Phase separation of a hafnium alkoxide-modified polysilazane upon polymer-to-ceramic transformation—A case study

The polymer-to-ceramic transformation of a hafnium alkoxide-modified polysilazane was investigated via thermogravimetric analysis coupled with in situ mass spectrometry (TG/MS), nuclear magnetic resonance (MAS NMR) and transmission electron microscopy (TEM). The results indicate that the structural evolution of the polysilazane upon ceramization is strongly affected by the modification with hafnium alkoxide. Thus, the content of carbon in the ceramic backbone was relatively low, whereas a large amount of SiN₄ sites and a segregated carbon phase was present in the sample. Furthermore, this study revealed the formation of a SiHfCNO amorphous single phase ceramic via pyrolysis of the polymer at 700 °C, whereas at higher pyrolysis temperatures precipitation of hafnia was observed, leading to an amorphous hafnia/silicon carbonitride ceramic nanocomposite. The precipitation of hafnia was shown to not rely on decomposition processes, but to be a result of rearrangement reactions occurring within the ceramic material.     

Effects of growth and breed on the fatty acid composition of the muscle lipids in cattle

 The adipose tissue development in muscle and the fatty acid composition of intramuscular fat of 200 bulls from three different breeds during growth was investigated. There were significant differences in quantitative and qualitative fat deposition which were genetically caused. The muscle of Galloway and White-blue Belgian bulls contained a high n–3 fatty acid content which is positive for human nutrition. During growth an increased deposition of saturated fatty acids into the adipocytes of muscle was observed.     

Satellite-based snow identification and its impact on monitoring photovoltaic systems

Earth observation allows the separation of snow cover and cloudiness using multispectral measurements. Several satellite-based snow monitoring services are available, ranging from regional to world-wide scales. Using these data enables photovoltaic (PV) plant management to differentiate between failures due to snow coverage on a PV system and other error sources. Additionally, yield estimates for solar siting are improved. This paper presents a validation study from January to April 2006 comparing satellite-based datasets with ground measurements from German and Swiss meteorological stations. A false alarm rate, an error due to irradiance underestimation, the availability of daily data, and the classification accuracy are introduced as quality metrics. Compared to Switzerland, generally a higher accuracy is found in all datasets for Southern Germany. The most significant difference among the datasets is found in the error pattern shifting from too much snow (which results in an error due to underestimation of irradiance) to too little snow detection, causing a false alarm in PV monitoring.Overall, the data records of the Land Surface Analysis Satellite Application Facility (LSA SAF), the German Aerospace Center (DLR) and the Interactive Multisensor Snow and Ice Mapping System (IMS) are found to be most suitable for solar energy purposes. The IMS dataset has a low false alarm rate (4%) and a good data availability (100%) making it a good choice for power plant monitoring, but the error due to underestimation relevant in site auditing is large with 59%. If a cumulative snow cover algorithm is applied to achieve information every day as needed both for power plant monitoring and site auditing, both the DLR and the LSA SAF datasets are comparable with classification accuracies of 70%, false alarm rates of 37% and 34%, respectively, and errors due to irradiance underestimation in 26% and 27% of all coincidences.     

The social bookmark and publication management system bibsonomy

Social resource sharing systems are central elements of the Web 2.0 and use the same kind of lightweight knowledge representation, called folksonomy. Their large user communities and ever-growing networks of user-generated content have made them an attractive object of investigation for researchers from different disciplines like Social Network Analysis, Data Mining, Information Retrieval or Knowledge Discovery. In this paper, we summarize and extend our work on different aspects of this branch of Web 2.0 research, demonstrated and evaluated within our own social bookmark and publication sharing system BibSonomy, which is currently among the three most popular systems of its kind. We structure this presentation along the different interaction phases of a user with our system, coupling the relevant research questions of each phase with the corresponding implementation issues. This approach reveals in a systematic fashion important aspects and results of the broad bandwidth of folksonomy research like capturing of emergent semantics, spam detection, ranking algorithms, analogies to search engine log data, personalized tag recommendations and information extraction techniques. We conclude that when integrating a real-life application like BibSonomy into research, certain constraints have to be considered; but in general, the tight interplay between our scientific work and the running system has made BibSonomy a valuable platform for demonstrating and evaluating Web 2.0 research.     

Characteristics of carcass composition,fat metabolism and meat quality of genetically different pigs

The aim of the study was to quantify the differences in meat and fat quality and lipid metabolism of pigs with either high or medium capacity for lipid accretion. A total of 58 castrated males of the breeds German Saddle Back (SB) and German Landrace (DL) were included in the experiment. Animals were housed individually and fed twice daily semi ad libitum. Saddle Back pigs indicated a lower lean meat content (41.4% vs 52.6%) and a higher fat percentage (40.9% vs 28.2%) in comparison to DL as a result of high lipid accumulation. The larger fat content of SB was related to an increased intramuscular fat concentration of longissimus muscle. A significant correlation between intramuscular fat content and fatty acid composition was estimated in both breeds. The relative concentration of saturated fatty acids was significantly increased in SB pigs. The percentage of polyunsaturated fatty acids (8.3%) in SB muscle fat was significantly lower than in DL muscle fat (10.7%). The de novo biosynthesis of fatty acids resulted in mostly saturated fatty acids and oleic acid. The higher activities of lipogenetic enzymes in backfat of SB proved a higher lipogenetic capacity. There were no significant differences in meat quality traits of longissimus muscle between the two breeds.     

Application and modelling of hybrid stereolithography injection mould tooling

The use of stereolithography (SL) to make injection moulding tools has been shown previously to be an efficient way of producing rapid tools for simple geometries, aiming at small lot sizes with an acceptable degree of accuracy. This paper highlights the unexplored potential of using SL inserts in hybrid tools using practical experiments and FEA mould filling models. The practical experiments reveal problems incurred by uneven flow as a result of differential thermal conductivity between dissimilar mould materials in a hybrid tool. The FEA flow models confirm that this uneven flow would be anticipated when using finite element analysis (FEA) software. A further FEA stress analysis predicts that catastrophic mould failure will be expected under some conditions and these reflect the results found in the practical experiments. The use of a homogeneous SL tool eliminates the issues caused by uneven mould filling but results in thermal distortion of the female mould. Ultimately, a SL tool backfilled with low melt point alloy provides a solution that eliminates the problems of uneven filling and thermal distortion.     

Negative Priming Effects in Children Engaged in Nonspatial Tasks: Evidence for Early Development of an Intact Inhibitory Mechanism.

Three experiments are reported that examined conceptual negative priming effects in children 5 to 12 years of age. Experiment 1 used a negative priming variant of a flanker task requiring the naming of a central color blob flanked by irrelevant distractors. Experiment 2 used a negative priming variant of the Stroop color-word task. Experiment 3 used a same-different matching task with novel 3-D shapes. Results revealed significant and equivalent magnitudes of negative priming across the tested age groups for all 3 tasks. It is concluded that the inhibitory mechanism underlying conceptual (i.e., identity or semantic) negative priming in visual selective attention tasks is intact in young children. Because the findings and conclusions diverge from the developmental literature on negative priming, the authors attempt to reconcile the contradictions by pinning down the reasons for the discrepancies. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Surface condition monitoring of unalloyed steel sheet by measuring ferromagnetic properties and using multi-parameter data analysis

Initial investigations into coated steel sheets were conductted to verify whether sample- and batch-independent classification of surface condition can be achieved with multi-inductive data acquisition and multivariate data analysis without using a priori information. Using an ‘integrated sensor’ - a multi-inductive sensor - it is possible to obtain parameters of eddy currents, hysteresis and noise voltage with PC control. These parameters are the input values of multivariate data analysis.