Chemical composition,antioxidant and antimicrobial activities of essential oil obtained from Ferula assa-foetida oleo-gum-resin: Effect of collection time

The properties of essential oils obtained from Ferula assa-foetida oleo-gum-resins (OGRs) collectioned in three collections times in 15 June (OGR1), 30 June (OGR2) and 15 July (OGR3) 2011 was investigated. Essential oil from OGR1 was constituted high levels of (E)-1-propenyl sec-butyl disulfide (23.9%) and 10-epi-γ-eudesmol (15.1%). Essential oil from OGR2 was constituted high levels of (Z)-1-propenyl sec-butyl disulfide (27.7%) and (E)-1-propenyl sec-butyl disulfide (20.3%). Essential oil from OGR3 was constituted high levels of β-pinene (47.1%) and α-pinene (21.3%). Inhibitory concentration (IC50) for radical scavenging were 0.012–0.035, 0.025–0.047 and 0.035–0.066 mg/ml of essential oil obtained from OGR1, OGR2 and OGR3, respectively. Minimal inhibitory concentration (MIC) for Gram-positive and Gram-negative bacteria and fungi grpwth were 0.028–0.111, 0.027–0.107 and 0.018–0.058 mg/ml of essential oil obtained from OGR1, OGR2 and OGR3, respectively. Essential oils obtained from different OGRs have different composition and biological activity thus have different applications in food and health industry.     

Nigella sativa L. improves lipid profile and prevents atherosclerosis: Evidence from an experimental study on hypercholesterolemic rabbits

The effects of Nigella sativa (NS) on lipid profile, C-reactive protein, oxidized LDL, antioxidant capacity, Apo A and Apo B and fatty streak formation in hypercholesterolemic male rabbits were examined. Fifteen rabbits were distributed into three groups of five each [normal diet, hypercholesterolemic diet (1% cholesterol) and hypercholesterolemic diet (1% cholesterol) supplemented with 5% NS]. They received rabbit laboratory chow diet for a period of 8 weeks. At the start and end of the study, fasting blood was taken from all animals. NS significantly decreased fatty streak formation as well as total cholesterol (TC) and low-density lipoprotein (LDL) in hypercholesterolemic male rabbits. NS showed positive effects on other factors (triacylglycerol, high-density lipoprotein, C-reactive protein, oxidized LDL, antioxidant capacity, Apo A and Apo B), but these were insignificant. Based on favorable efficiency of NS on TC and LDL reduction and its anti-atherogenic cardioprotective properties, it is suggested using this plant with fat-rich diets simultaneously may reduce their adverse health effects.     

Considering the game-theoretic approach and ultra combinative costs on scheduling

In this paper, we consider the different algorithmic and game-theoretic features of scheduling. We apply concepts of cooperative game theory to study states in which a set of brokers encounters ultra combinative costs. These states appear in a diversity of scheduling factors, such as facility location and network design. Although cooperation is improbable when costs are ultra combinative, the motivation to avoid cooperation may lead to an increase in negative externalities. We study the smallest core value of a cooperative game as a means of persuading cooperation. We prove that calculating the smallest core value of ultra combinative cost cooperative games is strongly NP-hard, and we design an approximation structure for this problem that in the margin produces a (3?+?σ)-estimation algorithm. We also apply our approximation structure to get better results for two cases of ultra combinative cost cooperative games that derive from scheduling and matroid optimization.     

DIAL–phoswich hybrid system for remote sensing of radioactive plumes in order to evaluate external dose rate

Radioactive pollutants which are released into the atmosphere are known to present a hazard to human health; therefore they must be identified and well protected. Here, an improved remote sensing system is investigated for monitoring radioactive plumes released into the atmosphere from nuclear sites. It is based on the combination of DIAL technique with a phoswich detector array. The DIAL, using a tunable UV/Vis laser, measures the concentration of the radionuclide and the plume distance, whereas the phoswich detects characteristic hard X/γ ray emissions. Here, we have shown the ability of a hybrid system for the prompt identification and quantification of the effluents containing the uranium radionuclide, using the parameters of uranium such as absorption cross-section, absorption spectrum and density.     

Development of an on-line optical method for assessment of the bubble size and morphology in aerated food products

The quality of whipped products of the food industry is closely linked to the characteristics of the dispersed gas phase, such as the bubble morphology, the mean bubble size and the uniformity of the bubble size distribution. Here, an on-line method based on imaging techniques was developed for measuring these quantities in food foams manufactured in a continuous foaming device. On-line image acquisition was based on a quartz visualization cell that ensured a continuous renewal of the samples. The mean bubble size and the bubble size distribution were obtained using a semi-automated image analysis procedure. The method was validated on four kinds of aerated food emulsions (ice cream, whipped cream, aerated fresh cheese and a foamed sauce), corresponding to a large range of overrun (30–180%). The σ/d₃₂ ratio of bubble size distributions of dairy foamed emulsions was shown to be nearly constant, regardless of the recipe and of operating conditions.     

High-performance and cost-effective membrane electrode assemblies for advanced proton exchange membrane water electrolyzers: Long-term durability assessment

Improved activity and durability performance of a two-cell (86 cm²) proton exchange membrane water electrolyzer (PEMWE) stack is reported for the first time. Both membrane electrode assemblies (MEAs) contain one order of magnitude lower platinum group metal (PGM) loadings compared to the state-of-the-art PEMWEs and incorporate novel Pt recombination layers. The high-performance and cost-effective MEAs are fabricated by the unique reactive spray deposition technology (RSDT). This advanced methodology allows for one-step fabrication of MEAs and ensures precise control and distribution of the catalyst composition and loading. The RSDT-fabricated MEAs contain only 0.2 and 0.3 mg_PGM cm^?2 loading in the cathode and anode electrodes, respectively, and demonstrate excellent activity and durability for over 3000 h of operation at industrially-relevant operating conditions without showing significant loss in performance. This novel work shows that a significant cost reduction for PEMWEs is achieved while maintaining excellent durability, high catalysts activities, and low hydrogen cross-over.     

Enhanced removal of benzene in nonthermal plasma with ozonation,flow recycling,and flow recirculation

A double stage AC/DC sequential high voltage reactor has been developed to study the decomposition of benzene in the air stream at atmospheric pressure. The removal efficiency was measured as a function of ozonation, flow recycling, and flow recirculation. Ozonation in the inlet, and recycling of the exhaust stream increased the removal of benzene, also with increasing of specific input energy (J l⁻¹) the effect of inlet flow ozonation on benzene decomposition was enhanced. The highest removal efficiency was obtained up to >99% in recirculation six times, while CO₂ selectivity reached 99.9% and energy efficiency was 0.59 g kWh⁻¹. O₃ production/ decomposition > production of OH radicals > electronic and ionic collisions were indicated as the main mechanisms influencing benzene abatement in this research.     

Fabrication and characterization of polyvinyl chloride mixed matrix membranes containing high aspect ratio anatase titania and hydrous manganese oxide nanoparticle for efficient removal of heavy metal ions: Competitive removal study

In this study, novel polyvinyl chloride (PVC) ultrafiltration mixed matrix membranes (MMMs) containing high aspect ratio anatase titania (ANT) and hydrous manganese oxide (HMO) nanoparticles were synthesized in order to decontaminate cadmium and copper metal ions. ANT and HMO nanoparticles with various loadings in a range of 5-15 were used in the casting solution of MMMs. The characterization of fabricated MMMs was carried out with respect to the structural morphology, hydrophilicity, and composition by scanning electron microscopy (SEM), water contact angle, and Fourier transform infrared spectroscopy (FTIR), respectively. With an increase in the nanoparticle loadings, the change in other membrane characteristics such as mean pore size, pure water flux, and porosity were also evaluated. The results revealed that the mean pore size and water flux increased at a higher loading of ANT and HMO nanoparticles, while the contact angle and porosity of the membranes showed reverse trends. Moreover, the higher flux of pure water was obtained for PVC-ANT MMMs compared to PVC-HMO MMMs because of the larger mean pore size, higher porosity, and hydrophilicity of PVC-ANT MMMs. In this study, the decontamination of cadmium and copper metal ions in single and binary systems of heavy metals was investigated and the effect of Mn²⁺ (as an interfering ion) was also studied. The evaluation of the metal ion removal data demonstrated that the affinity sequence of both the PVC-ANT-15 and PVC-HMO-15 MMMs for heavy metal removal was Cu²⁺ > Cd²⁺ > Mn²⁺ in the single and binary systems. It was found through ultrafiltration (UF) experiments that PVC-ANT MMM was the most efficient membrane in the elimination of heavy metals due to the superior ANT adsorption capacity. However, the overall findings disclosed that both ANT and HMO nanoparticles are suitable candidates for the preparation of MMMs used in cadmium and copper decontamination from aqueous solutions.