethylsiloxane (PDMS) elastomers spin coated on silicon wafers are patterned using plasma etching. The elastomers are formed by mixing vinyl‐terminated PDMS (prepolymer) and crosslinker containing hydride sites. The elastomers are made softer by adding either excess prepolymer, excess crosslinker, or swelling agent. The different elastomers were etched using reactive ion etching, an old and well established processing technology in the microelectronic and MEMS industry. The etch rate and profiles of the etched surfaces were dependent on the process pressure. The dependence was different for the different elastomers. It was found that at low pressure, the etch rate was dependent on the shear modulus. At high pressures, the etch rate was dependent on the chemical composition of the elastomer. The results for the swollen elastomers were different from those for the nonswollen elastomers. The etch rate was lower and the profiles of the etched cavities were different. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Grass-based ruminant production methods and human bioconversion of vaccenic acid with estimations of maximal dietary intake of conjugated linoleic acids

Reports on human conjugated linoleic acids (CLAs) intake vary, and usually don't consider food production methods and vaccenic acid (VA)-induced CLA biosynthesis in humans. The aim of this review was to estimate the achievable CLA intake considering both food sources produced by feeding patterns natural to animals and human VA bioconversion. Exogenous CLA supply from milk, cheese, lamb, and beef from grass-based ruminant production methods, was calculated to be about double that of estimates based on modern production methods (respectively, from the four sources: 1.25, 1.50, 1.44, and 0.69% of total fatty acids). Using available human consumption data this resulted in an estimated achievable CLA intake (including VA bioconversion) of between 711 and 1107 mg d^?1. Intake of products from natural grass-fed ruminants leads to a several-fold higher CLA food content and, along with consideration of endogenously formed CLA from VA, results in a substantially higher CLA availability than previously estimated.     

Best-Fit Models to Estimate Modified Proctor Properties of Compacted Soil

Regression models were developed to estimate the optimum moisture content and maximum dry density of clayey and fine-grained soils using physical and index properties from 30 soil samples collected in Central Italy and 41 soils described in the literature. The liquid limit of the soils analyzed ranged between 18 and 82%, the plasticity index between 1 and 51%, and specific gravity between 2.47 and 3.09. The most significant regression variables were the specific gravity and the Atterberg limits. The developed models are accurate and can be used as a simple tool to approximate the maximum dry density and optimum water content of clayey and fine-grained soils.     

Deflector Ski Jump Hydraulics

Ski jumps are a standard element of dam spillways for an efficient energy dissipation if takeoff velocities are large, and stilling basins cannot be applied. This laboratory study investigates the hydraulic performance of a triangular-shaped, rather than the conventional circular-shaped, bucket placed at the takeoff of ski jumps. The following items were addressed: (1) pressure head maximum and pressure distribution along the triangular-shaped bucket; (2) takeoff characteristics as a function of the bucket deflector angle and the relative bucket height including the lower and the upper jet trajectories; (3) jet impact characteristics in a prismatic tailwater channel including the shock wave formation and the height of recirculation depth below the jet cavity; (4) energy dissipation across the ski jump, from the approach flow channel to downstream of jet impact; and (5) choking flow conditions of the flip bucket. A significant effect of the approach flow Froude number, the relative bucket height, and the deflector angle is found. A comparison with previous results for the circular-shaped bucket geometry indicates a favorable behavior of the novel bucket design.     

High-resolution capillary tube NMR. A miniaturized 5-microL high-sensitivity TXI probe for mass-limited samples,off-line LC NMR,and HT NMR

A new triple-resonance (TXI) (1H, 13C, 15N) high-resolution nuclear magnetic resonance (NMR) capillary probe with 2.5-microL NMR-active sample volume (V(obs)) was built and tested for applications with mass- and volume-limited samples and for coupling of microbore liquid chromatography to NMR. This is the first microliter probe with optimized coil geometry for use with individual capillary tubes with an outer diameter of 1 mm. The 90 degree pulse lengths of the 1-mm microliter probe were below 2 micros for proton, below 8 micros for carbon, and below 20 micros for nitrogen, and a spectral line width at signal half-height below 1 Hz was obtained. Compared to a conventional 5-mm probe, the new 600-MHz 1-mm TXI microliter probe with z-gradient shows an increase in mass sensitivity by a factor of 5, corresponding to a 25-fold reduction in measuring time. The consumption of costly deuterated solvent is reduced by at least 2 orders of magnitude. The 1-mm TXI microliter probe with z-gradient allows the measurement of one-dimensional 1H NMR and two-dimensional heteronuclear NMR spectra with a few nanomoles (micrograms) of compound with high sensitivity, speed, and quality. This is a breakthrough for discrete sample NMR spectroscopy with paramount importance for structure elucidation in natural compound chemistry and metabolic research. It offers also advantages for linking chromatographic methods to NMR in a nindustrial environment. Capillary tube NMR may find new applications in areas where high sample throughput is essential, e.g., in the quality control of large sample arrays from parallel chemistry, screening, and compound depositories. It has the potential to increase the sample throughput by 1 order of magnitude or more if new hardware for fast sample handling and exchange becomes available.     

Hyperbolic representation of light propagation in a multilayer medium

By analogy with the representation of the polarization of light on the Poincaré sphere, we describe the propagation and the reflection/transmission of light in a multilayer on a hyperbolic surface. We show that the propagation of light corresponds to a classical rotation on this surface and that its reflection/transmission corresponds to a hyperbolic rotation.     

Methods based on discrete optimization for finding road network rehabilitation strategies

We study a dynamic optimization problem arising in the (long-term) planning of road rehabilitation activities. In this area one seeks a pavement resurfacing plan for a road network under budget constraints. Our main approach is to model this as an integer programming problem with underlying dynamic programming structure. We investigate properties of this model and propose a solution method based on Lagrangian relaxation where one gets subproblems that are shortest path problems. Some computational experiences based on realistic data are reported.     

Quantification of Fatty Acids and their Regioisomeric Distribution in Triacylglycerols from Porcine and Bovine Sources Using 13C NMR Spectroscopy

The uptake of specific fatty acids in humans is dependent on their position on the glycerol backbone. There is a great interest in methods that can access this information fast and accurately. By way of high-resolution NMR, we have analyzed TAG extracted from pig and beef tissues and obtained quantitative data for the composition and regioisomeric distribution of all major unsaturated fatty acids usually found in these source materials, using a combination of manual integration and deconvolution of ¹³C NMR spectra. In addition, we have developed a method for determining composition and regioisomeric distribution of the two main saturated fatty acids found in pork (16:0, 18:0). The results are discussed in relation to species-specific genetic characteristics of fatty acid and TAG biosynthesis. The developed method could support decisions related to breeding for desired fatty acid profiles, and stimulate further methodology developments using high field NMR.