环境工程地球物理技术在土木工程中的应用

环境工程地球物理技术含重力勘测、磁法勘测、电法勘测、电磁法勘测、浅层地震勘测、面波勘测、探地雷达勘测等，GPS（卫星定位系统）、GIS（地理信息系统）和RS（遥感遥测系统）亦可视为广义的地球物理技术，这些技术建立在位场、波动场、电磁感应及信息传播理论的基础上，其仪器软硬件随着计算机和微电子技术的发展而不断完善，已成功地应用在环境岩土工程、灾害地质调查与监测、工程地质与水文地质勘测、矿山隧道及洞穴调查、海洋与冰雪层调查等各类土木工程的勘察等方面。     

Plasmonic dimer antennas for surface enhanced Raman scattering

Electron beam induced deposition (EBID) has recently been developed into a method to directly write optically active three-dimensional nanostructures. For this purpose a metal-organic precursor gas (here dimethyl-gold(III)-acetylacetonate) is introduced into the vacuum chamber of a scanning electron microscope where it is cracked by the focused electron beam. Upon cracking the aforementioned precursor gas, 3D deposits are realized, consisting of gold nanocrystals embedded in a carbonaceous matrix. The carbon content in the deposits hinders direct plasmonic applications. However, it is possible to activate the deposited nanostructures for plasmonics by coating the EBID structures with a continuous silver layer of a few nanometers thickness. Within this silver layer collective motions of the free electron gas can be excited. In this way, EBID structures with their intriguing precision at the nanoscale have been arranged in arrays of free-standing dimer antenna structures with nanometer sized gaps between the antennas that face each other with an angle of 90°. These dimer antenna ensembles can constitute a reproducibly manufacturable substrate for exploiting the surface enhanced Raman effect (SERS). The achieved SERS enhancement factors are of the order of 10? for the incident laser light polarized along the dimer axes. To prove the signal enhancement in a Raman experiment we used the dye methyl violet as a robust test molecule. In future applications the thickness of such a silver layer on the dimer antennas can easily be varied for tuning the plasmonic resonances of the SERS substrate to match the resonance structure of the analytes to be detected.     

Investigations of silica scaling on reverse osmosis membranes

In reverse osmosis systems with high silica water severe and irreversible membrane scaling can be observed. But suitable test methods to find an appropriate antiscalant agent and the optimal dosage are missing. Usually only the silicate concentration in the feed water is regarded.In this paper the results of laboratory experiments about the influence of Ca²⁺- and Mg²⁺-ions on the behaviour of supersaturated solutions of silica in different test waters are discussed first. After that the new developed membrane-based test method to determine the effectiveness of antiscalants is presented.The applied different methods of analysis enabled the differentiation of three groups of silicates: ‘monomeric’, ‘polymeric’ and ‘filterable’.With the test method the strong impact of silicate scaling was proven, even if only small amounts of scale had been formed. It could be shown, that the ‘polymeric silica’ is mainly responsible for the membrane scaling. The kinetic of the formation of ‘polymeric silica’ is strongly influenced by the cations and the pH-value. It could be demonstrated that the use of a suitable antiscalant makes it possible to operate the plant at significantly higher recovery rates.     

Optimizing continuous annealing of interstitial-free steels for improving deep drawability

The crystallographic textures and the resulting plastic anisotropy of five interstitial-free (IF) steels with different carbon equivalents and Nb and Ti microalloying content have been investigated. The steels were industrially hot rolled, cold rolled, annealed, and finally hot-dip galvanized. An alternative heat treatment of the cold rolled samples was conducted in laboratory scale using parameters close to those in industry-scale continuous annealing lines. The anisotropy parameters were both measured and predicted on the basis of the measured texture data. The calculated values were corrected by using functions that were fitted to the experimental data. It was found that for a given hot and cold rolling state even minor changes in the annealing conditions can improve the anisotropy parameter by up to 13 pct. Increase in recrystallization texture and improvement of the resulting anisotropy parameters are discussed in terms of partial transformation of ferrite to austenite in the intercritical regime.     

Gas transport through ceramic membranes under super-critical conditions

In order to select and to apply a porous membrane under supercritical conditions, it is necessary to understand the transport mechanism affecting the permeation behaviour.This paper describes the investigation of gas transport through micro porous ceramic membranes consisting of several layers. The separation layer is made from TiO² with a nominal pore size diameter of 0.9 nm. Single gas permeation of helium, nitrogen, argon, methane, and carbon dioxide was measured in the temperature range of 293-443 K and in the pressure range of 1-10 MPa.Observation of the permeability of these membranes revealed that the transport of non?adsorbing gases under these conditions is governed by Knudsen diffusion and viscous flow.     

A Note on the Energy Norm for a Singularly Perturbed Model Problem

This paper considers a singularly perturbed reaction diffusion problem. It is investigated whether adaptive approaches are successful to design robust solution procedures. A key ingredient is the a posteriori error estimator. Since robust and mathematically analysed error estimation is possible in the energy norm, the focus is on this choice of norm and its implications. The numerical performance for several model problems confirms that the proposed adaptive algorithm (in conjunction with an energy norm error estimator) produces optimal results. Hence the energy norm is suitable for the purpose considered here. The investigations also provide valuable justification for forthcoming research. Received October 25, 2001; revised July 12, 2002 Published online: October 24, 2002     

Construction experiences with SSC collider dipole magnets atFermilab

Full length and short model SSC (Superconducting Super Collider) 50 mm bore dipoles are being built and tested at Fermilab. The mechanical design of these magnets has been determined from experience with the construction of previous superconducting magnets. Construction experience includes coil fabrication, ground insulation, instrumentation, collaring, and yoke assembly. Fabrication techniques are explained, and construction problems and their solutions are reviewed. The relationship of short to long model construction is discussed     

miR-16-5p Is a Stably-Expressed Housekeeping MicroRNA in Breast Cancer Tissues from Primary Tumors and from Metastatic Sites

For quantitative microRNA analyses in formalin-fixed paraffin-embedded (FFPE) tissue, expression levels have to be normalized to endogenous controls. To investigate the most stably-expressed microRNAs in breast cancer and its surrounding tissue, we used tumor samples from primary tumors and from metastatic sites. MiRNA profiling using TaqMan^® Array Human MicroRNA Cards, enabling quantification of 754 unique human miRNAs, was performed in FFPE specimens from 58 patients with metastatic breast cancer. Forty-two (72%) samples were collected from primary tumors and 16 (28%) from metastases. In a cross-platform analysis of a validation cohort of 32 FFPE samples from patients with early breast cancer genome-wide microRNA expression analysis using SurePrintG3 miRNA (8 × 60 K)^® microarrays from Agilent^® was performed. Eleven microRNAs could be detected in all samples analyzed. Based on NormFinder and geNorm stability values and the high correlation (rho ≥ 0.8) with the median of all measured microRNAs, miR-16-5p, miR-29a-3p, miR-126-3p, and miR-222-3p are suitable single gene housekeeper candidates. In the cross-platform validation, 29 human microRNAs were strongly expressed (mean log2-intensity > 10) and 21 of these microRNAs including miR-16-5p and miR-29a-3p were also stably expressed (CV < 5%). Thus, miR-16-5p and miR-29a-3p are both strong housekeeper candidates. Their Normfinder stability values calculated across the primary tumor and metastases subgroup indicate that miR-29a-3p can be considered as the strongest housekeeper in a cohort with mainly samples from primary tumors, whereas miR-16-5p might perform better in a metastatic sample enriched cohort.